Adsorption of copper and zinc by oil shale

 Oil shale is able to remove appreciable amounts of copper and zinc ions from aqueous solutions. It was noted that an increase in the adsorbent concentration with constant copper or zinc concentration resulted in greater metal removal from solution. An increase in the copper or zinc concentration with a constant sorbent concentration resulted in higher metal loading per unit weight of sorbent. For both metals, copper and zinc, equilibrium was attained after 24-h contact time. Increase in the initial pH or temperature of the metal solution resulted in an increase in the metal uptake per unit weight of the sorbent. Freundlich isotherm model was found to be applicable for the experimental data of Cu²⁺ and Zn²⁺. The results showed that oil shale could be used for the adsorption of the Cu²⁺ and Zn²⁺ with higher affinity toward Zn²⁺ ions. Addition of sodium salt to the metal solution influenced copper removal positively, but inhibited zinc removal. Received: 3 January 2000 · Accepted: 27 June 2000     

The relationship between seismic deformation and deep-seated gravitational movements during the 1997 Umbria–Marche (Central Italy) earthquakes

This paper re-evaluates the origin of some peculiar patterns of ground deformation in the Central Apennines, observed by space geodetic techniques during the two earthquakes of the Colfiorito seismic sequence on September 26th, 1997. The surface displacement field due to the fault dislocation, as modelled with the classic Okada elastic formulations, shows some areas with high residuals which cannot be attributed to non-simulated model complexities. The residuals were investigated using geomorphological analysis, recognising the geologic evidence of deep-seated gravitational slope deformations (DSGSD) of the block-slide type. The shape and direction of the co-seismic ground displacement observed in these areas are correlated with the expected pattern of movement produced by the reactivation of the identified DSGSD. At least a few centimetres of negative “Line of Sight” ground displacement was determined for the Costa Picchio, Mt. Pennino, and Mt. Prefoglio areas. A considerable horizontal component of movement in the Costa Picchio DSGSD is evident from a qualitative analysis of ascending and descending interferograms. The timing of the geodetic data indicates that the ground movement occurred during the seismic shaking, and that it did not progress appreciably during the following months. This work has verified the seismic triggering of DSGSD previously hypothesized by many researchers. A further implication is that in the assessment of DSGSD hazard seismic input needs to be considered as an important cause of accelerated deformation.     

The Big Circles in Jordan: First absolute ages using rock luminescence surface dating

In this study, we provide the first absolute ages for a Big Circle megalithic structure in Jordan, using rock surface luminescence dating of the buried surface of rocks collected from circle J4 in southern Jordan. Five rocks were used for this study. All rocks showed evidence of previous daylight exposure before being used in the construction of the circle. The exposure was sufficient to bleach the latent luminescence signal to a negligible level compared to the subsequent burial dose. Three rocks gave indistinguishable ages, and were last exposed to daylight in 1500 ± 100 BCE; this is very likely to be the date of circle construction. Two others gave younger ages, indicating later disturbance or reworking. These new results provide very strong evidence for construction during the Late Bronze Age, and refute the earlier hypothesis of construction during Umayyad period (661–750 CE) as a hunting trap.