Geochemical mobility of arsenic in the surficial waters from Argentina

The presence of arsenic (As) in surface water constitutes an important environmental risk, where mobility and adsorption processes are responsible for its behavior in the sediment–water interface. Therefore, the assessment of adsorption, mobility and water availability of arsenic in freshwater sediments, with agricultural, livestock and urban soil uses was performed. Arsenic concentrations in sediments ranged from 5.4 to 15.9 mg kg^?1 (total) and 2.8 to 6.5 mg kg^?1 (labile), and those of iron and manganese were 11,563–23,500 and 140.6–662.1 mg kg^?1, respectively. The As levels in water were significantly lower than those of sediments. Results would suggest that As co-precipitation and adsorption on Fe oxides are probably the major route of immobilization, determining its low lability. Manganese did not present an outstanding contribution to the retention, and cation-exchange capacity, pH and organic matter of sediments did not show an influence on the mobility of As.     

Flood risk management in Central Viet Nam: challenges and potentials

This article explores the impacts of floods on the economy, environment, and society and tries to clarify the rural community’s coping mechanism to flood disasters in Central Viet Nam. It focuses on the social aspects of flood risk perception that shapes the responses to floods. The research findings revealed that flooding is an essential element for a coastal population, whose livelihood depend on productive functions of cyclical floods. The findings also revealed that floods, causing losses and damages, often inhibited economic development. The surveyed communities appeared to have evolved coping mechanisms to reduce the negative impacts of the floods, yet these coping mechanisms are under pressure due to environmental degradation. Integrated flood risk management is considered as a suitable paradigm for coping with flood disasters.

Possible interaction between tectonic events and seismic noise at Las Cañadas Volcanic Caldera,Tenerife, Spain

Continuous seismic noise is recorded in the volcanic island of Tenerife (Canary Islands, Spain). The origin of this noise, strongly augmented by anthropogenic contamination, is still under debate. In this paper, we discuss the relationship between this noise and the occurrence of local tectonic events in the same area. In particular, transitions are sought in the time evolution of dynamic parameters computed on the seismic noise, and examples are shown where abrupt transitions may be associated with the occurrence of tectonic events. These transitions provide further evidence of the existence of a natural origin for at least part of the seismic noise, which is strongly contaminated—if not dominated—by anthropogenic sources.     

The role of mineralogy,geochemistry and grain size in badland development in Pisticci (Basilicata,southern Italy)

Mineralogical, geochemical and grain‐size composition of soil and pore‐water chemistry parameters were characterized on both eroded (south‐facing) and non‐eroded (north‐facing) clayey‐silt slopes in the Basilicata region (southern Italy). Only a few grain‐size parameters and clay mineralogy discriminate eroded from non‐eroded substrates. Compared with the latter, the former have fractions of over 63 µm and 1–4 µm lower and fractions 4–63 µm higher. Grain‐size characters of crusts did not discriminate with respect to substrate. Bulk rock mineralogy was not distinctive, but the clay mineral assemblage shows that the eroded slope is enriched in kaolinite, mixed layers (illite–smectite) and chlorite, whereas illite decreases, although overlaps are common. Chemical data enable discrimination between eroded and non‐eroded slopes. pH, SAR (sodium adsorption ratio), TDS (total dissolved salts) and PS (percentage of sodium) are distinctive parameters for both eroded and non‐eroded slopes. TDS increases in depth in the non‐eroded slope, whereas the maximum TDS is just below the crust in the eroded one. On average, eroded substrates are higher in pH, SAR and PS than non‐eroded ones. The ESP (exchangeable sodium percentage) of the eroded slope has a higher value than the non‐eroded one. Crusts are less dispersive than eroded substrates, and non‐eroded substrates behave as crusts. This suggests that the portion of the slope most severely exposed to weathering tends to stabilize, due to strong decreases in SAR, PS and ESP. Several diagrams reported in the literature show similarly anomalous crust samples on eroded slopes, compared with other samples coming from greater depths on eroded slopes. In the present case study, the exchangeable form of Na characterizes crusts more than the soluble form. This study describes the erosional mechanism, which involves morphological and geographic exposure and climatic elements, as well as grain size, mineralogy, chemistry and exchangeable processes of soils. Copyright © 2006 John Wiley & Sons, Ltd.     

Definition and performance of a threshold-based regional early warning model for rainfall-induced landslides

A process chain for the definition and the performance assessment of an operational regional warning model for rainfall-induced landslides, based on rainfall thresholds, is proposed and tested in a landslide-prone area in the Campania region, southern Italy. A database of 96 shallow landslides triggered by rainfall in the period 2003–2010 and rainfall data gathered from 58 rain gauges are used. First, a set of rainfall threshold equations are defined applying a well-known frequentist method to all the reconstructed rainfall conditions responsible for the documented landslides in the area of analysis. Several thresholds at different exceedance probabilities (percentiles) are evaluated, and nine different percentile combinations are selected for the activation of three warning levels. Subsequently, for each combination, the issuing of warning levels is computed by comparing, over time, the measured rainfall with the pre-defined warning level thresholds. Finally, the optimal percentile combination to be employed in the regional early warning system, i.e. the one providing the best model performance in terms of success and error indicators, is selected employing the “event, duration matrix, performance” (EDuMaP) method.     

Hydrodynamic instability of the solar nebula in the presence of a planetary core

When a planetary core composed of condensed matter is accumulated in the primitive solar nebula, the gas of the nebula becomes gravitationally concentrated as an envelope surrounding the planetary core. Models of such gaseous envelopes have been constructed subject to the assumption that the gas everywhere is on the same adiabat as that in the surrounding nebula. The gaseous envelope extends from the surface of the core to the distance at which the gravitational attraction of core plus envelope becomes equal to the gradient of the gravitational potential in the solar nebula; at this point the pressure and temperature of the gas in the envelope are required to attain the background values characteristics of the solar nebula. In general, as the mass of the condensed core increases, increasing amounts of gas became concentrated in the envelope, and these envelopes are stable against hydrodynamic instabilities. However, the core mass then goes through a maximum and starts to decrease. In most of the models tested, the envelopes were hydrodynamically unstable beyond the peak in the core mass. An unstable situation was always created if it was insisted that the core mass contain a larger amount of matter than given by these solutions. For an initial adiabat characterized by a temperature of 450°K and a pressure of 5 × 10^?6 atm, the maximum core mass at which instability occurs is approximately 115 earth masses; this value is rather insensitive to the position in the solar nebula or to the background pressure of the solar nebula. However, if the adiabat is lowered, then the core mass corresponding to instability is decreased. Since the core masses found by Podolak and Cameron for the giant planets are significantly less than the critical core mass corresponding to the initial solar nebula adiabat, we conclude that the giant planets obtained their large amounts of hydrogen and helium by a hydrodynamic collapse process in the solar nebula only after the nebula had been subjected to a considerable period of cooling.     

EXOTIME: searching for planets around pulsating subdwarf B stars

In 2007, a companion with planetary mass was found around the pulsating subdwarf B star V391 Pegasi with the timing method, indicating that a previously undiscovered population of substellar companions to apparently single subdwarf B stars might exist. Following this serendipitous discovery, the EXOTIME (http://www.na.astro.it/~silvotti/exotime/) monitoring program has been set up to follow the pulsations of a number of selected rapidly pulsating subdwarf B stars on time scales of several years with two immediate observational goals:

1. determine $\dot{P}$ of the pulsational periods P
2. search for signatures of substellar companions in O–C residuals due to periodic light travel time variations, which would be tracking the central star’s companion-induced wobble around the centre of mass

These sets of data should therefore, at the same time, on the one hand be useful to provide extra constraints for classical asteroseismological exercises from the $\dot{P}$ (comparison with “local” evolutionary models), and on the other hand allow one to investigate the preceding evolution of a target in terms of possible “binary” evolution by extending the otherwise unsuccessful search for companions to potentially very low masses. While timing pulsations may be an observationally expensive method to search for companions, it samples a different range of orbital parameters, inaccessible through orbital photometric effects or the radial velocity method: the latter favours massive close-in companions, whereas the timing method becomes increasingly more sensitive toward wider separations. In this paper we report on the status of the on-going observations and coherence analysis for two of the currently five targets, revealing very well-behaved pulsational characteristics in HS?0444+0458, while showing HS?0702+6043 to be more complex than previously thought.     

Characterization of Cu-complexes in smectite with different layer charge location: chemical, thermal and EXAFS studies

The retention of Cu and Cu-amino acid complexes by montmorillonite and beidellite, before and after repeated acidified aqueous solution treatments, was studied using X-ray diffraction, chemical and thermal analyses, mass spectrometry and synchrotron-based X-ray absorption spectroscopy (XAS).The results indicate that the extraction of metal complexes from smectites depends on the nature of the layer charge and on the kind of organic species. Cu-cysteine complexes are strongly retained in the interlayer position, whereas Cu-glycine complexes are mostly adsorbed in cationic form which can be easily removed from the silicate layer. The layer periodicity for Cu-smectites treated with glycine shows little or no layer expansion, whereas significant swelling of the layer periodicity is observed in smectites treated with cysteine.Thermal decomposition of both smectites with sorbed Cu-amino acid species shows the evolution of H₂O, NO, CH₃CH₃, and CO₂. In Cu-cysteine treated smectites, the release of H₂S, NO₂, SO₂, and N₂O₃ also occurs.X-ray absorption spectroscopy (XAS) was used to assess the relationships between the structure of the Cu complexes and their desorption from smectites. In Cu-exchanged smectites, the first coordination shell agrees with the hypothesis that the Cu coordinates to oxygen atoms to form monomer and/or dimer complexes. The first coordination shell of Cu in smectites treated with glycine shows four atoms at distances of ∼2 Å. Two of these bonds are with nitrogen and two with oxygen atoms. For copper-cysteine complexes XAS data are compatible with the existence of Cu-N clusters, thus suggesting that Cu links to the amino acid by the aminic group.     

Analysis of Ground Deformation Detected Using the SBAS-DInSAR Technique in Umbria, Central Italy

Ground deformation affecting the Umbria region (central Italy) in the 9-year period from 1992 to 2000 was investigated through multi-temporal Differential Synthetic Aperture Radar Interferometry (DInSAR). For the purpose, the Small BAseline Subset (SBAS) technique was adopted, which allows studying the temporal evolution of the detected deformation at two spatial scales: a low-resolution (regional) scale, and a full-resolution (local) scale. For the analysis, SAR data acquired by the European Remote Sensing (ERS-1/2) satellites along ascending and descending orbits were used. The detected deformation was analysed to investigate its relevance to geophysical, geomorphologic, and human-induced processes that may result in hazardous conditions to the population of Umbria. Low-resolution deformation data were used to: (i) determine the amount of displacement caused by the Umbria-Marche earthquake sequence from September 1997 to April 1998 in the Foligno area, (ii) determine the number and percentage of the known landslides that can be monitored by the DInSAR technology in the investigated area, and (iii) identify and measure subsidence induced by exploitation of a confined aquifer in the Valle Umbra. Results indicate that earthquakes moved through the Foligno area westwards up to 3.9 cm and with an uplift reaching 1.7 cm. Intersection in a GIS of the low-resolution deformation maps with a detailed landslide inventory map allowed the determination that the portion of landslides that can be monitored by the SBAS-DInSAR technique in Umbria ranges from 2.7% to 3.4%, and the percentage of the total landslide area ranges from 10.4% to 12.8%. In the Valle Umbra, a dependency was found between the time and the amount of detected ground deformation, and the record of water withdrawal. The full-resolution deformation data were used to investigate the movement of the Ivancich landslide, in the Assisi Municipality. Joint analysis of the spatial and the temporal characteristics of the ground displacement allowed the formulation of a hypothesis on the landslide geometry and deformation pattern.