<Superscript>57</Superscript>Fe Mössbauer spectroscopy,X-ray single-crystal diffractometry,and electronic structure calculations on natural alexandrite

Natural alexandrite Al₂BeO₄:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The ⁵⁷Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe³⁺ and Fe²⁺, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe³⁺ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe³⁺ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe³⁺ on M1.     

Changing poverty distribution in Bolivia: the role of rural–urban migration and urban services

Bolivia is a country with high levels of poverty and inequality among its peoples and regions. For the nation and its urban and rural areas, trends in the social and spatial distribution of poverty (and extreme poverty) are identified from 1976 to 2003 using UBN data with minor support where appropriate from poverty lines. The main survey between 1992 and 2001 uses composite and selected UBN to track detailed poverty change for the country’s nine departments, its ten largest cities and a selection of other smaller urban and rural municipalities. Because of rising background increases in population in the various surveyed administrative units, many instances of relative reductions in poverty are accompanied by rising absolute increases. Marked spatial variations in poverty and development in the country over the last several decades are identified as the main driver for the country’s quickening pace of rural–urban migration. As a result, the paper concludes by assessing two different but closely related views. One investigation tests the notion that because more poor people have been living in Bolivia’s cities than in its rural areas since the mid to late 1990s, rapid rural–urban migration has simply shifted the locus of poverty from the countryside to the cities in a process called, the ‘urbanisation of poverty.’ A second, more challenging, investigation assesses the view that the flow of poor rural people to the better serviced urban areas of Bolivia has actually acted to alleviate national poverty levels.     

A powder neutron diffraction study of the crystal structure of the fluoroperovskite NaMgF<Subscript>3</Subscript> (neighborite) from 300 to 3.6 K

The cell dimensions and crystal structures of the fluoroperovskite NaMgF₃ (neighborite), synthesized by solid state methods, have been determined by powder neutron diffraction and Rietveld refinement over the temperature range 300–3.6 K using Pt metal as an internal standard for calibration of the neutron wavelength. These data show that Pbnm NaMgF₃ does not undergo any phase transitions to structures of lower symmetry with decreasing temperature. The cell dimensions and atomic coordinates together with polyhedron volumes and distortion indices are given for Pbnm NaMgF₃ at 25 K intervals from 300 to 3.6 K. Decreases in the a and c cell dimensions reach a saturation point at 50 K, whereas the b dimension becomes saturated at 150 K. The distortion of the structure of Pbnm NaMgF₃ from the aristotype cubic structure is described in terms of the tilting of the MgF₆ octahedra according to the tilt scheme a ⁻ a ⁻ c ⁺ . With decreasing temperature the antiphase tilt (a ⁻) increases from 14.24° to 15.39°, whereas the in-phase tilt (c ⁺ ) remains effectively constant at ∼10.7°. Changes in the tilt angles are insufficient to cause changes in the coordination sphere of Na that might induce a low temperature phase transition. The structure of Pbnm NaMgF₃ is also described in terms of normal mode analysis and displacements of the condensed normal modes are compared with those of Pbnm KCaF₃.     

XMCD at Fe L<Subscript>2,3</Subscript> edges,Fe and S K edges on Fe<Subscript>7</Subscript>S<Subscript>8</Subscript>

Pyrrhotite (Fe₇S₈) is a natural iron sulphide that can participate in rock magnetisation. Its electronic structure is not yet surely described. X-ray magnetic circular dichroism (XMCD) at Fe L_2,3 edges on Fe₇S₈, coupled with multiplet calculations, shows that iron is present only as Fe²⁺ in this magnetic iron sulphide. It reveals a strong magnetic orbital moment. XMCD at Fe and S K edges shows the quite strong polarization of both Fe and S in Fe₇S₈.     

Graben width controlling syn-rift sedimentation: the Palaeogene southern Upper Rhine Graben as an example

Eocene to Early Oligocene syn-rift deposits of the southern Upper Rhine Graben (URG) accumulated in restricted environments. Sedimentation was controlled by local clastic supply from the graben flanks, as well as by strong intra-basinal variations in accommodation space due to differential tectonic subsidence, that in turn led to pronounced lateral variations in depositional environment. Three large-scale cycles of intensified evaporite sedimentation were interrupted by temporary changes towards brackish or freshwater conditions. They form three major base level cycles that can be traced throughout the basin, each of them representing a stratigraphic sub-unit. A relatively constant amount of horizontal extension (ΔL) in the range of 4–5 km has been estimated for the URG from numerous cross-sections. The width of the rift (L _f ), however, varies between 35 and more than 60 km, resulting in a variable crustal stretching factor between the bounding masterfaults. Apart from block tilting, tectonic subsidence was, therefore, largely controlled by changes in the initial rift width (L ₀). The along-strike variations of the graben width are responsible for the development of a deep, trough-like evaporite basin (Potash Basin) in the narrowest part of the southern URG, adjacent to shallow areas in the wider parts of the rift such as the Colmar Swell in the north and the Rhine Bresse Transfer Zone that delimits the URG to the south. Under a constant amount of extension, the along-strike variation in rift width is the principal factor controlling depo-centre development in extensional basins.     

Spatial assessment of groundwater use potential for irrigation in Teesta Barrage Project in Bangladesh

In Bangladesh, development of the groundwater resource for irrigation is a vital component of the government’s agricultural strategy to attain food self-sufficiency. Amidst reports of falling groundwater levels in many parts of Bangladesh, the potential of groundwater use has been investigated in the Teesta Barrage Project (TBP) in which large-scale groundwater development for dry-season irrigation has taken place in the recent past. Several techniques and tools have been applied such as the combination of analysis of groundwater hydrographs and mathematical modelling to derive key hydrogeological variables, calculation of net irrigation requirement and the use of geographical information systems. The results show that the economically attractive high-yielding variety (HYV) Boro (dry season) rice cultivation during the groundwater irrigation season may not be sustained in large parts of the project area if the current trends in abstraction are continued. However, due to spatial variation in abstraction, nine thanas (sub-districts)—out of a total of 21 in the project area—may still be able to expand groundwater-irrigated cropland and a groundwater-use potential of 40 mm/year may be created if deep-set shallow tubewells are used by the farmers to abstract groundwater. A structured approach, based on zoning of potential areas, is recommended for groundwater development and use.

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Resumen En Bangladesh, el desarrollo de las aguas subterráneas para riego es un componente vital del la estrategia agrícola del Gobierno para obtener la auto-suficiencia alimentaria. Un informe intermedio evidencia un descenso de los niveles de aguas subterráneas en muchas partes de Bangladesh, el uso potencial de aguas subterránea ha sido investigado en el Proyecto Tessta Barrage (TBP) en el cual ha tenido lugar el desarrollo de las aguas subterráneas a gran escala para el riego en la estación seca en un pasado reciente. Se ha aplicado algunas técnicas y herramientas, como la combinación del análisis de datos gráficos de aguas subterráneas y modelización matemática para obtener variables hidrogeológicas clave, el cálculo de la necesidad neta de riego y el uso de Sistemas de Información Geográfica. El resultado muestra que el cultivo, económicamente atractivo, de arroz HYV Boro (estación seca) durante la estación de riego con aguas subterráneas puede no ser sostenible en gran parte del área del proyecto si continúan las tendencias actuales en las extracciones. Sin embargo, debido a la variación espacial en la extracción, nueve thanas (subdistritos)—de un total de 21 en el área del Proyecto—pueden todavía sufrir un aumento de la tierra cultivable regada con aguas subterráneas y que se puede asumir un uso potencial de agua subterránea de 40 mm/estación si los granjeros utilizan sondeos someros instalados en fosas para la extracción. Se recomienda una aproximación estructurada para el desarrollo y uso de las aguas subterráneas, basada en la zonificación de áreas potenciales.

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Résumé Au Bangladesh, l’exploitation des ressources en eau souterraines pour l’irrigation est une composante vitale de la stratégie agricole gouvernementale pour atteindre l’auto-suffisance alimentaire. Parmi les baisses de niveaux piézométriques rapportées sur de nombreuses régions du Bangladesh, le potentiel d’utilisation des eaux souterraines a été étudié sur le Projet de Barrage de Teesta (TBP), où, dans un passé récent, les eaux souterraines ont été massivement exploitées pour l’irrigation en saison sèche. De nombreux outils et techniques ont été utilisés, comme l’analyse combinée des chroniques piézométriques et des modèles mathématiques pour dégager les variables hydrogéologiques clés, le calcul des besoins nets pour l’irrigation, et l’utilisation des systèmes d’information géographique. Les résultats démontrent que la culture en saison d’irrigation de la variété de riz HYV Boro (saison sèche), économiquement attrayante, n’est potentiellement pas viable sur de nombreux secteurs de la zone étudiée si les prélèvements perdurent selon la tendance actuelle. Cependant, du fait de la variation spatiale des prélèvements, neuf thanas (sous-districts)—sur un total de 21 sur le secteur d’étude—pourraient encore augmenter les surfaces irriguées, et une disponibilité en eau de 40 mm/saison pourrait être générée si les agriculteurs utilisaient des puits peu profonds pour exploiter les ressources souterraines. Une approche structurée, basée sur le zonage des secteurs potentiels, est recommandée pour l’exploitation et l’utilisation des eaux souterraines.

     

Analysis of kinematic seismic response of tapered piles

In the present work, a two-phase analysis is used to assess the lateral movement of a tapered pile due to kinematic seismic loading resulted from earthquakes. First, the free-field horizontal displacement of the ground due to earthquake is estimated using available theory of wave propagation. Second, these estimated soil movements are imposed on the taper pile in a closed-form solution to compute the pile response. The governing differential equation for an arbitrary pile segment is obtained, which includes the free-field horizontal movement estimated from the first phase. The equation is solved explicitly to obtain the horizontal deflection. Parametric studies show that tapered piles tend to be more flexible than uniform piles of the same volume and length under earthquake loading, which is soundly interesting.     

Investigation of waste disposal areas using electrical methods: a case study from Chania,Crete, Greece

A geophysical investigation of a landfill area was conducted as inextricable phase of a preliminary geotechnical, geological and hydrogeological study of the area under investigation. Electrical resistivity tomography (ERT), one of the most promising prospecting techniques mainly concerning its effective contribution to resolve several environmental problems, was applied for the geophysical modeling. ERT is a robust imaging method the theory and implementation of which are well documented in geophysical research literature. The survey site is located in Akrotirion Peninsula, about 7 km east of Chania city in Crete I. The geological setting comprises Trypalion limestones, marly limestones and a clayed weathered layer. Cavities are also identified at various scales which are recent tectono-karstic voids. Due to the above-mentioned geological singularity and in the light of the requirement for an environmentally safe construction of the landfill, an ERT survey was carried out. Specifically, seven geoelectrical tomographies were conducted reaching the prospecting depth of 36 m. The resulted images conduced, to overcome geotechnical problems since the spatial distribution of karstic voids was determined, to plan the future sites for waste disposal as the geological conditions were studied in detail and to reliably estimate the thickness of the already deposited wastes. The resulted images were confirmed using available borehole logs and ambient noise measurements.