浓硫酸钠水溶液中的离子对

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。     

Mixing of event and pre‐event water in a shallow Entisol in sloping farmland based on isotopic and hydrometric measurements,SW China

Water percolation and flow processes in subsurface geologic media play an important role in determining the water source for plants and the transport of contaminants or nutrients, which is essential for water resource management and the development of measures for pollution mitigation. During June 2013, the dynamics of the rainwater, soil water, subsurface flows and groundwater in a shallow Entisol on sloping farmland were monitored using a hydrometric and isotopic approach. The results showed that effective mixing of rainwater and soil water occurred in hours. The rebound phenomenon of δD profiles in soils showed that most isotope‐depleted rainwater largely bypassed the soil matrix when the water saturation in the soil was high. Preferential‐flow, which was the dominant water movement pattern in the vadose zone, occurred through the whole soil profile, and infrequent piston‐flow was mainly found at 20–40 cm in depth. The interflow in the soil layer, composed of 75.2% rainwater, was only generated when the soil profile had been saturated. Underflow in the fractured mudrock was the dominant flow type in this hillslope, and outflow was dominated by base flow (groundwater flow) with a mean contribution of 76.7%. The generation mechanism of underflow was groundwater ridging, which was superimposed upon preferential‐flow composed mainly of rainwater. The quick mixing process of rainwater and soil water and the rapid movement of the mixture through preferential channels in the study soil, which shows a typical bimodal pore size distribution, can explain the prompt release of pre‐event water in subsurface flow. Water sources of subsurface flows at peak discharge could be affected by the antecedent soil water content, rain characteristics and antecedent groundwater levels. Copyright © 2016 John Wiley & Sons, Ltd.     

Impacts of groundwater flow on the evolution of a thermokarst lake in the permafrost–dominated region on the Qinghai–Tibet plateau

As a result of global warming induced permafrost degradation in recent decades, thermokarst lakes in the Qinghai–Tibet plateau (QTP) have been regulating local hydrological and ecological processes. Simulations with coupled moisture–heat numerical models in the Beiluhe basin (located in the hinterland of permafrost regions on the QTP) have provided insights into the interaction between groundwater flow and the freeze–thaw process. A total of 30 modified SUTRA scenarios were established to examine the effects of hydrodynamic forces, permeability, and climate on thermokarst lakes. The results indicate that the hydrodynamic condition variables regulate the permafrost degradation around the lakes. In case groundwater recharges to the lake, a low–temperature groundwater flow stimulates the expansion of the surrounding thawing regions through thermal convection. The thawing rate of the permafrost underlying the lake intensifies when groundwater is discharged from the lake. Under different permeability conditions, spatiotemporal variations in the active layer thickness significantly influence the occurrence of an open talik at the lake bottom. A warmer and wetter climate will inevitably lead to a sharp decrease in the upper limit of the surrounding permafrost, with a continual decrease in the duration of open talik events. Overall, our results underscore that comprehensive consideration of the relevant hydrologic processes is critical for improving the understanding of environmental and ecological changes in cold environments.     

Effects of Enclosure on Plant and Soil Nutrients in Different Types of Alpine Grassland

Enclosure is one of the most widely used management tools for degraded alpine grassland on the northern Tibetan Plateau, but the responses of different types of grassland to enclosure may vary, and research on these responses can provide a scientific basis for improving ecological conservation. This study took one site for each of three grassland types (alpine meadow, alpine steppe and alpine desert) on the northern Tibetan Plateau as examples, and explored the effects of enclosure on plant and soil nutrients by comparing differences in plant community biomass, leaf-soil nutrient content and their stoichiometry between samples from inside and outside the fence. The results showed that enclosure can significantly increase all aboveground biomass in these three grassland types, but it only increased the 10-20 cm underground biomass in the alpine desert. Enclosure also significantly increased the leaf nutrient content of the dominant plants and contents of total nitrogen (N), total potassium (K), and organic carbon (C) in 10-20 cm soil in alpine desert, thus changing the stoichiometry between C, N and P (phosphorus). However, enclosure significantly increased only the N content of dominant plant leaves in alpine steppe, while other nutrients and stoichiometries of both plant leaves and soil did not show significant differences in alpine meadow and alpine steppe. These results suggested that enclosure has differential effects on these three types of alpine grasslands on the northern Tibetan Plateau, and the alpine desert showed the most active ecological conservation in the responses of its soil and plant nutrients.     

Peatland initiation and carbon dynamics in northeast China: links to Holocene climate variability

Throughout northeast China, the widely distributed peatlands have formed a large carbon (C) pool. However, the relationship between peatland initiation and climate controls is still poorly documented and understood. Understanding the responses of these C‐rich ecosystems to past climate change will provide useful insights into projecting the fate of peatland C in the future. In this study, we present a detailed historical reconstruction of peatland development in northeast China based on 312 basal peat dates, and examine the relationship between Holocene peatland dynamics and climate sensitivity. Our results indicate that peatland initiation started in the early Holocene, and that the majority of peatlands were initiated by and developed during the late Holocene. After the most intensive initiation period of 4.2–0.8 ka, the rate of peatland development slowed, which was concomitant with decreasing insolation and monsoon intensity. The widespread peatland initiation in the late Holocene might have been caused by the cool and moist climate patterns. The optimum timing of the peatland development was not uniform across northeast China, and these spatio‐temporal differences indicate the influences of regional climate and terrain on peatland initiation. Peat‐core data show variations in the long‐term apparent rate of C accumulation (LORCA) during the Holocene, with an average rate of 37.2 g C m^?2 a^?1. The peak LORCA occurred during 10.5–9.0 ka, probably in response to higher temperatures and stronger East Asia summer monsoon intensities. Both temperature and humidity are important factors influencing the peatland initiation and C dynamics in this region.     

Numerical simulation on mining-induced water inrushes related to geologic structures using a damage-based hydromechanical model

A large number of statistics indicate that water inrush has a direct relationship with geological structures such as fault and karst collapse columns. Understanding the mechanism of water inrushes controlled by geologic structures is of vital importance for adopting effective measures to prevent their occurrence. The work begins with formulization of a damage-based hydromechanical model based on elastic damage theory. Next, the model is numerically implemented with finite element method by employing a finite element package called COMSOL Multiphysics, and is also validated against some existing experimental observations. Finally, the model is used to simulate the mining-induced groundwater inrushes when the effect of faults and karst collapse columns is considered in the numerical simulation, and some suggestive conclusions for preventing water inrushes and optimizing underground mining operations are drawn.     

Assessing the effectiveness of imperviousness on stormwater runoff in micro urban catchments by model simulation

Imperviousness, considered as a critical indicator of the hydrologic impacts of urbanization, has gained increasing attention both in the research field and in practice. However, the effectiveness of imperviousness on rainfall–runoff dynamics has not been fully determined in a fine spatiotemporal scale. In this study, 69 drainage subareas <1 ha of a typical residential catchment in Beijing were selected to evaluate the hydrologic impacts of imperviousness, under a typical storm event with a 3‐year return period. Two metrics, total impervious area (TIA) and effective impervious area (EIA), were identified to represent the impervious characteristics of the selected subareas. Three runoff variables, total runoff depth (TR), peak runoff depth (PR), and lag time (LT), were simulated by using a validated hydrologic model. Regression analyses were developed to explore the quantitative associations between imperviousness and runoff variables. Then, three scenarios were established to test the applicability of the results in considering the different infiltration conditions. Our results showed that runoff variables are significantly related to imperviousness. However, the hydrologic performances of TIA and EIA were scale dependent. Specifically, with finer spatial scale and the condition heavy rainfall, TIA rather than EIA was found to contribute more to TR and PR. EIA tended to have a greater impact on LT and showed a negative relationship. Moreover, the relative significance of TIA and EIA was maintained under the different infiltration conditions. These findings may provide potential implications for landscape and drainage design in urban areas, which help to mitigate the runoff risk. Copyright © 2015 John Wiley & Sons, Ltd.     

Prediction of the South China Sea Dipole Using SSA-MEM

ABSTRACT

A dipole structure appears in the sea surface height off the central coast of Vietnam during boreal summer in the South China Sea. This dipole, which possesses a chlorophyll signature associated with higher phytoplankton concentrations arising from nutrient upwelling, is important for the productivity of local fisheries. Multi-satellite sea level anomalies are used to investigate the life cycle of the dipole structure. By applying empirical orthogonal function (EOF) analysis, the third EOF mode (EOF 3) is found to represent the major variations of the dipole structure. By removing the temporal noise of EOF 3, a South China Sea dipole index is defined. This index captures the life cycle of the dipole including its generation, mature strength, and final termination. Both one-dimensional and two-dimensional forecasts are generated using a statistical forecasting method that combines singular-spectrum analysis and the maximum entropy method. The appearance of the dipole structure can be predicted with an accuracy of 78% at one-month lead times and an accuracy of 61% at one-year lead times.     

临震前地壳变形不动点现象与机制研究

在综合分析国内外地形变前兆研究现状的基础上,结合汶川8.0级地震前GPS、应变、重力等研究结果,提出临震前震源区域可能出现变形不动点现象。地壳变形过程中的不动点现象是临震前区域应力场进入临界状态的重要标志,是地震潜在危险区域划定的重要依据。借助不动点理论,给出汶川地震前变形不动点集合的演化,结合大区域地震活动空区与远场显著形变异常分布,探讨变形不动点现象发生的动力学背景,验证了汶川地震前地壳变形的不动点现象是大区域应力场有序运动的结果。