Dissolved and particulate trace metals and their partitioning in a hypoxic estuary: The Tanshui Estuary in Northern Taiwan

The distribution and partitioning of trace metals (Co, Cu, Fe, Mn, Ni, and Zn) between dissolved and particulate phases were studied in the Tanshui Estuary. The upper reach of the estuary is hypoxic and heavily polluted due to domestic and industrial discharges. The concentration ranges of dissolved and leachable particulate trace metals in the Tanshui Estuary were: Co: 0.3–6.1 nM, 1.8–18.6 mg kg⁻¹; Cu: 5–53 nM, 22–500 mg kg⁻¹; Fe: 388–3,364 nM, 1.08–6.67%; Mn: 57–2,914 nM, 209–1,169 mg kg⁻¹; Ni: 7–310 nM, 6–108 mg kg⁻¹; and Zn: 12–176 nM, 62–1,316 mg kg⁻¹; respectively. The dissolved concentrations of the metals were 2–35 times higher than the average values of the world river water. The distributions of dissolved and particulate studied metals, except Mn, in the estuary showed scattering, which could be attributed to the discharges from many industrial wastewater disposal works located in the upper tributaries. The daily input of dissolved metals from the disposal works to the Tanshui Estuary ranged from 0.1–0.4 tons. Dissolved Mn was nearly conservative in the region with salinity higher than 10 psu, while particulate Mn decreased in the region with salinity of 10–15 psu. The concentration increased significantly seawards, corresponding with the distribution of dissolved oxygen. The distribution coefficient (K_D) for Mn in the lower estuary was nearly three orders of magnitude higher than in the upper estuary. This phenomenon may be attributed to the diffusion of Mn from the anoxic sediment in the upper estuary and gradual oxidation into particulate Mn in the middle and lower estuary as the estuarine water became more oxygenated. The distribution coefficient for Cu decreased with increasing salinity. The percentages of trace metals bound by suspended particulate matter decreased in the following order: Fe>Zn, Cu>Co>Mn>Ni.     

中条山同善天窗铜矿类型及找矿新认识

在总结同善构造—剥蚀窗内成矿地质条件的前提下 ,运用成矿系列理论 ,把区内具有多种表现形式的变基性火山岩型、变砂岩型、大理岩型三大类铜矿分成了八种亚类 ,认为诸类铜矿与区内广泛发育的新太古代基性岩存在着成生联系 ,铜矿的形成经历了一个复杂的过程。早期的海底火山喷发带来的铁、铜、硫等成矿物质 ,经过最初的海水富集、火山活动末期的热液作用富集以及后来区域变质叠加富集进而形成了这一系列矿床。同时提出了新的找矿思路、找矿方法及找矿靶区。     

Geochronology of Gold Deposits and Its Implication for Metallogenesis in the Fengxian-Lixian Area, Qinling Orogenic Belt, China

Abstract: A series of super large‐scale and large‐scale Pb and Zn, and Au deposits are distributed in the Qinling orogenic belt, China. Gold deposits were generally ascribed to Carlin‐type originated from circular meteoric water. Visible and coarse‐grained gold (up to over 3mm in grain size) was recently identified in some gold deposits in the Fengxian‐Lixian area, Qinling. Au‐bearing quartz lodes related to magmatism were discovered in the Xiaogouli gold deposit. Two types of Au‐bearing quartz veins, i.e., NW‐trending quartz veins and NE‐trending quartz veins cutting strata are widely present in the Baguamiao gold deposit. Both are spatially associated with each other. The former is generally snake–like, S‐shape or zigzag, which was resulted from plastic deformation by ductile shearing, being generally cut by the latter. The latter is generally linear with widely developed bleaching alteration zones in its adjacent wall rocks, which symbolizes the superimposition of brittle deformation and filling and metasomatism of magmatic hydrothermal solution in ductile shear zones after uplifting of the shear zones near the surface. The NW‐trending quartz veins contain Au of lower than 3ppm. The NE‐trending quartz veins contain Au of more than 3 ppm, so that NE‐trending quartz veins and the adjoining altered rocks are important ores. The NW‐trending Au–bearing quartz vein was dated as 210.61.26 to 232.581.59 Ma by ⁴⁰Ar–³⁹Ar method, i.e., late Indosinian epoch (Triassic). The NE‐trending Au–bearing quartz vein was dated as 131.910.89 to 197.451.13 Ma by ⁴⁰Ar–³⁹Ar method, i.e., Yanshanian epoch (Jurassic). The ⁴⁰Ar–³⁹Ar age of the NW‐trending Au–bearing quartz veins represents the age of the ductile shear formation. The isotope data of the NE‐trending quartz veins indicate that gold mineralization was closely related to Indosinian and Yanshanian granite intrusives not only in time and space, but also in origin.     

泥页岩吸水扩散系数测量新方法

介绍了一种模拟井下温压条件下泥页岩吸水扩散系数测量的新方法及共实验装置和实验数据回归处理技术.利用该装置对泥页岩的扩散系数值进行了测定,并据此对泥浆滤液在泥页岩井壁中的渗透运移规律进行了数值计算.使用结果表明,该种测量方法新颖科学、数据可靠,且大大的简化了实验过程,缩短了实验时间,所得结果更符合现场实际,具有较大的实用价值.     

某人工挖孔桩质量事故检测及加固处理实例

应用动测和钻芯等无损检测技术,综合诊断分析出某桩基工程的重大质量隐患,发现了桩身空洞缺陷或桩底沉渣等质量问题,并采用灌浆技术进行了加固处理.     

塑料排水板在高速公路软基处理中的效果分析

基于塑料排水板排水固结机理,利用编制的程序结合实例,计算了不同参数的塑料排水板在成层地基、多级等速加载情况下不同时间的固结度,对几种主要参数对固结效果的影响进行了分析,并对相应参数的取值问题提出了优化意见.     

模拟深基坑开挖和支护全过程的有限元数值分析

选用Drucker-Prager弹塑性本构关系,建立了模拟深基坑开挖和支护全过程的平面有限元数值分析模型.运用该模型并结合工程实际,对深基坑开挖过程巾边坡土体的应力场和塑性区的分布以及变形进行了分析,找出了影响深基坑变形的主要因素:支护结构的刚度、支护结构入土深度、基坑开挖深度和宽度以及土层强度参数等.     

深基坑土钉锚固技术工程应用研究

简要介绍了土钉挡墙技术的发展历史及其国内外的发展现状,分析了常用深基坑土钉挡墙的计算方法和使用条件,提出了当前土钉技术应用中亟待解决的问题,探讨了土钉技术今后的发展方向.     

新疆伽师及邻近地区现今地壳形变的GPS监测与研究

利用高精度数据软件对伽师及邻近地区的GPS监测网观测数据进行计算分析(基线精度达到了 10 - 8～ 10 - 9) ,获得了该地区的现今地壳形变速率图 .结果表明 ,伽师及邻近地区在印度板块的推挤作用下 ,地壳正快速缩短变形 ,主压应力为近南北方向 .各地块运动速率不同 ,平均应变率为 0 .0 4× 10 - 6 /a .     

有限元分析方法在黄土地基震陷预测中的应用

将有限元方法应用于黄土地基的震陷量预测，定量地研究了黄土地基地震沉陷特性与场地条件、基础形式、土动力特性等因素的相关关系，为黄土地基基础的抗震增稳设计与处理提供了科学依据。