三元体系Li~+,Mg~(2+)∥SO_4~(2-)—H_2O 25℃相关系及溶液物化性质的研究

研究了三元体系Li~+,Mg~(2+)∥SO_4~(2-)—H_2O在25℃时的相关系和平衡液相的密度、粘度、折光率、电导等物化性质,该体系为简单共饱型,两段溶解度曲线对应于体系的两种原始组份Li_2SO_4·H_2O和MgSO_4·7H_2O的结晶区,无复盐和固溶体形成,亦无脱水作用发生,应用电解质溶液Pitzer模型检测该体系25C的溶解度,并用经验或半经验公式对平衡液相的密度和折光率进行了理论计算,计算值与实验值非常接近。     

A PRELIMINARY ANALYSIS ON THE CHARACTERISTICS OF THE KUROSHIO FRONTAL EDDY IN THE EAST CHINA SEA IN SPRING

The Kuroshi'o front eddy's surface and sectional isothermal distribution characteristics were analyzed on the basis of observation data obtained in April 13-16 of 1989 in the East China Sea. It was found from the similarity between these isothermal distributions with those in January and beginning of June for the years 1986-1990 that the Kuroshio front eddy often occurred from March to the beginning of June. The Kuroshio front eddy movement in the East China Sea in spring was along two routes: the Okinawa Trough route, and the continental shelf slope route. The two moving routes both in the surface layer and in the section are described, their causes are discussed, and differences are compared.     

正压大气中非线性重力惯性波的非频散周期解——论Taylor展开的可能性

本文论证了正压大气中非线性重力惯性波的非频散周期解存在性及找到了该波解存在条件。通常来说要得到解析解是困难的,故利用Taylor展开来得到近似解。本文给出了Taylor展开的可能性。然后在Taylor展开允许的情况下,我们得到了近似解的表达式及波速公式,给出了该波动流场与位势高度场的配置结构,并揭示了非线性效应使得波动结构变得不对称。     

REE Geochemistry in the Weathered Crust of Granites, Longnan Area,Jiangxi Province

Warm and humid climate and gentle hilly topography have provided favourable conditions for the devel-opment of the weathering crust of the granite intrusions in the Longnan area, Jiangxi Province. REE is mostlyconcentrated in an adsorption state in clay in the wholly weathered zone. The rare-earth minerals enriched inthe parent rocks provided the source material for the REE enrichment. Exchangeable REE accounts for48-86%. Extraction experiments and stable isotopic study of clay minerals suggest that the downward infiltra-tion of meteoric water and increasing gradient of pH values have played an important role in the enrichment ofREE during the progressive weathering. Slight fractionation of individual REE can not change their distribu-tion patterns in the profiles. which are inherited from the parent rocks.     

博格达山晚古生代坳拉谷(Aulacogen)的初步研究

博格达地区在晚古生代不是与哈尔里克相联的岛弧,而是坳拉谷.它发育较完整的滨浅海→陆棚→陆坡→坡角→盆地平原相的沉积相序.建造类型和充填序列与国内外坳拉谷很相似,而与岛弧建造相差甚远.早期具多旋回的火山喷发,中期发育多种重力流沉积组分,晚期出现复理石和磨拉石建造.东与兴蒙大洋相联,西端伸入准噶尔小板块内部.从中泥盆世开始由巴里坤一带逐渐向乌鲁木齐地区发育.     

钛-氨三乙酸-对氯苯基荧光酮-CTMAB四元配合物的分光光度法研究

本文研究Ti(Ⅳ)-氨三乙酸(NTA)-对氯苯基荧光酮(p-ClPF)-CTMAB四元配合物的显色条件。结果表明,在pH5.8—6.6形成了摩尔比为Ti(Ⅳ):NTA:p-ClPF:CTMAB=1:1:3:3的四元配合物,借此反应测定钛,灵敏度高,其ε_(573nm)=2.1×10~5L·mol~(-1)·cm~(-1)。Ti(Ⅳ)浓度在0—1.4μg/10ml范围服从比耳定律。已用本法直接测定了岩矿和铝合金中的Ti,结果满意。     

陕西地区岩浆岩Nd、Sr同位素特征及其与大地构造发展的联系

岩浆岩Nd、Sr同位素特征表明,扬子地块基底有着和华北地块很不相同的早期演变历史。这意味着华北和扬子两地块在历史上曾经是相互独立的,后来才拼合在一起。Nd、Sr同位素研究还表明,华北和扬子两地块的会聚在泥盆纪以前就已经在进行中,它是通过位於两地块之间的古秦岭海洋壳俯冲消亡在华北地块之下实现;华北和扬子两陆块最终相碰撞至少发生在二叠纪以前。     

邯邢侵入体中幔源超镁铁质岩包体的发现及其矿物地球化学特征

邯邢中基性侵入杂岩体中产有众多的岩石包体。作者在暗色闪长岩相中首次发现了超镁铁质岩包体,以方辉榄橄岩为主,由镁榄橄石(Fo=92±),顽火辉石(En=90±),铬透辉石和铬尖晶石组成,碎斑-平结构,发育扭折带。全岩SiO_2=41.02,MgO=42.24,∑EREE(3.95)甚低,稀土元素配分曲线显示特殊的向下凸的形状。δ~(18)O=6.5～7.0。辉石平衡温度约为1000℃,压力为20×10~8～22×10~8Pa。矿物-地球化学研究表明具上地幔岩特征,属A型包体,这在国内外文献中还未曾见过类似的报导。这个发现对探讨华北板块的地壳上地幔组成与演化,中生代构造岩浆活动的大地构造背景以及物质来源和邯邢式铁矿的成因将产生深远的影响。     

Huanghe (Yellow River) and its estuary: Sediment origin, transport and deposition

The upper part of the Huanghe (Yellow River) drainage basin supplies 50–60% of the annual water discharge and only 10% of the total river sediment load, while the middle reaches contribute 30–40% of the water flow and 90% of the annual sediment load, because of severe erosion over the Loess Plateau. Large variations in both annual water discharge and sediment load occur in the Huanghe. Heavy sedimentation in the lower reaches of the channel makes the river bed aggrade several centimetres per year. Of the suspended sediment in the river, 90–95% is deposited in the lower part of the river course and in the coastal shallow water area; less than 5–10% escapes from Laizhou Bay and enters the Central Bohai and/or North Huanghai (Yellow Sea). The active delta complex now propagates seawards at a mean rate of 42 km² year⁻¹.