电活化硫酸盐处理四环素类废水的研究

本文构建以掺硼金刚石(Boron-doped diamond,BDD)为阳极、不锈钢为阴极、硫酸盐为电解质的电化学体系,考察了电流密度、pH值、硫酸盐浓度以及初始四环素浓度等四个因素对电化学氧化降解废水中四环素的影响,运用响应曲面法对运行参数进行优化;通过电子自旋共振检测技术分析电化学反应中产生的自由基,探究了间歇通电模式下电化学体系持续氧化机理。结果表明,四个因素对TOC去除率的影响大小次序为:电流密度>初始四环素浓度>初始pH值>硫酸盐浓度,其中初始pH值和硫酸盐浓度与电流密度和初始四环素浓度的交互作用对TOC去除率的影响较为显著;最佳运行参数为pH值为5,电流密度为100 mA·cm^-2,硫酸盐浓度为0.25 mol·L^-1,初始四环素浓度为1000 mg·L^-1;间歇通电模式下,BDD电极表面产生的SO₄^·-等高活性物质间相互转化提供了体系的可持续氧化能力。该研究结果为电化学氧化技术的实际应用提供了节省能耗的有效途径。     

Multi-scale coupling analysis of urbanization and ecosystem services supply-demand budget in the Beijing-Tianjin-Hebei region,China

Journal of Geographical Sciences - Rapid economic development and human activities have severely affected ecosystem function. Analysis of the spatial distribution of areas of rapid urbanization is...     

Spatiotemporal variations of water use efficiency and its driving factors in Inner Mongolia from 2001 to 2020

Water use efficiency (WUE) is an important variable to explore coupled relationships in carbon and water cycles. In this study, we first compared the spatial variations of annual gross primary productivity (GPP) and evapotranspiration (ET) using four GPP and ET products. Second, we selected the products closest to the flux towers data to estimate WUE. Finally, we quantitatively analyzed the impact of climate change and soil water content on WUE. The results showed that: (1) Four GPP and ET products provided good performance, with GOSIF-GPP and FLDAS-ET exhibiting a higher correlation and the smallest errors with the flux tower data. (2) The spatial pattern of WUE is consistent with that of GPP and ET, gradually decreasing from the northeast to the southwest. Higher WUE values appeared in the northeast forest ecosystem, and lower WUE values occurred in the western Gobi Desert, with a value of 0.28 gC m^?2 mm^?1. The GPP and ET products showed an increasing trend, while WUE showed a decreasing trend (55.15%) from 2001 to 2020. (3) The spatial relationship between WUE and driving factors reveal the variations in WUE of Inner Mongolia are mainly affected by soil moisture between 0 and 10 cm (SM0-10cm), vapor pressure deficit (VPD), and precipitation, respectively. (4) In arid regions, VPD and precipitation exhibit a major influence on WUE. An increase in VPD and precipitation has a negative and positive effect on WUE, with threshold values of approximately 0.36 kPa and 426 mm, respectively. (5) In humid regions, SM0-10cm, VPD, SM10-40cm, and SM40-100cm exert a significant impact on WUE, especially SM0-10cm, and weakens with increasing soil depths, these differences may be related to physiological structure and living characteristics of vegetation types in different climate regimes. Our results emphasize the importance of VPD and soil moisture in regional variability in WUE.     

Transcriptome profile of Dunaliella salina in Yuncheng Salt Lake reveals salt-stress-related genes under different salinity stresses

Journal of Oceanology and Limnology - Salt stress is an abiotic stress to plants in especially saline lakes. Dunaliella, a halophilic microalga distributed throughout salt lakes and seas, can...     

可控源法在海阳市郭城地区鑫泰金矿床成矿规律中的应用

可控源音频大地电磁法(CSAMT法)是一种利用人工场源研究地层、构造等深部地质特征问题的新技术新方法。在山东省海阳市郭城地区鑫泰金矿床的应用研究表明,CSAMT法可以较好地用于确定矿体的产状和大致地层结构,在矿体成矿规律研究方面具有较为突出的应用效果。     

中国科技资源配置效率测度及其时空格局演变特征(英文)

According to the connotation and structure of science and technology resources and some relevant data of more than 286 cities at prefecture level and above during 2001–2010, using modified method—Data Envelopment Analysis(DEA), science and technology(ST) resource allocation efficiency of different cities in different periods has been figured out, which, uncovers the distributional difference and change law of ST resource allocation efficiency from the time-space dimension. Based on that, this paper has analyzed and discussed the spatial distribution pattern and evolution trend of ST resource allocation efficiency in different cities by virtue of the Exploratory Spatial Data Analysis(ESDA). It turned out that:(1) the average of ST resource allocation efficiency in cities at prefecture level and above has always stayed at low levels, moreover, with repeated fluctuations between high and low, which shows a decreasing trend year by year. Besides, the gap between the East and the West is widening.(2) The asymmetrical distribution of ST resource allocation efficiency presents a spatial pattern of successively decreasing from Eastern China, Central China to Western China. The cities whose ST resource allocation efficiency are at higher level and high level take on a cluster distribution, which fits well with the 23 forming urban agglomerations in China.(3) The coupling degree between ST resource allocation efficiency and economic environment assumes a certain positive correlation, but not completely the same. The differentiation of ST resource allocation efficiency is common in regional development, whose existence and evolution are directly or indirectly influenced by and regarded as the reflection of many elements, such as geographical location, the natural endowment and environment of ST resources and so on.(4) In the perspective of the evolution of spatial structure, ST resource allocation efficiency of the cities at prefecture level and above shows a notable spatial autocorrelation, which in every period presents a positive correlation. The spatial distribution of ST resource allocation efficiency in neighboring cities seems to be similar in group, which tends to escalate stepwise. Meanwhile, the whole differentiation of geographical space has a diminishing tendency.(5) Viewed from LISA agglomeration map ofST resource allocation efficiency in different periods, four agglomeration types have changed differently in spatial location and the range of spatial agglomeration. And the continuity of ST resource allocation efficiency in geographical space is gradually increasing.     

Propagation of vertical and horizontal source data errors into a TIN with linear interpolation

Digital elevation models (DEMs) have been widely used for a range of applications and form the basis of many GIS-related tasks. An essential aspect of a DEM is its accuracy, which depends on a variety of factors, such as source data quality, interpolation methods, data sampling density and the surface topographical characteristics. In recent years, point measurements acquired directly from land surveying such as differential global positioning system and light detection and ranging have become increasingly popular. These topographical data points can be used as the source data for the creation of DEMs at a local or regional scale. The errors in point measurements can be estimated in some cases. The focus of this article is on how the errors in the source data propagate into DEMs. The interpolation method considered is a triangulated irregular network (TIN) with linear interpolation. Both horizontal and vertical errors in source data points are considered in this study. An analytical method is derived for the error propagation into any particular point of interest within a TIN model. The solution is validated using Monte Carlo simulations and survey data obtained from a terrestrial laser scanner.     

Water discharge variability of Changjiang （Yangtze） and Huanghe （Yellow） Rivers and its response to climatic changes

Influences of large-scale climatic phenomena, such as the E1Nifio/La Nifia-Southem Oscillation （ENSO） and the Pacific Decadal Oscillation （PDO）, on the temporal variations of the annual water discharge at the Lijin station in the Huanghe （Yellow） River and at the Datong station in the Changjiang （Yangtze） River were examined. Using the empirical mode decomposition-maximum entropy spectral analysis （EMD- MESA） method, the 2- to 3-year, 8- to 14-year, and 23-year cyclical variations of the annual water discharge at the two stations were discovered. Based on the analysis results, the hydrological time series on the inter- annual to interdecadal scales were constructed. The results indicate that from 1950 to 2011, a significant downward trend occurred in the natural annual water discharge in Huanghe River. However, the changes in water discharge in Changjiang River basin exhibited a slightly upward trend. It indicated that the changes in the river discharge in the Huanghe basin were driven primarily by precipitation. Other factors, such as the precipitation over the Changjiang River tributaries, ice melt and evaporation contributed much more to the increase in the Changjiang River basin. Especially, the impacts of the inter-annual and inter-decadal climate oscillations such as ENSO and PDO could change the long-term patterns of precipitation over the basins of the two major rivers. Generally, low amounts of basin-wide precipitation on interannual to interdecadal scales over the two rivers corresponded to most of the warm ENSO events and the warm phases of the PDO, and vice versa. The positive phases of the PDO and ENSO could lead to reduced precipitation and consequently affect the long-term scale water discharges at the two rivers.     

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Wave effect on the ocean circulations through mass transport and wave-induced pumping

The wave Coriolis-Stokes-Force-modified ocean momentum equations are reviewed in this paper and the wave Stokes transport is pointed out to be part of the ocean circulations. Using the European Centre for Medium-Range Weather Forecasts 40-year reanalysis data (ERA-40 data) and the Simple Ocean Data Assimilation (SODA) version 2.2.4 data, the magnitude of this transport is compared with that of wind-driven Sverdrup transport and a 5-to-10-precent contribution by the wave Stokes transport is found. Both transports are stronger in boreal winter than in summers. The wave effect can be either contribution or cancellation in different seasons. Examination with Kuroshio transport verifies similar seasonal variations. The clarification of the efficient wave boundary condition helps to understand the role of waves in mass transport. It acts as surface wind stress and can be functional down to the bottom of the ageostrophic layer. The pumping velocities resulting from wave-induced stress are zonally distributed and are significant in relatively high latitudes. Further work will focus on the model performance of the wave-stress-changed-boundary and the role of swells in the eastern part of the oceans.