电活化硫酸盐处理四环素类废水的研究

本文构建以掺硼金刚石(Boron-doped diamond,BDD)为阳极、不锈钢为阴极、硫酸盐为电解质的电化学体系,考察了电流密度、pH值、硫酸盐浓度以及初始四环素浓度等四个因素对电化学氧化降解废水中四环素的影响,运用响应曲面法对运行参数进行优化;通过电子自旋共振检测技术分析电化学反应中产生的自由基,探究了间歇通电模式下电化学体系持续氧化机理。结果表明,四个因素对TOC去除率的影响大小次序为:电流密度>初始四环素浓度>初始pH值>硫酸盐浓度,其中初始pH值和硫酸盐浓度与电流密度和初始四环素浓度的交互作用对TOC去除率的影响较为显著;最佳运行参数为pH值为5,电流密度为100 mA·cm^-2,硫酸盐浓度为0.25 mol·L^-1,初始四环素浓度为1000 mg·L^-1;间歇通电模式下,BDD电极表面产生的SO₄^·-等高活性物质间相互转化提供了体系的可持续氧化能力。该研究结果为电化学氧化技术的实际应用提供了节省能耗的有效途径。     

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正Electrical and electromagnetic method Wang et al.present an anomalous principal component decomposition method based on the Stratton-Chu integral.The airwaves and sea layers can be separated from the anomalous field,eliminating the airwave effect.The method is implemented in integral transform form,making it a robust processing method,is particularly effective for removing the effect of the entire sea layer.     

Indicator of Favorable Sedimentary Facies and Shale Enrichment in Lower Silurian Longmaxi Formation, Eastern Sichuan Basin, China

<正>1 Introduction The organic-rich shale in Lower Silurian Longmaxi formation Sichuan Basin is marine sedimentary strata,and it has large thickness and rich resources.Therefore,it is one of the most important parts in unconventional oil and gas reservoir exploration.Eastern Sichuan area is located     

Fluid unmixing/immiscibility as an ore-forming process in the giant REE–Nb–Fe deposit, Inner Mongolian, China: Evidence from fluid inclusions

The giant Bayan Obo REE–Nb–Fe deposit consists of replacement bodies hosted in dolomite marble made up of magnetite, REE fluorocarbonates, fluorite, aegirine, amphibole, calcite and barite. Two or three phase CO₂-rich, three phase hypersaline liquid–vapor–solid, and two phase liquid-rich inclusions have been recognized in mineralized fluorite and quartz samples. Microthermometry measurements indicate that the carbonic phase in CO₂-rich inclusions is nearly pure CO₂. Fluids involving in REE–Nb–Fe mineralization at Bayan Obo might be mainly of H₂O–CO₂–NaCl–(F–REE) system. Coexistences of brine inclusions and CO₂-rich inclusions with similar homogenization temperatures give evidence that immiscibility happened during REE mineralization. An unmixing of an original H₂O–CO₂–NaCl fluid probably derived from carbonatitic magma. The presence of REE-carbonates as an abundant solid in fluid inclusions shows that the original ore-forming fluids are very rich in REE, and therefore, have the potential to produce economic REE ores at Bayan Obo.     

耕作措施对陕西耕作土壤碳储量的影响模拟*

鉴于农业生态系统土壤有机碳(SOC)平衡对中国农业可持续发展的重要性,文章以陕西农业生态系统为对象,整合农业生物地球化学模型(DNDC)与陕西农业地理信息系统数据库,利用陕西地区气象和作物资料,对陕西省2000年作物生长发育和土壤碳循环进行了模型模拟,实例探讨了耕作管理对土壤碳储量的影响,并由此评价生物地球化学模型在气候变化、土壤性质及农业耕作管理措施对土壤碳含量影响方面的预测能力。敏感性分析表明土壤性状,尤其是初始有机碳含量是影响模型区域尺度模拟的最主要敏感因素。区域模拟使用灵敏系数分析法,分别采用敏感因子的最大、最小值驱动模型在每一模拟单元内的运算,以产生一个土壤有机碳变化的范围值,土壤有机碳变化的真实值应以较大机率包含在这一范围内。分析模拟结果可以得出3点结论: 1)2000年陕西耕作土壤总有机碳储量约为103TgC,是一个大气CO₂源,向大气释放碳0.5TgC; 2)提高作物秸秆还田率是提高陕西农田碳库储量的有效可行措施,将作物秸秆还田率从当前的15 ％ 提高到50 ％ 或90 ％ 会使陕西农田土壤从大气CO₂源转变为汇,每年分别增加土壤有机碳库储量0.7TgC或2.1TgC; 3)施用有机农肥(500kg/hm²)也会增加土壤碳输入,从而提高土壤碳储量,使陕西农田系统转变为较弱的碳(C)源,每年可多固定0.2TgC。     

西太平洋暖池近3万年来的沉积序列及其环境特征-WP92-3柱样的REE记录

WP92-3柱样采自西太平洋暖池核心区。利用稀土元素(REE)特征参数研究了该柱样的沉积物来源和地层序列划分,并对其所揭示的环境变化特征进行了探讨。研究认为:样品的REE分布模式揭示了该海域的沉积物源主要为海相自生沉积;基于REE指标的垂向深度变化特征可将该柱样划分为3个地层序列;∑REE,LREE/HREE和δCe几个指标对环境的温度变化以及地磁场的极性变换均有良好的响应,∑REE高值段基本对应于δ18O和SST所揭示的暖池低温期,而地磁场极性转变的时间正好对应着稀土指标(∑REE,LREE/HREE和δCe)快速大幅波动的层位。REE特征参数较好地记录了暖池区近3万年来的沉积和环境变化信息,是一组对气候环境演化具有潜在良好指示作用的地球化学指标。     

Carbon and oxygen isotopic constraints on paleoclimate and paleoelevation of the southwestern Qaidam basin,northern Tibetan Plateau

We investigate the growth of the northern Tibetan Plateau and associated climate change by applying oxygen and carbon isotopic compositions in Cenozoic strata in the southwestern Qaidam basin. The X-ray diffraction and isotopic studies reveal that the carbonate minerals are mainly authigenic and they do not preserve any evidence for detrital carbonate and diagenesis. The isotope data show large fluctuations in the δ¹⁸O and δ¹³C values in the middle–late Eocene, indicating relatively warm and seasonal dry climate. The positive correlation of the δ¹⁸O and δ¹³C values in the Oligocene and the positive shift of the δ¹³C values from the Eocene to Oligocene suggest that the climate changed to arid in the Oligocene. However, the δ¹⁸O values show negative shift, which is closely related to the global cooling event. During the Miocene, the δ¹³C values vary between –2‰ and –4‰, whereas the δ¹⁸O values show continuous negative shift. The mean δ¹⁸O values decrease from –8.5‰ in the early Miocene to –10.0‰ in the late Miocene. The stable isotope-based paleoaltimetry results suggest that the elevation of the southwestern Qaidam basin was approximately 1500 m in the middle–late Eocene and Oligocene. Subsequently, during Miocene the crustal uplift process started and the elevation reached approximately 2000 m in the early Miocene and 2500 m in the late Miocene, which suggests large-scale growth of the northern Tibet Plateau during the Miocene.     

渤海湾北岸TZ02孔晚新生代沉积环境演化过程

渤海湾北岸晚新生代沉积环境和沉积体系不仅是区域水文地质、工程地质的基础,也为古近纪沉积模式提供“将今论古”的依据。本文依据沉积物色度和粒度,以及沉积物岩性、结构和构造等,将渤海湾北岸TZ02孔划分了6个沉积组合、4个沉积阶段：1）2.10~3.22Ma,沉积组合Ⅰ和Ⅱ,湖盆填充期,发育湖相-泛滥平原相或湖相-曲流河相,该时期处于构造稳定期,干冷气候时期发育河流相、泛滥平原相,湿润气候时期发育湖泊相。2）1.33~2.10Ma,沉积组合Ⅲ,湖盆开始发育期,主要为浅湖相,仅有少量砂体,下部多有机质,上部多钙质淀积结核,指示了盆山之间的构造分异后,湖泊初始发育的特征。3）0.62~1.33Ma,沉积组合Ⅳ,湖盆扩张期,以湖相为主,多砂体,且有短期湖泊水位变浅和成陆过程;指示了盆山构造分异后,盆地加速沉降,湖盆扩张;山体隆起、河流下切,盆地中湖相砂体增多;此时TZ02孔附近为湖相中心,BG10孔为湖泊边缘。4）0~0.62Ma,沉积组合Ⅴ和Ⅵ,湖泊填充期,BG10孔为湖相的沉积中心,而TZ02孔为湖泊的边缘,接受滦河迁移摆动后的沉积物;中更新世后,构造沉降形成湖相,而间冰期发育海相,埋深0~22.5m的海相-河流相更直接地反映了末次冰消期海平面变化过程。

     

滑坡灾害环境与山区建设的和谐

滑坡是浙江省沿海及丘陵山区频发的地质灾害之一,常堵塞交通、农田毁损、民房倒塌、使山区人民生活环境严重恶化。分析滑坡灾害机理,提早预警预报,是合理规划山区民居建设、治理地质灾害、建立民居与生态环境合谐的的关系,是各级政府、地质工程界、建设部门和环境监理部门的重要社会责任和理论研究范围。     

利用地震层析成象技术确定横向非均匀介质中的速度分布和界面位置

本文提出一种横向非均匀介质中的地震层析成象方法，由地震走时资料确定介质的速度分布和界面位置。计算中采用了参数分离、变阻尼、奇异值分解等技术，方程的解较稳定，且可得到解的分办。除反射波外，该方法还可同时利用分析波的资料。因此，适宜于折射及宽角度反射地震测深剖面的资料处理。数字试验结果表明，在模型内部，该方法能得到可靠的反演结果。在边界附近效果较差，受初始值影响较大。