Shock metamorphism of quartz at the submarine Mjølnir impact crater,Barents Sea

Abstract— Shock metamorphosed quartz grains have been discovered in a drill core from the central peak of the Late Jurassic, marine Mjølnir structure; this finding further corroborates the impact origin of Mjølnir. The intersected strata represent the Upper Jurassic Hekkingen Formation and underlying Jurassic and Upper Triassic formations. The appearance, orientation, and origin of shock features in quartz grains and their stratigraphic distribution within the core units have been studied by optical and transmission electron microscopy. The quartz grains contain planar fractures (PFs), planar deformation features (PDFs), and mechanical Brazil twins. The formation of PFs is the predominant shock effect and is attributed to the large impedance differences between the water‐rich pores and constituent minerals in target sediments. This situation may have strengthened tensional/extensional and shear movements during shock compression and decompression. The combination of various shock effects indicates possible shock pressures between 5 and at least 20 GPa for three core units with a total thickness of 86 m (from 74.00 m to 171.09 m core depth). Crater‐fill material from the lower part of the core typically shows the least pressures, whereas the uppermost part of the allochthonous crater deposits displays the highest pressures. The orientations of PFs in studied quartz grains seem to become more diverse as the pressure rises from predominantly (0001) PFs to a combination of (0001), , and orientations. However, the lack of experimental data on porous sedimentary rocks does not allow us to further constrain the shock conditions on the basis of PF orientations.     

Microstructure,composition and P–T conditions of rutile from diamondiferous gneiss of the Saxonian Erzgebirge,Germany

The chemical composition and microstructure of rutile grains in a ultra-high pressure metamorphic gneiss of the Saxonian Erzgebirge, Germany have been studied by Raman spectroscopy, SEM, EMPA and TEM. Rutile inclusions in garnet contain free dislocations, iron-enriched dislocations and exsolved ilmenite lamellae, while subgrain boundaries are observed in rutile grains of the rock matrix. The previously reported α-PbO₂ type TiO₂ phase could not be confirmed by our TEM observations. On the basis of Zr solubility in the rutile and the presence of microdiamonds, minimum metamorphic peak conditions of 3.95 GPa and 915 °C are estimated.     

Wüstite in the fusion crust of Almahata Sitta sulfide‐metal assemblage MS‐166: Evidence for oxygen in metallic melts

Meteorite fusion crusts form during the passage of a meteoroid through the Earth's atmosphere and are highly oxidized intergrowths as documented by the presence of e.g., oxides. The porous and irregular fusion crust surrounding the Almahata Sitta sulfide‐metal assemblage MS‐166 was found highly enriched in wüstite (Fe_1‐xO). Frictional heating of the outer portions of the assemblage caused partial melting of predominantly the Fe‐sulfide and minor amounts of the outer Ni‐rich portions of the originally zoned metal in MS‐166. Along with melting significant amounts of oxygen were incorporated into the molten fusion crust and mainly FeS was oxidized and desulfurized to form wüstite. Considerable amounts of FeS were lost due to ablation, whereas the cores of the large metal grains appear largely unmelted leaving behind metal grains and surrounding wüstite‐rich material (matte). Metal grains along with the surrounding matte typically form an often highly porous framework of globules interconnected with the matte. Although textures and chemical composition suggest that melting of Fe,Ni metal occurred only partially (Ni‐rich rims), there is a trace elemental imprint of siderophile element partitioning influenced by oxygen in the metallic melt as indicated by the behavior of W and Ga, the two elements significantly affected by oxygen in a metallic melt. It is remarkable that MS‐166 survived the atmospheric passage as troilite inclusions in iron meteorites are preferentially destroyed.     

Response of Pediastrum in German floodplain lakes to Late Glacial climate changes

Subfossil remains of the Pediastrum-algae group (Fam. Hydrodictyaceae) are frequently found in lake sediments, but very few studies have used them as palaeoclimate and palaeolimnological indicators. This study explored the species composition of Pediastrum assemblages in shallow floodplain lakes in northern Germany during two transitional periods from cold to temperate climate conditions (GS-2/GI-1 and GI-1/Holocene). We identified Pediastrum taxa to subspecies level and used multivariate statistics (constrained clustering, principal component analysis and redundancy analysis) to show that shifts in taxonomic composition reflected the strong Late Glacial climate oscillations. The Pediastrum assemblages indicate that climate amelioration already begun shortly before the main GS-2/GI-1 summer-temperature transition. In contrast to previous studies that identified trophic state as the main driver of change in Pediastrum species composition, we identified climate shifts and related factors as the major drivers of community change. Water depth and trophic state probably acted as secondary factors that were responsible for differences in Pediastrum response between the first and second investigated climate transitions. During cold periods, Pediastrum algae composition was controlled mainly by environmental variables, whereas during warm periods, Pediastrum assemblages may have been influenced to a greater extent by intra- and intergeneric competition. This study contributes to knowledge about ecological niches of Pediastrum species. Size-measurements on Pediastrum coenobia reveal that one response of Pediastrum algae to climate shifts probably was size change. Coenobia of Pseudopediastrum boryanum var. boryanum were significantly smaller during cold climate periods than during temperate periods. The shifts in Pediastrum species composition and coenobium size suggest this algae group has great potential for enabling palaeoecological and palaeoclimate inferences.     

Pyroxenes microstructure in comet 81P/Wild 2 terminal Stardust particles

Abstract— We report the examination by transmission electron microscopy (TEM) of four Stardust terminal particles extracted from two neighboring tracks (32 an 69). The particles are made of well‐preserved crystalline grains dominated by low‐Ca pyroxene ranging from nearly pure enstatite to pigeonite. Some olivine grains are also found, in chemical equilibrium with the surrounding pyroxenes. Various microstructures are observed, as a function of the composition of the grains. They include (100)‐twinned pigeonite, clino/ortho domains in enstatite and exsolution in a Ca‐rich grain. The microstructures are mostly consistent with a formation by cooling from high‐temperature phases, which could be associated to igneous processes. Some dislocations in glide configuration are also present, probably attesting for small intensity shocks. Possible effects of the rapid heating/cooling stage and thermal shock associated to the collect are discussed. It appears that most of the microstructural features reported here are plausibly pristine.     

Localized shock-induced melting of sandstone at low shock pressures (<17.5 GPa): An experimental study

Shock-induced recovery experiments were performed to investigate melt formation in porous sandstones in the low shock pressure regime between 2.5 and 17.5 GPa. The sandstone shocked at 2.5 and 5 GPa is characterized by pore closure, fracturing of quartz (Qtz), and compression and deformation of phyllosilicates; no melting was observed. At higher pressures, five different types of melts were generated around pores and alongside fractures in the sandstone. Melting of kaolinite (Kln), illite (Ill), and muscovite (Ms) starts at 7.5, 12, and 15 GPa, respectively. The larger the amount of water in these minerals (Kln ~14 wt%, Ill ~6–10 wt%, and Ms ~4 wt% H₂O), the higher the shock compressibility and the lower the shock pressure required to induce melting. Vesicles in the almost dry silicate glasses attest to the loss of structural water during the short shock duration of the experiment. The compositions of the phyllosilicate-based glasses are identical to the composition of the parental minerals or their mixtures. Thus, this study has demonstrated that phyllosilicates in shocked sandstone undergo congruent melting during shock loading. In experiments at 10 GPa and higher, iron melt from the driver plate was injected into the phyllosilicate melts. During this process, Fe is partitioned from the metal droplets into the surrounding silicate melts, which induced unmixing of silicate melts with different chemical properties (liquid immiscibility). At pressures between 7.5 and 15 GPa, a pure SiO₂ glass was formed, which is located as short and thin bands within Qtz grains. These bands were shown to contain tiny crystals of experimentally generated stishovite.