High-pressure behaviour along the jadeite NaAlSi2O6–aegirine NaFeSi2O6 solid solution up to 10 GPa

The volume variation as a function of pressure along the jadeite–aegirine solid solution was determined at room temperature up to pressures between 6.5 and 9.7 GPa by single-crystal X-ray diffraction. The unit-cell volumes collected at room pressure for the different compositions indicate a slight deviation from linearity along the join. The pressure–volume data have been fitted using a third-order Birch-Murnaghan equation of state (BM3-EoS). The bulk modulus, K _T0, varies from 134.0(7) GPa for pure jadeite to 116.1(5) GPa for pure aegirine. Its evolution with composition along the join is not linear and can be described by the following second order polynomial:

On the nature of the z=0 X-ray absorbers: I. Clues from an external group

We describe the main features of the evolutionary code ATON 3.1 and its latest version, particularly deviced to be apt for follow up asteroseismology applications. An older version of the code including rotational evolution is also shortly described.     

Properties of dusty tori in active galactic nuclei – I. The case of SWIRE/SDSS quasars

We derive the properties of dusty tori in active galactic nuclei from the comparison of observed spectral energy distributions (SEDs) of SDSS quasars and a precomputed grid of torus models. The observed SEDs comprise SDSS photometry, Two-Micron All-Sky Survey J , H and K data, whenever available, and mid-infrared (mid-IR) data from the Spitzer Wide-area InfraRed Extragalactic Survey. The adopted model is that of Fritz, Franceschini & Hatziminaoglou. The fit is performed by standard  χ²  -minimization; the model, however, can be a multicomponent comprising a stellar and a starburst component, whenever necessary. Models with low equatorial optical depth, τ_9.7, were allowed as well as 'traditional' models with  τ_9.7≥ 1.0  , corresponding to   A _V≥ 22  and the results were compared. Fits using high optical depth tori models only produced dust more compactly distributed than in the configuration where all τ_9.7 models were permitted. Tori with decreasing dust density with the distance from the centre were favoured while there was no clear preference for models with or without angular variation of the dust density. The computed outer radii of the tori are of some tens of parsecs large but can reach, in a few cases, a few hundreds of parsecs. The mass of dust, M _Dust, and IR luminosity, L _IR, integrated in the wavelength range between 1 and 1000 μm, do not show significant variations with redshift, once the observational biases are taken into account. Objects with 70-μm detections, representing 25 per cent of the sample, are studied separately and the starburst contribution (whenever present) to the IR luminosity can reach, in the most extreme but very few cases, 80 per cent.     

Interplay of S and As in Mekong Delta sediments during redox oscillations

The cumulative effects of periodic redox cycling on the mobility of As,Fe,and S from alluvial sediment to groundwater were investigated in bioreactor experiments.Two particular sediments from the alluvial floodplain of the Mekong Delta River were investigated:Matrix A(14 m deep)had a higher pyrite concentration than matrix B(7 m deep)sediments.Gypsum was present in matrix B but absent in matrix A.In the reactors,the sediment suspensions were supplemented with As(Ⅲ)and SO_4~(2-),and were subjected to three full-redox cycles entailing phases of nitrogen/CO_2,compressed air sparging,and cellobiose addition.Major differences in As concentration and speciation were observed upon redox cycling.Evidences support the fact that initial sediment composition is the main factor controlling arsenic release and its speciation during the redox cycles.Indeed,a high pyrite content associated with a low SO_4~(2-)content resulted in an increase in dissolved As concentrations,mainly in the form of As(Ⅲ),after anoxic half-cycles;whereas a decrease in As concentrations mainly in the form of As(Ⅴ),was instead observed after oxic half-cycles.In addition,oxic conditions were found to be responsible for pyrite and arsenian pyrite oxidation,increasing the As pool available for mobilization.The same processes seem to occur in sediment with the presence of gypsum,but,in this case,dissolved As were sequestered by biotic or abiotic redox reactions occurring in the Fe—S system,and by specific physico-chemical condition(e.g.pH).The contrasting results obtained for two sediments sampled from the same core show that many complexes and entangled factors are at work,and further refinement is needed to explain the spatial and temporal variability of As release to groundwater of the Mekong River Delta(Vietnam).     

Catchment properties,function, and conceptual model representation: is there a correspondence?

This study investigates the possible correspondence between catchment structure, as represented by perceptual hydrological models developed from fieldwork investigations, and mathematical model structures, selected on the basis of reproducing observed catchment hydrographs. Three Luxembourgish headwater catchments are considered, where previous fieldwork suggested distinct flow‐generating mechanisms and hydrological dynamics. A set of lumped conceptual model structures are hypothesized and implemented using the SUPERFLEX framework. Following parameter calibration, the model performance is examined in terms of predictive accuracy, quantification of uncertainty, and the ability to reproduce the flow–duration curve signature. Our key research question is whether differences in the performance of the conceptual model structures can be interpreted based on the dominant catchment processes suggested from fieldwork investigations. For example, we propose that the permeable bedrock and the presence of multiple aquifers in the Huewelerbach catchment may explain the superior performance of model structures with storage elements connected in parallel. Conversely, model structures with serial connections perform better in the Weierbach and Wollefsbach catchments, which are characterized by impermeable bedrock and dominated by lateral flow. The presence of threshold dynamics in the Weierbach and Wollefsbach catchments may favour nonlinear models, while the smoother dynamics of the larger Huewelerbach catchment were suitably reproduced by linear models. It is also shown how hydrologically distinct processes can be effectively described by the same mathematical model components. Major research questions are reviewed, including the correspondence between hydrological processes at different levels of scale and how best to synthesize the experimentalist's and modeller's perspectives. Copyright © 2013 John Wiley & Sons, Ltd.     

1D velocity structure of the Po River plain (Northern Italy) assessed by combining strong motion and ambient noise data

Strong ground motions recorded on the sedimentary deposits of the Po River alluvial plain during the Emilia (Northern Italy) Mw 5.7 earthquake of May 29, 2012 are used to assess the vertical profile of shear-wave velocity above the limestone basement. Data were collected by a linear array installed for site effect studies after the Mw 5.9 mainshock of May 20, 2012. The array stations, equipped with both strong and weak motion sensors, are aligned in the South–North direction, at distances ranging from 1 to 26 km from the epicenter. The vertical components of ground motion show very distinctive, large-amplitude, low-frequency dispersive wave trains. Wavelet analysis yields group-velocity dispersion curve in the 0.2–0.7 Hz frequency band. The availability of a long ambient noise record allows estimates of the site resonance frequency along with its stability among stations. The joint inversion of dispersion of surface waves and ellipticity curves derived from ambient noise H/V allows extending investigations down to the sediment-limestone interface, at a depth of about 5,000 m. Our results add new information about the velocity structure at a scale that is intermediate between the local scale already investigated by other authors with small-aperture arrays using ambient noise and the regional scale inferred from modeling of seismogram waveforms recorded at hundreds of kilometers from the source.     

Estimation procedures for exchangeable Marshall copulas with hydrological application

Complex phenomena in environmental sciences can be conveniently represented by several inter-dependent random variables. In order to describe such situations, copula-based models have been studied during the last year. In this paper, we consider a novel family of bivariate copulas, called exchangeable Marshall copulas. Such copulas describe both positive and (upper) tail association between random variables. Specifically, inference procedures for the family of exchangeable Marshall copulas are introduced, based on the estimation of their (univariate) generator. Moreover, the performance of the proposed methodologies is shown in a simulation study. Finally, an illustration describes how the proposed procedures can be useful in a hydrological application.     

Seismic fragility of reinforced concrete girder bridges using Bayesian belief network

Infrastructure owners and operators, or governmental agencies, need rapid screening tools to prioritize detailed risk assessment and retrofit resources allocation. This paper provides one such tool, for use by highway administrations, based on Bayesian belief network (BBN) and aimed at replacing so‐called generic or typological seismic fragility functions for reinforced concrete girder bridges. Resources for detailed assessments should be allocated to bridges with highest consequence of damage, for which site hazard, bridge fragility, and traffic data are needed. The proposed BBN based model is used to quantify seismic fragility of bridges based on data that can be obtained by visual inspection and engineering drawings. Results show that the predicted fragilities are of sufficient accuracy for establishing relative ranking and prioritizing. While the actual data and seismic hazard employed to train the network (establishing conditional probability tables) refer to the Italian bridge stock, the network structure and engineering judgment can easily be adopted for bridges in different geographical locations. Copyright © 2015 John Wiley & Sons, Ltd.