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21.
Günther J. Redhammer Fernando Cámara Matteo Alvaro Fabrizio Nestola Gerold Tippelt Sebastian Prinz Jan Simons Georg Roth Georg Amthauer 《Physics and Chemistry of Minerals》2010,37(10):685-704
A synthetic clinopyroxene with composition LiFe3+Ge2O6, monoclinic s.g. P21/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) Å, β = 108.844(6)°, V = 442.75(16) Å3, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P21/c to C2/c at a transition temperature T tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T tr the thermal volume expansion is due to dilatation of the structure in the $(\bar{1}\,0\,1) A synthetic clinopyroxene with composition LiFe3+Ge2O6, monoclinic s.g. P21/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) ?, β = 108.844(6)°, V = 442.75(16) ?3, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters
and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P21/c to C2/c at a transition temperature T
tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds
to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T
tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T
tr the thermal volume expansion is due to dilatation of the structure in the ([`1] 0 1)(\bar{1}\,0\,1) plane, mostly along [0 1 0], and pure shear in the (0 1 0) plane due to the decrease of β. From comparison with silicate analogues, the germanate clinopyroxenes are more expansible, while the P21/c expands more than the C2/c phase. The evolution of Q
2 (calculated as the normalized intensity of b-type reflections) with T in the framework of the Landau theory has been done using a standard expression for a first order phase transition. We observe
a jump of Q
02 = 0.538(2) at T
tr, with T
c of 481(7) K, b/a = −2,290 K, and c/a = 3,192 K, and thus far from being tri-critical point. A closely related composition (LiFe3+Si2O6) shows an equivalent phase transition at 228 K, which is very close to the tri-critical point and 561 K cooler. This result
indicates that a change in the composition of tetrahedral sites can have dramatic effects on the P21/c ↔ C2/c displacive phase transition in clinopyroxenes. The major changes observed in the evolution of the crystal structure with
T are observed in the M2 polyhedron, with a volume decrease by ca. 13.3%, compared to ca. 1.3% observed in the M1 polyhedron.
The tetrahedra behave as rigid units with neither a significant change of volume at T > T
tr (<1‰), nor a change of tilting of the basal plane. No change in coordination is observed at T > T
tr in the M2 polyhedron, which remains sixfold coordinated although a strong deformation of this polyhedron is observed. This
deformation is related to a strong change by 51.4° at T
tr of the kinking angle (O3–O3–O3 angle) of the B-chain of tetrahedra, which switches from O-rotated to S-rotated [from 143.3(5)°
to 194.7(6)°]. The A-chain is S-rotated at T < T
tr [206.8(5)° at 703 K] and extends by 12° at the transition. 相似文献
22.
Roberto Cossu Monique Petitdidier Julian Linford Vincent Badoux Luigi Fusco Benoit Gotab Ladislav Hluchy Giuditta Lecca Fabrizio Murgia Camiel Plevier Philippe Renard Horst Schwichtenberg Wim Som de Cerff Viet Tran Gerald Vetois 《Earth Science Informatics》2010,3(3):135-148
Due to its intensive data processing and highly distributed organization, the multidisciplinary Earth Science applications community is uniquely positioned for the uptake and exploitation of Grid technologies. Currently Enabling Grids for E-sciencE, and other large Grid infrastructures are already deployed and capable of operational services. So far however, the adoption and exploitation of Grid technology throughout the Earth Science community has been slower than expected. The Dissemination and Exploitation of GRids in Earth sciencE project, proposed by the European Commission to assist and accelerate this process in a number of different ways, had between its main goals the creation of a roadmap towards Earth Science Grid platform. This paper presents the resulting roadmap. 相似文献
23.
Recent Chandra and XMM-Newton surveys have uncovered a large fraction of the obscured AGN responsible of the hard X-ray background. One of the most intriguing
results of extensive programs of follow-up observations concerns the optical and near-infrared properties of the hard X-ray
sources counterparts. More specifically, for a significant fraction of hard X-ray obscured sources the AGN responsible of
the high X-ray luminosity remains elusive over a wide range of wavelengths from soft X-rays to near-infrared. This very observational
result opens the possibility to investigate the host of bright obscured quasars in some detail. Here we briefly report on
some preliminar results obtained for a small sample of elusive AGN in the HELLAS2XMM survey. 相似文献
24.
M. Vaccari C. Lari L. Angeretti D. Fadda C. Gruppioni F. Pozzi O. Prouton H. Aussel T. Babbedge P. Ciliegi A. Franceschini E. Gonzalez-Solares F. La Franca S. Oliver I. Perez-Fournon M. Rowan-Robinson S. Serjeant P. Väisänen 《Monthly notices of the Royal Astronomical Society》2005,358(2):397-418
We present the final analysis of the European Large Area Infrared Space Observatory ( ISO ) Survey (ELAIS) 15-μm observations, carried out with the ISO Camera (ISOCAM) instrument on board the ISO .
The data-reduction method, known as the Lari Method, is based on a mathematical model of the behaviour of the detector and was specifically designed for the detection of faint sources in ISOCAM/ISO Photopolarimeter (ISOPHOT) data. The method is fully interactive and leads to very reliable and complete source lists.
The resulting catalogue includes 1923 sources detected with signal-to-noise ratio of > 5 in the 0.5–100 mJy flux range and over an area of 10.85 deg2 split into four fields, making it the largest non-serendipitous extragalactic source catalogue obtained to date from the ISO data.
This paper presents the concepts underlying the data-reduction method together with its latest enhancements. The data-reduction process, the production and basic properties of the resulting catalogue are discussed. The catalogue quality is assessed by means of detailed simulations, optical identifications and comparison with previous analyses. 相似文献
The data-reduction method, known as the Lari Method, is based on a mathematical model of the behaviour of the detector and was specifically designed for the detection of faint sources in ISOCAM/ISO Photopolarimeter (ISOPHOT) data. The method is fully interactive and leads to very reliable and complete source lists.
The resulting catalogue includes 1923 sources detected with signal-to-noise ratio of > 5 in the 0.5–100 mJy flux range and over an area of 10.85 deg
This paper presents the concepts underlying the data-reduction method together with its latest enhancements. The data-reduction process, the production and basic properties of the resulting catalogue are discussed. The catalogue quality is assessed by means of detailed simulations, optical identifications and comparison with previous analyses. 相似文献
25.
F. Frontera A. Pisa G. Loffredo D. Pellicciotta V. Carassiti F. Evangelisti K. Andersen P. Courtois L. Amati E. Caroli T. Franceschini G. Landini S. Silvestri J. Stephen 《Experimental Astronomy》2005,20(1-3):241-251
A review of the HAXTEL project devoted to the development of a Laue lens telescope for hard X-/gamma-ray observation of the continuum spectra of celestial sources is presented. Main design properties, open issues, the status of the project and an example of multi-lens configuration with sensitivity expectations are discussed. 相似文献
26.
Marco Micheli Detlef Koschny Gerhard Drolshagen Olivier Hainaut Fabrizio Bernardi 《Earth, Moon, and Planets》2014,113(1-4):1-13
In this work we summarize the initial results of a targeted effort of the ESA NEO Coordination Centre to obtain additional observational data in order to eliminate or reduce the impact probability estimate of a subset of the known near-Earth objects representing the highest fraction of the total known impact risk, as measured by the Palermo Scale. 相似文献
27.
T. S. R. Babbedge M. Rowan-Robinson M. Vaccari J. A. Surace C. J. Lonsdale D. L. Clements F. Fang D. Farrah A. Franceschini E. Gonzalez-Solares E. Hatziminaoglou C. G. Lacey S. Oliver N. Onyett I. Pérez-Fournon M. Polletta F. Pozzi G. Rodighiero D. L. Shupe B. Siana H. E. Smith 《Monthly notices of the Royal Astronomical Society》2006,370(3):1159-1180
28.
E. Hatziminaoglou P. Cassata G. Rodighiero I. Pérez-Fournon A. Franceschini A. Hernán-Caballero F. M. Montenegro-Montes A. Afonso-Luis T. Jarrett G. Stacey C. Lonsdale F. Fang S. Oliver M. Rowan-Robinson D. Shupe H. E. Smith J. Surace C. K. Xu E. A. González-Solares 《Monthly notices of the Royal Astronomical Society》2005,364(1):47-58
29.
Boron isotope data are presented for Cenozoic Western Anatolia rocks, which define two main associations: (i) calc-alkaline, shoshonitic and ultra-potassic rocks (Early to Middle Miocene); and (ii) Late Miocene–Quaternary intraplate alkali basalts. Boron data, together with Sr–Nd isotope and other trace elements, are consistent with a progressive dehydration of the slab, producing fluid phases gradually depleted in B (and 11B). These fluids were added to the supraslab mantle, triggering a partial melting that gave rise to orogenic magmatism. The stretching and tearing of the slab caused by the faster convergence of Greece over Africa with respect to Anatolia facilitated an interaction of the upwelling subslab asthenosphere with residual slab-fluids during the Late Miocene followed by production of typical intraplate magmas during the Pleistocene–Holocene, whose relatively high δ11B (approximately −2‰) is considered representative of the local asthenosphere not affected by subduction contamination. 相似文献
30.