Distribution and population structure of deep‐dwelling red coral in the Northwest Mediterranean

Commercially harvested since ancient times, the highly valuable red coral Corallium rubrum (Linnaeus, 1758) is an octocoral endemic to the Mediterranean Sea and adjacent Eastern Atlantic Ocean, where it occurs on rocky bottoms over a wide bathymetric range. Current knowledge is restricted to its shallow populations (15–50 m depth), with comparably little attention given to the deeper populations (50–200 m) that are nowadays the main target of exploitation. In this study, red coral distribution and population structure were assessed in three historically exploited areas (Amalfi, Ischia Island and Elba Island) in the Tyrrhenian Sea (Western Mediterranean Sea) between 50 and 130 m depth by means of ROV during a cruise carried out in the summer of 2010. Red coral populations showed a maximum patch frequency of 0.20 ± 0.04 SD patches·m^?1 and a density ranging between 28 and 204 colonies·m^?2, with a fairly continuous bathymetric distribution. The highest red coral densities in the investigated areas were found on cliffs and boulders mainly exposed to the east, at the greatest depth, and characterized by medium percentage sediment cover. The study populations contained a high percentage (46% on average) of harvestable colonies (>7 mm basal diameter). Moreover, some colonies with fifth‐order branches were also observed, highlighting the probable older age of some components of these populations. The Ischia population showed the highest colony occupancy, density and size, suggesting a better conservation status than the populations at the other study locations. These results indicate that deep dwelling red coral populations in non‐stressed or less‐harvested areas may diverge from the inverse size‐density relationship previously observed in red coral populations with increasing depth.     

Evaluation of the influence of experimental conditions on H/V results from ambient noise recordings

The H/V-noise technique is now widely used to estimate site effect parameters (fundamental frequency and sometimes the associated soil amplification), and many surveys using this technique have provided convincing results. However, a general agreement on a methodology for data acquisition, data processing and result interpretation has yet to be found. H/V measurements from ambient noise recordings imply both reliability of the results and rapidity of data collection. It is therefore important to understand which experimental conditions (1) influence data quality and reliability, and (2) can help speeding up the recording process. Within the framework of the SESAME European project, a specific task was defined to investigate the reliability of the H/V spectral ratio technique in assessing the site effects. The aim of WP02, one specific Work Package of the SESAME project, is to study the effects of experimental conditions on both stability and reproducibility of H/V results. This study has been conducted in a purely experimental way, by testing the possible influence of various experimental conditions on H/V results both on the frequency peak value and on its amplitude. WP02 results help setting up the experimental conditions under which ambient noise recordings have to be performed in order to provide reproducible, reliable and meaningful H/V results. In this paper we present the results of the WP02 SESAME project concerning the evaluation of the influence of experimental conditions of ambient noise recording on H/V results.     

Deriving vulnerability curves using Italian earthquake damage data

The concerted effort to collect earthquake damage data in Italy over the past 30 years has led to the development of an extensive database from which vulnerability predictions for the Italian building stock can be derived. A methodology to derive empirical vulnerability curves with the aforementioned data is presented herein and the resulting curves have been directly compared with mechanics-based vulnerability curves. However, it has been found that a valid comparison between the empirical and analytical vulnerability curves is not possible mainly due to a number of shortcomings in the database of surveyed buildings. A detailed discussion of the difficulties in deriving vulnerability curves from the current observed damage database is thus also presented.     

Natural Cr(VI) contamination of groundwater in the Cecina coastal area and its inner sectors (Tuscany,Italy)

A detailed hydrogeochemical study of groundwater in the Cecina coastal plain (Livorno province, Italy) and its inner sectors was undertaken in 2008, as chemical analyses carried out on groundwater since 2006 have revealed Cr(VI) concentrations of up to 49 μg/L (well above the permissible limit of 5 μg/L). Ophiolite outcrops are present throughout the study area, and their fragments likely represent a significant portion of the existing multilayered aquifer skeleton. Waters delivered by the serpentinite outcrops have a typically Mg–HCO₃ composition, whereas those of the coastal plain are prevailingly of the Ca/Mg–HCO₃ type with significant Mg contents. Significant NO₃ contamination characterises the studied coastal plain, and an interesting negative correlation exists between Cr(VI) and both NO₃ and SO₄ deriving from the widespread use of (NH₄)₂SO₄ as a farm fertilizer. Chromium speciation calculations carried out using the EQ3NR code reveal that the prevailing Cr(VI) species in solution is CrO₄ ^2?; however, CaCrO₄° and MgCrO₄° neutral complexes represent significant percentages (up to 42 %). These findings suggest that the mobility and consequently the bioavailability of Cr(VI) can be significantly enhanced by these neutral complexes, which are not considered to be affected by adsorption/desorption processes. The Cr(VI) source, investigated by means of the Mg/SiO₂ molar ratio, seems to be represented mainly by Mg-bearing minerals of the chlorite group. Petrographic observations confirm the occurrence of this mineral group. The interaction between rainwater and the local serpentinite rock was simulated at different $P_{{{\text{CO}}_{ 2} }}$ and $P_{{{\text{O}}_{ 2} }}$ conditions by reaction path modelling using the EQ3/6 software package. $P_{{{\text{O}}_{ 2} }}$ was varied in accordance with the assumption that redox conditions are determined in part by NO₃. Results are in good agreement with experimental data on spring waters and subordinately with data on some coastal plain groundwater, which plot in a rather wide $P_{{{\text{CO}}_{ 2} }}$ and $P_{{{\text{O}}_{ 2} }}$ field. Although the dissolved Cr content is mostly of natural origin, fertilization may affect its fate.     

Antigorite equation of state and anomalous softening at 6 GPa: an in situ single-crystal X-ray diffraction study

The compressibility of antigorite has been determined up to 8.826(8) GPa, for the first time by single crystal X-ray diffraction in a diamond anvil cell, on a specimen from Cerro del Almirez. Fifteen pressure–volume data, up to 5.910(6) GPa, have been fit by a third-order Birch–Murnaghan equation of state, yielding V ₀ = 2,914.07(23) Å³, K _T0 = 62.9(4) GPa, with K′ = 6.1(2). The compression of antigorite is very anisotropic with axial compressibilities in the ratio 1.11:1.00:3.22 along a, b and c, respectively. The new equation of state leads to an estimation of the upper stability limit of antigorite that is intermediate with respect to existing values, and in better agreement with experiments. At pressures in excess of 6 GPa antigorite displays a significant volume softening that may be relevant for very cold subducting slabs.     

Effects of interplanetary dust on the LISA drag-free constellation

The analysis of non-radiative sources of static or time-dependent gravitational fields in the Solar System is crucial to accurately estimate the free-fall orbits of the LISA space mission. In particular, we take into account the gravitational effects of Interplanetary Dust (ID) on the spacecraft trajectories. The perturbing gravitational field has been calculated for some ID density distributions that fit the observed zodiacal light. Then we integrated the Gauss planetary equations to get the deviations from the LISA Keplerian orbits around the Sun. This analysis can be eventually extended to Local Dark Matter (LDM), as gravitational fields are expected to be similar for ID and LDM distributions. Under some strong assumptions on the displacement noise at very low frequency, the Doppler data collected during the whole LISA mission could provide upper limits on ID and LDM densities.     

Integrated stratigraphy (cyclostratigraphy and biochronology) of late Middle Miocene deposits in the Mediterranean area and comparison with the North and Equatorial Atlantic Oceans: synthesis of the major results

The stratigraphic correlation of North and Equatorial Atlantic Ocean records with Mediterranean astronomically tuned sections reveals the diachrony of several planktonic foraminiferal bioevents, but shows the possibility to adopt the Mediterranean biostratigraphy in North Atlantic records. These data provide new tools for biostratigraphic correlation, mainly between the Mediterranean and the North Atlantic areas. Quantitative analyses carried out on planktonic foraminifera reveal the occurrence at Site 982-HoleB (ODP Leg 162) of some bioevents in the same order as those recorded in Mediterranean sequences. In addition, Neogloboquadrina atlantica praeatlantica first occurrence (FO) [within the short range of Paragloborotalia mayeri, sensuRiv. Ital. Paleontol. Stratigr. 108 (2002) 257] occurs in levels older than its FO in the Mediterranean area where it first appears at the same level as N. acostaensis s.s. coinciding with the last occurrence of P. partimlabiata. In agreement with the findings of Poore [Init. Rep. Deep Sea Drilling Proj. 49 (1979) 447] and the hypothesis of Zachariasse and Aubry [Paleobios 16 (1994) 68], the first representative of the neogloboquadrinids originated north of Iceland and migrated towards the southern latitudes at different times, first in the Mediterranean and mid-latitude Atlantic Ocean, then in low-latitudes (Site 397).