SLRS‐5 Elemental Concentrations of Thirty‐Three Uncertified Elements Deduced from SLRS‐5/SLRS‐4 Ratios

The fifth version of natural river water certified reference material, SLRS‐5 (National Research Council – Conseil National de Recherches Canada), is commonly used to control the quality of major and trace element measurements. Concentrations of silicon and thirty‐one uncertified trace elements have been reported for the certified reference material SLRS‐4, but they are not yet available for SLRS‐5. Here, SLRS‐5/SLRS‐4 ratios were deduced from SLRS‐5 and SLRS‐4 measurements by inductively coupled plasma‐atomic emission spectrometry and high‐resolution inductively coupled plasma‐mass spectrometry for certified elements and thirty‐five uncertified elements (rare earth elements, B, Bi, Br, Cs, Ga, Ge, Hf, Li, Nb, P, Pd, Rb, Rh, S, Sc, Si, Sn, Th, Ti, Tl, Y). Both reference materials were measured directly one after the other, so that calculated elemental ratios would not be notably influenced either by calibration uncertainties or by eventual long‐term instrumental drift. The computed ratios are in good agreement with those deduced from the certified values. We also report concentrations for thirty‐three uncertified elements in SLRS‐5 by combining the measured SLRS‐5/SLRS‐4 ratios and the published SLRS‐4 values. The resulting new data set provides target SLRS‐5 values, which will be useful in quality control procedures.     

Textures in deforming forsterite aggregates up to 8 GPa and 1673 K

We report results from axisymmetric deformation experiments carried out on forsterite aggregates in the deformation-DIA apparatus, at upper mantle pressures and temperatures (3.1–8.1 GPa, 1373–1673 K). We quantified the resulting lattice preferred orientations (LPO) and compare experimental observations with results from micromechanical modeling (viscoplastic second-order self-consistent model—SO). Up to 6 GPa (~185-km depth in the Earth), we observe a marked LPO consistent with a dominant slip in the (010) plane with one observation of a dominant [100] direction, suggesting that [100](010) slip system was strongly activated. At higher pressures (deeper depth), the LPO becomes less marked and more complex with no evidence of a dominant slip system, which we attribute to the activation of several concurrent slip systems. These results are consistent with the pressure-induced transition in the dominant slip system previously reported for olivine and forsterite. They are also consistent with the decrease in the seismic anisotropy amplitude observed in the Earth’s mantle at depth greater than ~200 km.     

Oxygen isotope analyses of fine silica grains using laser-extraction technique: Comparison with oxygen isotope data obtained from ion microprobe analyses and application to quartzite and silcrete cement investigation

The laser fluorination technique reported here for analyzing the oxygen isotope composition (δ¹⁸O) of fine quartz size fractions 50-20, 20-10, 10-5, 5-2, 2-1 and <1 μm has been validated by comparison with the ion microprobe technique. It yields accurate δ¹⁸O data with an external precision better than 0.15‰. This is a significant methodological improvement for isotopic studies dealing with materials such as soil or biogenic oxides and silicates: particles are often too small and recovered in insufficient amount to be easily handled for ion microprobe analysis. Both techniques were used to investigate δ¹⁸O composition of a Cretaceous quartzite and silcrete sequence from the South-East of France. Quartzite cements average 31.04 ± 1.93‰. They formed from Mid-Cretaceous seawater. Higher in the series, silcretes cements average 26.66 ± 1.36‰. They formed from Upper- or post-Upper-Cretaceous soil water and groundwater. Oxygen isotope data show that the silicification steps from one mineralogical phase to another and from one layer to another (including from an upper pedogenic silcrete to a lower groundwater silcrete) occurred in a closed or weakly evaporating hydrological system.     

Criteria for Selecting and Adjusting Ground-Motion Models for Specific Target Regions: Application to Central Europe and Rock Sites

A vital component of any seismic hazard analysis is a model for predicting the expected distribution of ground motions at a site due to possible earthquake scenarios. The limited nature of the datasets from which such models are derived gives rise to epistemic uncertainty in both the median estimates and the associated aleatory variability of these predictive equations. In order to capture this epistemic uncertainty in a seismic hazard analysis, more than one ground-motion prediction equation must be used, and the tool that is currently employed to combine multiple models is the logic tree. Candidate ground-motion models for a logic tree should be selected in order to obtain the smallest possible suite of equations that can capture the expected range of possible ground motions in the target region. This is achieved by starting from a comprehensive list of available equations and then applying criteria for rejecting those considered inappropriate in terms of quality, derivation or applicability. Once the final list of candidate models is established, adjustments must be applied to achieve parameter compatibility. Additional adjustments can also be applied to remove the effect of systematic differences between host and target regions. These procedures are applied to select and adjust ground-motion models for the analysis of seismic hazard at rock sites in West Central Europe. This region is chosen for illustrative purposes particularly because it highlights the issue of using ground-motion models derived from small magnitude earthquakes in the analysis of hazard due to much larger events. Some of the pitfalls of extrapolating ground-motion models from small to large magnitude earthquakes in low seismicity regions are discussed for the selected target region.     

First assessment of the Caulerpa racemosa (Caulerpales, Chlorophyta) invasion along the French Mediterranean coast

The introduced green alga Caulerpa racemosa var. cylindracea has been rapidly spreading in the Mediterranean Sea since 1990. It was first observed in France in 1997 (Marseilles). In early 2004, the stretch of the French Mediterranean coastline and the surface area affected by the invasion were estimated at about 83 km and 4014 ha, respectively. The depth range of colonized areas was usually 10-35 m depth. Shallow (0-10 m) and deep (down to 40 m) dense meadows were rarely observed. In contrast to the dead matte of Posidonia oceanica, which constituted the most widely colonized substratum, dense P. oceanica meadows and fine sand with large ripple-marks were not invaded. Few rocky areas were colonized and coarse sand bottoms were usually colonized below 20 m depth. All the colonized areas were exposed to human activities and more than 40% were fishing areas. Mild climate, suitable substrata, presence of vectors of dispersal and absence of efficient biological control make the French Mediterranean coast particularly vulnerable to the further spread of the alga.     

Relative current effect on short wave growth

Ocean Dynamics - Short waves growth is characterized by nonlinear and dynamic processes that couple ocean and atmosphere. Ocean surface currents can have a strong impact on short wave steepness and...     

On the developments of spectral wave models: numerics and parameterizations for the coastal ocean

The development of numerical wave models for coastal applications, including coupling with ocean circulation models, has spurred an ongoing effort on theoretical foundations, numerical techniques, and physical parameterizations. Some important aspects of this effort are reviewed here, and results are shown in the case of the French Atlantic and Channel coast using version 4.18 of the WAVEWATCH III ^R model. Compared to previous results, the model errors have been strongly reduced thanks to, among other things, the introduction of currents, coastal reflection, and bottom sediment types. This last item is described here for the first time, allowing unprecedented accuracy at some sites along the French Atlantic Coast. The adequate resolution, necessary to represent strong gradients in tidal currents, was made possible by the efficiency brought by unstructured grids. A further increase in resolution, necessary to resolve surf zones and still cover vast regions,will require further developments in numerical methods.