Marine snow originating from appendicularian houses: Age-dependent settling characteristics

The evolution of size, sinking velocity, and dry weight of aging discarded appendicularian houses, a component of marine snow, were examined in laboratory experiments. The sizes of discarded houses decrease over time, with a rapid deflation during the first hour, followed by a slower rate of compression leading to a total of 60% and 87% decrease in diameter after 1 h and 5 d, respectively. The initial rapid deflation of the houses is accompanied by a massive loss of its particle content and a 10–63% loss in weight. The initial weight loss is left as a trail of elevated particle and solute concentration in the wake of the sinking house. Subsequently the house weight decreases at a much lower rate that is consistent with bacterial degradation. The combined effect of weight losses and deflation–compression process is an increase in the sinking speed of the houses, by a factor of 1.7–6 after 1.5–3 d. These processes can provide a new insight on the sinking dynamic and flux of appendicularian produced marine snow from in situ observations. We applied our laboratory derived rates to field data from the East Atlantic Ocean and estimate that large (2000–4000 μm) houses account for about 1/3 of the 300–500 μm particles in the upper 100 m and loose 30% of their mass before leaving the upper 200 m. The observed deflation–compression process may have several consequences on the dynamics of appendicularian-derived marine snow particles. First, it may explain field observations that marine snow sinking velocities increase with depth. Second, an initial rapid loss of weight and particles will decrease the potential vertical flux of particulate carbon due to appendicularians. And finally, the trail of particles and solutes may guide zooplankton to the sinking house, and further increase its degradation due to grazing by detrivorous organisms.     

Second generation instrumentation for the VLTI: The french VLTI connection

We describe the current French ideas for the instrumentation of the second generation of the VLTI. Instruments concepts addressed include: integrated optics beam combiner, extension of MIDI to a four beam facility, extension of AMBER to the visible and a densified pupil direct imaging beam combiner. This revised version was published online in July 2006 with corrections to the Cover Date.     

SMOS reveals the signature of Indian Ocean Dipole events

The tropical Indian Ocean experiences an interannual mode of climatic variability, known as the Indian Ocean Dipole (IOD). The signature of this variability in ocean salinity is hypothesized based on modeling and assimilation studies, on account of scanty observations. Soil Moisture and Ocean Salinity (SMOS) satellite has been designed to take up the challenge of sea surface salinity remote sensing. We show that SMOS data can be used to infer the pattern of salinity variability linked with the IOD events. The core of maximum variability is located in the central tropical basin, south of the equator. This region is anomalously salty during the 2010 negative IOD event, and anomalously fresh during the 2011 positive IOD event. The peak-to-peak anomaly exceeds one salinity unit, between late 2010 and late 2011. In conjunction with other observational datasets, SMOS data allow us to draw the salt budget of the area. It turns out that the horizontal advection is the main driver of salinity anomalies. This finding is confirmed by the analysis of the outputs of a numerical model. This study shows that the advent of SMOS makes it feasible the quantitative assessment of the mechanisms of ocean surface salinity variability in the tropical basins, at interannual timescales.     

Null Variance Altitudes for the photolysis rate constants of species with barometric distribution: Illustration on Titan upper atmosphere modeling

The precision of the rates of the photolysis processes initiating the complex chemistry of Titan’s upper atmosphere conditions strongly the predictivity of photochemical models. Recent studies in sensitivity analysis of such models point out photolysis rate constants as key parameters. However, they have been treated approximately so far. We deal here directly with uncertainty in the absorption cross-sections to derive the uncertain altitude-dependent photolysis rate constants. We observe that the uncertainty on the photolysis rate constants of the major species, N₂ and CH₄, varies strongly with altitude and rather surprisingly vanishes at specific altitudes. We propose a simple model to interpret these features and we demonstrate that they are transferable to any major absorber distributed barometrically in an atmosphere.     

Groundwater age,life expectancy and transit time distributions in advective–dispersive systems; 2. Reservoir theory for sub-drainage basins

Groundwater age and life expectancy probability density functions (pdf) have been defined, and solved in a general three-dimensional context by means of forward and backward advection–dispersion equations [Cornaton F, Perrochet P. Groundwater age, life expectancy and transit time distributions in advective–dispersive systems; 1. Generalized reservoir theory. Adv Water Res (xxxx)]. The discharge and recharge zones transit time pdfs were then derived by applying the reservoir theory (RT) to the global system, thus considering as ensemble the union of all inlet boundaries on one hand, and the union of all outlet boundaries on the other hand. The main advantages in using the RT to calculate the transit time pdf is that the outlet boundary geometry does not represent a computational limiting factor (e.g. outlets of small sizes), since the methodology is based on the integration over the entire domain of each age, or life expectancy, occurrence. In the present paper, we extend the applicability of the RT to sub-drainage basins of groundwater reservoirs by treating the reservoir flow systems as compartments which transfer the water fluxes to a particular discharge zone, and inside which mixing and dispersion processes can take place. Drainage basins are defined by the field of probability of exit at outlet. In this way, we make the RT applicable to each sub-drainage system of an aquifer of arbitrary complexity and configuration. The case of the well-head protection problem is taken as illustrative example, and sensitivity analysis of the effect of pore velocity variations on the simulated ages is carried out.     

Fluid-dynamics driving saline water in the North East German Basin

In several areas of the North German Basin, saline water comes close to, or even reaches the surface. Available data from wells indicate that brine stratification is under unstable conditions in the deeper underground. In order to analyse the possible transport mechanisms, 3D thermohaline simulations have been carried out for two different scenarios. The 3D regional model (230×330 km) indicates that salty water is driven to the surface by hydrostatical forces from the surrounding highlands. In addition, a smaller scale model (10×10 km) has been constructed with a grid resolution accounting for possible convective flow. The results indicate that convective flow may play a dominant role in areas with minor topography. In summary, the complex pattern of near surface occurrences of saline water probably results from the interaction of hydrostatic and thermal forces.     

How to anchor hotspots in a convecting mantle?

Laboratory experiments were performed to study the influence of density and viscosity layering on the formation and stability of plumes. Viscosity ratios ranged from 0.1 to 6400 for buoyancy ratios between 0.3 and 20, and Rayleigh numbers between 10⁵ and 2.10⁸. The presence of a chemically stratified boundary layer generates long-lived thermochemical plumes. These plumes first develop from the interface as classical thermal boundary layer instabilities. As they rise, they entrain by viscous coupling a thin film of the other layer and locally deform the interface into cusps. The interfacial topography and the entrainment act to further anchor the plumes, which persist until the chemical stratification disappears through entrainment, even for Rayleigh numbers around 10⁸. The pattern of thermochemical plumes remains the same during an experiment, drifting only slowly through the tank. Scaled to an Earth’s mantle without plate tectonics, our results show that: (1) thermochemical plumes are expected to exist in the mantle, (2) they could easily survive hundreds of millions of years, depending on the size and magnitude of the chemical heterogeneity on which they are anchored, and (3) their drift velocity would be at most 1-2 mm/yr. They would therefore produce long-lived and relatively fixed hotspots on the lithosphere. However, the thermochemical plumes would follow any large scale motion imposed on the chemical layer. Therefore, the chemical heterogeneity acts more as a ‘floating anchor’ than as an absolute one.     

Electrochemical properties of solids at the aqueous–solid interface and heterogeneity of surfacePropriétés électrochimiques des solides à l'interface solide–eau et hétérogénéité de surface

In aqueous medium, solid surfaces are in general electrically charged. The induced electrical and chemical properties govern numerous phenomena, such as colloidal stability or transport of pollutants. Numerous industrial processes make use of these properties. The understanding of the underlying mechanisms at molecular level is of high importance in order to predict and master the behaviour of dispersed matter in the environment and in industrial processes. The present paper shows the evolution of theories and experimental methods, their recent developments and applications. To cite this article: F. Thomas et al., C. R. Geoscience 334 (2002) 633–648.     

Salinization problems in the NEGB: results from thermohaline simulations

The occurrence of salty waters close to the surface is a well-known problem in the North East German Basin. Previous numerical simulations showed that near-surface brine occurrences are due to the interaction of hydrostatic and thermally induced forces (mixed convection). The influence of hydraulic permeabilities and thermal conductivities on the observed patterns remained an open question. Based on a hydro-geochemical dataset, thermohaline simulations are carried out in order to quantify the impact of these physical parameters on brine migration. The results indicate that the salinity and temperature profiles are strongly controlled by hydraulic permeabilities and can locally be influenced by thermal conductivities.