2010—2020年黄河下游河南典型灌区浅层地下水中砷和氟的演化特征及变化机制

黄河下游典型灌区河南段是豫北平原重要的农业种植区。该地区浅层水质整体较差,因常用于作物灌溉或家畜饮用,会对人体健康产生风险,因此对该地区地下水中砷与氟浓度变化特征和机制的研究将有助于提高对该地区地下水污染的认识水平。本文基于2010年和2020年在灌区范围内采集的327组浅层地下水样品,研究区内地下水砷和氟分布情况,并在此基础上对比研究十年间灌区浅层地下水中砷、氟的演化特征,探索分析砷与氟浓度及空间变化机制。研究结果表明：该地区浅层地下水中存在砷与氟超标问题,2020年浅层地下水中高砷（砷浓度大于10μg/L）和高氟（氟浓度大于1mg/L）的样品数量分别占总数的26.1%和26.06%。高砷水分布在太行山前洼地与黄河冲积平原等泥沙互层结构的沉积环境中,还原性较强,同时地下水径流不畅,较强的阳离子交换作用使得其所处环境中Ca²⁺浓度较高。近十年间砷浓度增加的水样占总数31.8%,砷浓度减少的水样占36.7%。砷浓度的增长（减少）是地下水还原性增强（减弱）使得锰氧化物溶解释放（吸附）导致。近十年间不同地区农业灌溉和水源置换等用水方式导致水位变化是引起砷浓度变化的潜在因素。高氟水主要分布在河南新乡与濮阳的黄河沿线,氟离子浓度受到沉积物中萤石等钙质矿物溶解影响,使得高氟地下水出现在低钙环境中。近十年间研究区中氟离子浓度减少的占总数60.2%,氟离子浓度增加的占32.1%,整体变化趋势向好,但是高氟区中氟离子浓度继续增加。氟浓度的变化同样受到Ca²⁺变化影响,在Ca²⁺浓度降低（升高）时氟浓度进一步升高（降低）。地下水中氟升高地区分布在黄河沿线,因此受到黄河水补给影响较大,地下水径流条件较好,阳离子交换作用减弱,使得Ca²⁺浓度降低,此时地下水中砷浓度受到环境影响而降低,因此研究区氟增加地区中砷与氟的分布和演化呈现反向关系。     

扬子地区震旦纪—寒武纪转折期大陆风化研究进展与展望

通过调研扬子地区震旦纪（埃迪卡拉纪）—寒武纪（E—C）转折期大陆风化、海洋环境和有机质富集特征研究。结果显示,扬子地区E—C转折期遭受了较强烈的化学风化作用,且在这一时期区内兼具浅水碳酸盐台地和深水盆地环境。在台地相区,下寒武统牛蹄塘组黑色岩系不整合接触于震旦系灯影组白云岩之上,该不整合与E—C转折期全球“大不整合”具有紧密的关系,盆地区发育的完整的沉积地层记录了台地区被风化地层的痕迹。现有大陆风化的地球化学证据集中于n(87Sr)/ n(86Sr)、δ13C、CIA和e??Nd(t)等,同时这些地球化学数据也局限在少数的剖面和层段,因此迫切需要更多的地球化学参数来反映该风化作用的影响范围和演化特征。准确认识扬子地区E—C转折期大陆风化作用与海洋环境演变间的耦合关系,是揭示古生物演化、有机质富集机制的重要环节。     

Assessment of regional drought vulnerability and risk using principal component analysis and a Gaussian mixture model

Due to the complex characteristics of drought, drought risk needs to be quantified by combining drought vulnerability and drought hazard. Recently, the major focus in drought vulnerability has been on how to calculate the weights of indicators to comprehensively quantify drought risk. In this study, principal component analysis (PCA), a Gaussian mixture model (GMM), and the equal-weighting method (EWM) were applied to objectively determine the weights for drought vulnerability assessment in Chungcheong Province, located in the west-central part of South Korea. The PCA provided larger weights for agricultural and industrial factors, whereas the GMM computed larger weights for agricultural factors than did the EWM. The drought risk was assessed by combining the drought vulnerability index (DVI) and the drought hazard index (DHI). Based on the DVI, the most vulnerable region was CCN9 in the northwestern part of the province, whereas the most drought-prone region based on the DHI was CCN12 in the southwest. Considering both DVI and DHI, the regions with the highest risk were CCN12 and CCN10 in the southern part of the province. Using the proposed PCA and GMM, we validated drought vulnerability using objective weighting methods and assessed comprehensive drought risk considering both meteorological hazard and socioeconomic vulnerability.

     

Comprehensive analysis control effect of faults on the height of fractured water-conducting zone in longwall mining

Natural Hazards - In order to examine the height of a fractured water-conducting zone due to the presence of a fault, a typical working face in the Baodian Coal Mine which is located in the Yanzhou...     

Physical Model Tests on the Effect of Anchoring on the Splitting Failure of Deep Large-Scale Underground Rock Cavern

Geotechnical and Geological Engineering - A set of splitting cracks often occur in the high side wall of the deep underground hydropower station due to the excavation-induced unloading during the...     

New Systematic Method to Determine Elastic Constants and Crack Propagation Thresholds of Brittle Rocks Under Triaxial Compression

Geotechnical and Geological Engineering - Elastic constants and crack propagation stress thresholds of brittle rocks are important mechanical properties for engineering applications. However, these...     

Destressing Mechanics Effect of Surrounding Rock Induced by Blasting Precondition at Deep Drift Development

Geotechnical and Geological Engineering - Using a detailed modeling simulation technology, a mechanics simulation model was constructed, including multiple development rounds, stress relief holes...     

Simulation Study on Electromagnetic Response Characteristics of Unfavorable Geological Body Under Complex Conditions

Geotechnical and Geological Engineering - The second phase of the Chongqing Rail Transit Line project has poor rock and soil stability, slow construction progress, complex and variable geological...     

祁连山区多年冻土空间分布模拟

祁连山区位于青藏高原东北边缘,是亚洲水塔重要的组成部分,多年冻土的变化对生态系统和水资源平衡有着重要影响。基于青藏高原第二次综合科学考察、道路勘察钻孔点以及前人所获得的多年冻土下界资料,回归得出祁连山区多年冻土下界统计模型,借助ArcGIS平台在DEM数据的支持下,模拟出祁连山区多年冻土空间分布图。结果表明：祁连山区多年冻土分布的下界具有良好的地带性规律,表现为随经纬度增加而降低的规律;祁连山区多年冻土在空间分布上呈现出以哈拉湖为中心向四周扩散的分布格局;祁连山区总面积约为16.90×10⁴ km²,其中多年冻土面积约为8.03×10⁴ km²,占总面积约47.51%。多年冻土区与季节冻土区之间存在着有不连续多年冻土分布的过渡区,过渡区面积约1.43×10⁴ km²,占总面积约8.46%。     

高寒冻土区生物结皮对土壤理化属性的影响

生物结皮是高寒地区地被层的重要组分之一。其作为地表特殊的结构层,能够改变地表结构及土壤理化属性,从而影响冻土环境。迄今为止,关于青藏高原高寒生态系统中生物结皮对土壤理化属性的影响尚不清楚。以青藏高原高寒冻土区生物结皮为研究对象,初步研究了生物结皮的特征及其对土壤理化属性的影响。结果表明：生物结皮在高寒草甸退化过程中广泛发育,主要以藻结皮为主,其盖度可达37.3%~51.7%,结皮层平均厚度为12.6 mm。由于生物结皮的发育,高寒地区5~20 cm土层粉粒含量有所增加,但差异不显著,而结皮层土壤田间持水量相比于裸地表层（2 cm）增加了10%~40%,结皮层容重较裸地降低了30%;两种类型藻结皮均显著增加了结皮层及其下0~20 cm土层土壤有机质,而深色藻结皮增加了结皮层及其下0~20 cm土层土壤全氮含量,浅色藻结皮仅增加了结皮层土壤全氮含量,对其下0~20 cm土层土壤全氮含量没有显著影响;生物结皮对土壤pH没有显著影响;生物结皮是高寒生态系统植被退化过程中的关键环节。研究结果为揭示生物结皮在高寒生态系统中发挥重要生态功能提供依据。