Geochemical Assessment of a Subtropical Reservoir: A Case Study in Curitiba,Southern Brazil

Suspended particles and dissolved substances in water provide reactive surfaces, influence metabolic activity and contribute to the net sediment deposition. It therefore plays an important part in the ecology and quality of the water mass. The water quality in reservoirs is crucial and it is naturally maintained by flushing and sedimentation, which continuously remove phosphorus from the water. In some reservoirs, however, these removal processes are countered by recycling of ions which could play a key role to start and/or maintain the eutrophic state. The combination of macro‐, trace‐ and microanalysis techniques can be useful to trace pollution sources through a chemical fingerprint, whether be during an acute environmental disaster or a long‐term release of pollutants. The water quality and total metal content of reservoir sediments were assessed in a reservoir, situated in the capital of the Paraná State, in the South‐Eastern part of Brazil. The goal of this paper was to determine the metal presence in the sediment and metal and ionic speciation in the Green River reservoir water. Water and bed sediment samples, collected from various sites during 2008 and 2009, were investigated using XRF, ICP‐OES, ICP‐MS, XRD and zeta potential measurements. Based on the results, the heavy metal concentration and chemical composition of the suspended matter in the water samples, as well as the sediment's chemical composition will be discussed.     

The autonomous <Emphasis Type="Italic">Simpatico</Emphasis> system for real-time continuous water-quality and current velocity monitoring: examples of application in three Portuguese estuaries

This technical paper describes an autonomous recording system with remote data access for the continuous, long-term in situ monitoring of water quality and discharge, as well as current velocity. The Simpatico system has been recently deployed in three estuaries in Portugal (Mondego and Tagus in July 2007; Guadiana in March 2008), highly suitable to illustrate its multifaceted potential applications: surveillance of the effects of mitigation measures to combat eutrophication (lower Mondego Estuary); real-time implementation of boundary conditions for a water modelling system (upper Tagus Estuary); study of dam-induced impacts in terms of water quality, water discharge and sediment budgets (mouth of the Guadiana Estuary). An extract of recorded data serves as an example to discuss data reliability, as well as field maintenance of the system, with implications for labour and operational costs. The use of a new generation of copper-based anti-biofouling kits significantly reduced the need for field maintenance operations. Other examples of possible application of the system include the assessment of gas accumulation in coastal waters.     

Geoacoustic character,sedimentology and chronology of a cross-shelf Holocene sediment deposit off Cabo Frio,Brazil (southwest Atlantic Ocean)

The Cabo Frio region in the state of Rio de Janeiro, southeast coast of Brazil, is characterized by a local coastal upwelling system and converging littoral sediment transport systems that are deflected offshore at Cabo Frio, as a consequence of which a thick cross-shelf sediment deposit has developed over time. To investigate the evolution of this muddy deposit, geophysical, sedimentological and geochemical data from four sediment cores (3.8–4.1 m in length) recovered in water depths between 88 and 141 m were analyzed. The high-resolution seismic data show variable sediment thicknesses ranging from 1 to 20 m, comprising two sedimentary units separated by a high-impedance layer at a depth of about 10 m below the seafloor at the coring sites. According to the available age datings, the upper sedimentary unit is late Pleistocene to Holocene in age, whereas the lower unit (not dated) must, by implication, be entirely Pleistocene in age. The boomer-seismic reflection signal can be divided into three echo-types, namely transparent (inner shelf), stratified (middle shelf) and reflective (outer shelf), each type seemingly related to the local sediment composition. The upper 4 m of the upper sedimentary unit is dominated by silty sediment on the middle shelf, and by upward-fining sediments (silty sand to sandy silt) on the inner and outer shelf. The downcore trends of P-wave velocity, gamma-ray density and acoustic impedance are largely similar, but generally reversed to those of water and organic carbon contents. Total organic carbon contents increase with decreasing mean grain size, periodic fluctuations suggesting temporal changes in the regional hydrodynamics and primary productivity fuelled by the local upwelling system. The reconstruction of sedimentation rates in the course of the Holocene is based on 35 AMS age datings of organic material recovered from variable downcore depths. These range from a maximum of 13.3 cm/decade near the base of the inner shelf core (7.73–7.70 ka BP) to generally very low values (<0.11 cm/century) over the last thousand years in all cores. Over the last 6 ka there appear to have been three distinct sedimentation peaks, one between 6 and 5 ka BP, another between 4 and 3 ka PB, and one around 1 ka BP. Due to different time intervals between dates, not every peak is equally well resolved in all four cores. Based on the similar sedimentology of the inner and outer shelf cores, an essentially identical sedimentation model is proposed to have been active in both cases, albeit at different times. Thus, already during the last glacial maximum, alongshore sediment transport was deflected offshore by a change in shoreline orientation caused by the Cabo Frio structural high. The source of terrigenous material was probably a barrier-island complex that was subsequently displaced landward in the course of sea-level rise until it stabilized some 6.5 ka BP along the modern coast.     

The influence of an extreme drought event in the fish community of a southern Europe temperate estuary

Between 2003 and 2006, a severe drought occurred throughout the Mondego River catchment's area, inducing lower freshwater flows into the estuary. As a consequence, both 2004 and 2005 were considered as extreme drought events. From June 2003 to June 2006, the fish assemblage of the Mondego Estuary was sampled monthly in five stations during the night, using a 2 m beam trawl. Fish abundance was standardized as the number of individuals per 1000 m² per season and the assemblage was analyzed based on ecological guilds: estuarine residents, marine juveniles, marine adventitious, freshwater, catadromous and marine species that use the estuary as a nursery area. A total of 42 species belonging to 23 families were identified, with estuarine residents and nursery species dominating the fish community. Variations in the fish community were assessed using non-metric MDS, being defined as three distinct periods: summer and autumn 2003, 2004/2005 and winter and summer 2006. The main drought-induced effects detected were the depletion of freshwater species and an increase in marine adventitious in 2004/2005, due to an extended intrusion of seawater inside the estuary and a significant reduction in abundance during the driest period of estuarine resident species. Nevertheless, from the management point of view, it could be stated that although some variations occurred due to environmental stress, the main core of the Mondego Estuary fish community remained relatively unchanged.     

Timing and mechanisms for the generation and modification of the anomalous topography of the Borborema Province,northeastern Brazil

The results of apatite fission-track analysis in 14 granitic-gneissic samples from two regional transects across the Borborema Plateau, northeastern Brazil, show evidence for two dominant paleothermal events: a Late Cretaceous cooling event beginning sometime between 100 and 90 Ma, and a second cooling event in the Neogene. The distribution of the fission-track results suggests that the cooling events have a broad regional expression and are consistent with the geologic record in the Araripe Basin, western Borborema Province, which attests to a post-Albian uplift of the whole region. We hypothesize that the first event is due to the uplift and denudation of regional, permanent topography generated after the breakup of Brazil and Africa. Such topography is predicted by models of continental margin extension in which continental lithosphere thinning is followed by thickening of the adjacent hinterland lithosphere and crust (Kusznir, N.J., Karner, G.D., 2007. Continental lithospheric thinning and breakup in response to upwelling divergent mantle flow: application to the Woodlark, Newfoundland and Iberia margins. In: Karner, G.D., Manatschal, G., Pinheiro, L. (Eds), Imaging, mapping and modeling continental lithosphere extension and breakup. Special Publication 282, Geological Society, London, pp. 389–419.). In northeastern Brazil, this extension-engendered topography may have been amplified by magmatic underplating related to the Saint Helena and Ascension plumes. The Miocene cooling event (20–0 Ma) occurred at a time characterized by the transition from carbonate ramp to progradational clastic systems on the Pernambuco–Paraíba margin and the offshore Potiguar Basin. This same stratigraphic response characterizes the Neogene stratigraphy of many passive margins and attests to a global increase in the delivery of clastics to margins, the simplest explanation of which is a climate change that accentuated erosion of pre-existing topography. Thus, the present rugged landscape of northeastern Brazil is interpreted to be a product of this younger denudation event. A corollary of this study is that the history, distribution and delivery of clastics to the northern and northeastern margins of Brazil are a function of the regional development of the continental landscape during the Late Cenozoic.     

Geosteranes: Identification and synthesis of a novel series of 3-substituted steranes

A novel series of 3-alkyl and 3-carboxyalkyl-5β(H)-steranes 7–10 along with a full homologous series of carboxyalkyl-sterane (C₁ to C₆) 4–6 with 3α(H)5α(H) configuration have been identified in marine-evaporitic oils from Fazenda Belém, Potiguar Basin (Brazil) on the basis of mass spectral interpretation. The synthesis of enantiomerically pure 3α-alkyl-5β(H)-cholestane and 3β-alkyl-5α(H)-cholestane standards and their coinjection with petroleum fractions confirmed the structural assignments.     

Metal concentration and structural changes in Corallina elongata (Corallinales, Rhodophyta) from hydrothermal vents

Shallow-water hydrothermal activity is widely present at Azores archipelago. Organisms in such environments present great potential as sentinels of the effects derived from chronically exposure to increased temperature, metal concentrations and reduced pH. This study aimed to evaluate metal concentration in Corallina elongata collected at locations exposed and not exposed to shallow-water hydrothermal activity and evaluate changes in its calcareous structure. Elemental concentration was determined and morphometric analysis was performed by scanning electron microscopy. Thicker cell walls and a bleached appearance were observed on C. elongata specimens from the hydrothermally active location, as well as increased concentrations of elements associated to volcanic activity.This study reports on metal accumulation and morphometric changes in the calcareous structure of C. elongata from a hydrothermally active location, adding new data for further research on such habitats and communities, providing an insight on how coralline algae might be affected by ocean acidification.