Aragonite loss in a cold‐water coral mound: mechanisms and implications

Selective dissolution of aragonitic grains is emerging as a volumetrically significant process that affects a broad range of modern carbonate settings. This study explores mechanisms and implications of aragonite loss in Challenger Mound, a giant cold‐water coral (Lophelia pertusa) mound of Pleistocene age, which lies on the continental slope off south‐west Ireland. A comprehensive sampling scheme allowed the integration of petrographic data with geochemical analyses of sediment and pore water. The mound remains virtually unlithified and consists of stacked, fining‐upward cycles of silty coral floatstone–rudstone and bafflestone grading into wackestone. Whereas calcitic grains appear unaltered, aragonitic grains are corroded and fragmented. Aragonite dissolution is attributed to organic matter oxidation at/near the sediment–water interface and, at greater depths, to the initial stages of bacterially mediated sulphate reduction, when alkalinity production is outpaced by the generation of H⁺. Pore water profiles indicate that undersaturated waters are diffusing towards the mound interior from two centres of sulphate reduction: one located in the upper 10 m of the sediment column and a second that lies below an erosional unconformity which marks the base of the mound. Continued aragonite dissolution is expected to gradually lower the diagenetic potential of the Challenger Mound and delay lithification until deep burial, when solution‐compaction processes come into play. Despite a fundamental role in predestining the final taphonomic and textural characteristics of Challenger Mound, the processes described here are expected to leave little trace in the geological record due to a lack of cementation and calcitization. Assuming that similar processes have been active throughout the Phanerozoic, results imply that the understanding of diagenetic processes in carbonate systems may be incomplete.     

Spatial reconstruction of summer temperatures in Central Europe for the last 500 years using annually resolved proxy records: problems and opportunities

Most palaeoclimate studies in Central Europe, utilizing annually resolved proxies such as tree-ring and documentary sources to reconstruct past temperatures, have focused mainly upon single sites or regional studies. The combined information of published summer temperature reconstructions from the Alpine region show a generally coherent picture of cool conditions for the periods c. 1450-1475, 1575-1610, 1660-1710, 1800-1850 and 1875-1925. These reconstructed cool periods can be partly explained by external forcing (e.g. low solar activity and volcanic events). However, these reconstructions, in their present form, cannot be used to comparatively assess spatial summer temperature variability through the region due to methodological differences in their development and the fact that many of them were not originally developed to emphasize spatial patterns. We propose that a network of tree-ring chronologies which have been processed in a consistent way would allow the robust reconstruction of spatial summer temperature variability for high elevations in Central Europe. Unfortunately, most living tree-ring chronologies only go back into the 18th century - so restricting the length of reconstruction. As a possible solution, we introduce a historical database of ring-width series, measured from string instruments, that could be used to extend high elevation spruce chronologies in Central Europe back for at least 500 years.     

桂林水南洞洞穴沉积物的古地磁记录及其古环境意义

通过对桂林水南洞2.5m厚的洞穴沉积物剖面的古地磁初步研究,其结果及地质证据表明该沉积剖面形成期可能与贾拉米洛正向期对应。根据磁化率、磁性矿物的特征和沉积学特征,对该地区这一地质时期的古环境变化提出以下认识:1.第三暖湿期,以钙华沉积为特征;2.第二干冷期,以含有少量钙质的黄褐色粘土为特征,并以含有高矫顽磁性矿物和低磁化率为特征;3.第二暖湿期,以互层的红褐色粘土、含高含量钙质的粘土或钙华为特征,并以含有低矫顽磁性矿物和高磁化率为特征;4.第一干冷期,以褐灰色粘土为特征,并以含有高矫顽磁性矿物和低磁化率为特征;5.第一暖湿期,以地下河沉积相(砂卵石为主)为特征。      

On small particles in the Arctic summer boundary layer: observations at two different heights near Ny-Ålesund, Svalbard

Concurrent observations of particle number densities and size distributions observed at two different heights (near ocean level and 475 m above sea level) in Ny-Ålesund, Svalbard were studied with respect to the diurnal variation during a summer period in June 2004. The results show that observed variation in particle number density in the Arctic boundary layer may be strongly modulated by vertical mixing and dilution. The particles appeared to be formed in the early morning when solar intensity reached about 30% of the mid-day intensity. Based on differences in the observed number densities at the two heights it appears as if particles are formed in the lower part of the boundary layer. The formation rate of 10 nm diameter particles is estimated to be 0.11 cm⁻³ s⁻¹ and the growth rate is in a range between 1 and 2 nm h⁻¹.     

Diagenetic processes in carbonate mound sediments at the south‐west Rockall Trough margin

Cold water coral covered carbonate mounds at the south‐west margin of the Rockall Trough form ridges several kilometres long and up to 380 m high. Piston cores obtained at three mound crests reveal the complex internal structure of the mound build up, with alternating unlithified coral‐dominated intervals and lithified intervals. The most recent lithified interval is covered by corals embedded in a fine‐grained matrix, comprising ca 11 000 years of continuous mound evolution. Before this time ²³⁰Th/U dating shows the presence of several hiatuses in mound build‐up. Aragonitic coral material is absent or only present as mouldic porosity in the lithified intervals and coccoliths display widespread overgrowth. Downcore X‐ray fluorescence scanning, computer tomography scan images and petrographic observations indicate different degrees of diagenetic alteration. The upper boundary of the most recent lithified interval shows some erosional features, but petrographic observations indicate that initial lithification of the sediments is not related to this erosive event or to long‐term non‐sedimentation, but to earlier sub‐surface diagenesis. Organic matter oxidation and the subsequent lowering of the saturation state of the carbonate system drives dissolution of the unstable aragonitic coral skeletons. Depending on the openness of the system, this can lead to precipitation of a more stable low‐magnesium carbonate. A model is presented describing the sedimentary and diagenetic processes leading to the formation of lithified intervals.     

A 12.5-kyr history of vegetation dynamics and mire development with evidence of Younger Dryas larch presence in the Verkhoyansk Mountains, East Siberia, Russia

Werner, K., Tarasov, P. E., Andreev, A. A., Müller, S., Kienast, F., Zech, M., Zech, W. & Diekmann, B. 2009: A 12.5‐kyr history of vegetation dynamics and mire development with evidence of Younger Dryas larch presence in the Verkhoyansk Mountains, East Siberia, Russia. Boreas, 10.1111/j.1502‐3885.2009.00116.x. ISSN 0300‐9483. A 415 cm thick permafrost peat section from the Verkhoyansk Mountains was radiocarbon‐dated and studied using palaeobotanical and sedimentological approaches. Accumulation of organic‐rich sediment commenced in a former oxbow lake, detached from a Dyanushka River meander during the Younger Dryas stadial, at ～12.5 kyr BP. Pollen data indicate that larch trees, shrub alder and dwarf birch were abundant in the vegetation at that time. Local presence of larch during the Younger Dryas is documented by well‐preserved and radiocarbon‐dated needles and cones. The early Holocene pollen assemblages reveal high percentages of Artemisia pollen, suggesting the presence of steppe‐like communities around the site, possibly in response to a relatively warm and dry climate ～11.4–11.2 kyr BP. Both pollen and plant macrofossil data demonstrate that larch woods were common in the river valley. Remains of charcoal and pollen of Epilobium indicate fire events and mark a hiatus ～11.0–8.7 kyr BP. Changes in peat properties, C31/C27 alkane ratios and radiocarbon dates suggest that two other hiatuses occurred ～8.2–6.9 and ～6.7–0.6 kyr BP. Prior to 0.6 kyr BP, a major fire destroyed the mire surface. The upper 60 cm of the studied section is composed of aeolian sands modified in the uppermost part by the modern soil formation. For the first time, local growth of larch during the Younger Dryas has been verified in the western foreland of the Verkhoyansk Mountains (～170 km south of the Arctic Circle), thus increasing our understanding of the quick reforestation of northern Eurasia by the early Holocene.     

Properties of dust aerosol particles transported to Portugal from the Sahara desert

Aerosol properties of mineral particles in the far field of an African desert dust outbreak were investigated that brought Saharan dust over the Mediterranean in different layers to Portugal. The measurements were performed inside the project Desert Aerosols over Portugal (DARPO) which was linked to the Saharan Mineral Dust Experiment (SAMUM). The maximum particle mass concentration was about 150 μg m⁻³ and the corresponding scattering coefficient was 130 M m⁻¹ which results in a mass scattering efficiency of 0.87 m² g⁻¹. The aerosol optical depth reached values up to 0.53 and the lidar ratio was between 45 and 50 in the whole dust loaded column. A comparison between particle size distributions and refractive indices derived from different instruments and models showed a general good agreement but some minor differences could also be observed. Measurements as well as calculations with a particle transport model suggest that there is a relatively higher concentration of very large particles in the upper region of the dust layer than on the surface which is likely connected with meteorological conditions at the observational site (Évora, Portugal).     

A Metamorphosed Early Cambrian Crust-Mantle Transition in the Eastern Alps, Austria

In the Speik Complex (Eastern Alps, Austria), highly melt-depleted,metamorphosed harzburgites with abundant pods and layers ofchromitite are interlayered with a suite of metamorphosed orthopyroxenites,clinopyroxenites and gabbros. Coarse-grained orthopyroxenitesoccur as centimetre- to metre-wide veinlets and pods, but alsoas intrusive plugs several tens of metres wide. Intimately associatedmetaclinopyroxenite and metagabbro are present as bodies upto several metres thick at a distinct stratigraphic level withinthe complex. In the ultramafic rocks, relict magmatic olivine,orthopyroxene, clinopyroxene and spinel have been overprintedby a metamorphic assemblage of forsterite, diopside, tremolite,anthophyllite, chlorite, serpentine, talc and Cr–Fe-richspinel. Hornblende, epidote, zoisite and chlorite dominate themetamorphic paragenesis in metagabbros, in addition to rarerelicts of clinopyroxene and two phases of Ca-rich garnet. Thepolymetamorphic evolution of the Speik Complex includes rarelypreserved pre-Variscan (400 Ma) eclogite-facies conditions,Variscan (330 Ma) amphibolite-facies conditions (600–700°C,>5 kbar) and Eoalpine (100 Ma) greenschist- to amphibolite-faciesconditions reaching 550°C and 7–10 kbar. Orthopyroxenitesare characterized by high concentrations of SiO₂, MgO and Cr,and by U-shaped chondrite-normalized rare earth element (REE)patterns similar to those of their harzburgite hosts. The REEpatterns of the clinopyroxenites are flat to slightly enrichedin light REE. Metagabbro compositions are variable, but generallycharacterized by low SiO₂ and high mg-numbers (61–78).Their REE patterns all have Gd_N/Yb_N > 1; some samples havelarge positive Eu anomalies implying the original presence ofcumulus plagioclase. In the orthopyroxenites, clinopyroxenitesand some peridotites, Pt, Pd and Re are distinctly enrichedcompared with Os, Ir and Ru, whereas most harzburgites haveunfractionated to slightly fractionated platinum-group element(PGE) patterns with respect to average upper mantle. The Re–Osisotope compositions of the pyroxenites define an errorchronat 550 ± 17 Ma and a supra-chondritic ¹⁸⁷Os/¹⁸⁸Os of0·179 ± 0·003. An isochron age of 554 ±37 Ma with _Nd(i) +0·7 is indicated by the Sm–Ndisotope compositions of whole-rock pyroxenite and gabbro samples,whereas the harzburgites plot on an errorchron of 745 ±45 Ma and _Nd(i) +6. The pyroxenites and gabbros probably representa cogenetic suite of magmatic dykes intruded into uppermost,highly depleted, suboceanic mantle below the crust–mantletransition zone in an oceanic basin close to the northwesternmargin of Gondwana. KEY WORDS: pyroxenite; metagabbro; geochemistry; Re–Os isotopes; Sm–Nd isotopes     

Monazite-Xenotime-Garnet Equilibrium in Metapelites and a New Monazite-Garnet Thermometer

Prograde suites of pelitic rocks were examined with electronmicroprobe and laser ablation inductively coupled plasma massspectrometry to determine the systematics of element partitioningbetween coexisting monazite, xenotime, and garnet. Monazitegrains that grew in equilibrium with xenotime are enriched inY and Dy compared with monazite that grew in xenotime-absentassemblages. Y and heavy rare earth element contents of monazitecoexisting with xenotime increase with rising temperature. Monazite–xenotimeY–Gd and Y–Dy partitioning is systematic withina metamorphic grade, and increases slightly with increasingmetamorphic grade, suggesting that monazite–xenotime pairsapproached partitioning equilibrium. Garnet and monazite inboth xenotime-bearing and xenotime-absent assemblages show astrong ( R² = 0·94) systematic relationship between inversetemperature and ln(K_Eq) for the net-transfer equilibrium YAG+ OH-Ap + (25/4)Qtz = (5/4)Grs + (5/4)An + 3YPO₄-Mnz + 1/2H₂O,suggesting that garnet and monazite crystallized in compositionalequilibrium. The following temperature–K_Eq relationshipfor the equilibrium above has been derived:      

Selecting conservation reserves using species-covering models: Adapting the ARC/INFO GIS

Conflicts between human development of the landscape and conservation of biodiversiry will continue to grow. Given this reality, there have been a number of attempts to model the optimal selection of conservation reserve sites such that maximum biodiversity protection can be attained within a limited budget for land acquisition. Here we adapt the Location-Allocation module of ARC/INFO to solve the problem of representing, or covering, as many species as possible in a fixed number of selected reserve sites. Resident ARC/INFO solution routines are applied to an innovative 'logical' network that converts the problem of optimal reserve selection into a problem of optimal facility placement, which the Location-Allocation module can recognize and solve. Use of this unique logical network structure as input to ARC/INFO's internal solvers makes possible, compared to previous methods, a much tighter integration of spatial optimization tools with mapping and database tools, all of which are internal to the GIS and accessed via a menu-driven interface. The main advantage is that users of public domain data (such as the US Gap Analysis data) can conduct their own explorations of possible reserve systems without having to acquire and master optimization packages and reformat model output data for GIS display and post-analysis of solutions. Our sample application uses species data from south-western California. We also present a second major form of species-covering model grounded in the same logical network. This enhanced modcl accommodates weighting of species by their conservation importance, thus allowing reserve systems to be designed around the protection of the most threatened or vulnerable biota.