四川盆地下侏罗统陆相页岩气源储特征及耦合评价

四川盆地陆相页岩气勘探前景良好,目前已在川东北地区下侏罗统获得良好页岩气显示和工业气流.与海相页岩相比,陆相页岩具有相变快、岩相组合类型多(夹层发育)、有机质丰度低和源储配置关系复杂等特点.运用"源储耦合"研究思路,利用宏观-微观结合的储层表征技术对下侏罗统自流井组大安寨段页岩的烃源特征、储集特征及其耦合关系开展了分析...     

Measurement and Analysis of Thermal Conductivity of Rocks in the Tarim Basin, Northwest China

: As a parameter that describes heat transmission properties of rocks, thermal conductivity is indispensable for studying the thermal regime of sedimentary basins, and retrieving high-quality data of thermal conductivity is the basis for geothermal related studies. The optical scanning method is used here to measure the thermal conductivity of 745 drill-core samples from the Tarim basin, the largest intermontane basin with abundant hydrocarbon potential in China, and water saturation correction is made for clastic rock samples that are of variable porosity. All the measured values, combined with previously published data in this area, are integrated to discuss the distribution characteristics and major controlling factors that affect the thermal conductivity of rocks in the basin. Our results show that the values of thermal conductivity of rocks generally range from 1.500 to 3.000 W/m·K with a mean of 2.304 W/m·K. Thermal conductivity differs considerably between lithological types: the value of a coal sample is found to be the lowest as being only 0.249 W/m·K, while the values for salt rock samples are the highest with a mean of 4.620 W/m·K. Additionally, it is also found that the thermal conductivity of the same or similar lithologic types shows considerable differences, suggesting that thermal conductivity cannot be used for distinguishing the rock types. The thermal conductivity values of mudstone and sandstone generally increase with increasing burial depth and geological age of the formation, reflecting the effect of porosity of rocks on thermal conductivity. In general, the mineral composition, fabric and porosity of rocks are the main factors that affect the thermal conductivity. The research also reveals that the obvious contrast in thermal conductivity of coal and salt rock with other common sedimentary rocks can induce subsurface temperature anomalies in the overlying and underlying formations, which can modify the thermal evolution and maturity of the source rocks concerned. This finding is very important for oil and gas resources assessment and exploration and needs further study in detail. The results reported here are representative of the latest and most complete dataset of thermal conductivity of rocks in the Tarim basin, and will provide a solid foundation for geothermal studies in future.     

利用方式对东北黑土粘土矿物组成的影响

土地利用方式是影响土壤可持续利用的重要因素。粘土矿物是土壤重要的活泼物质,会受利用方式的影响而发生改变。为了揭示利用方式对土壤粘土矿物的影响,对不同利用方式下的东北黑土进行土壤理化特性及粘粒XRD分析。结果表明:荒地、旱田(大豆)、旱田(玉米)、水田利用的土壤矿物颗粒的风化依次增强,伊利石的含量和结晶度也依次降低。经水田利用后的黑土,粘土矿物的演变过程为:云母→伊利石→蛭石和绿泥石。定量结果表明黑土水田利用会出现蛭石绿泥石化现象。综合说明旱田利用会使土壤结构破坏以及水土流失加剧,而水田利用则能较好的协调土壤理化性质,可较大程度的改良土壤。     

黄河中游汛期水沙联合分布模型及其应用

为在宏观上对黄河中游水沙运动的变化规律从随机过程的角度予以揭示,以黄河中游潼关水文站1952-1998年期间流量超过6 000m3/s的次洪过程中的洪峰流量和相应的沙峰含沙量系列为基础,运用Copula函数方法构建了黄河中游汛期水沙联合分布模型并对其应用进行了探讨.结果表明:在水沙丰枯同步频率中,同丰的频率略大于同枯的...     

福建省中新生代古火山构造基本特征

福建位于我国东海之滨,环太平洋西部古火山带内,中新生代火山岩极为发育,尤以晚侏罗—早白垩世最为强烈,它们不仅规模庞大,且表现为由弱到强到弱的多次喷发。在闽东呈大面积分布,闽西则以单个盆地形式出现,面积约四万平方公里,占全省总面积的三分之一。新中国成立后,我们对中新生代火山岩进行了较系统的工作,特别是经过1∶20万区域     

青海省天峻县木里煤田煤层气有利区块的 多层次模糊数学评判

对影响煤层气勘探开发潜力的各种因素进行了综合研究,确定了煤层气勘探开发潜力评价的3个二级指标(生气潜力、储层物性和封盖性能)及对应的三级指标。采用模糊数学方法对各级因素指标赋予权重,建立了用于煤层气勘探开发潜力评价的多层次模糊数学评判模型。利用该模型,对青海木里煤田中低煤阶煤层气资源勘探开发潜力进行了评价,认为江仓矿区是木里煤层气勘探开发的最佳试验区。所建立的评价体系可以作为中低煤阶煤层气资源开发潜力评价的参考体系。     

基于COMSOL MULTIPHYSICS的直流电法正演模拟

以点电源和线电源为例,叙述了基于COMSOL MULTIPHYSICS的直流电法正演模拟过程。通过对COMSOL MULTIPHYSICS正演模拟解与理论值的对比分析,验证了应用COMSOL MULTIPHYSICS进行直流电法正演模拟的正确性与可行性。鉴于COMSOL MULTIPHYSICS强大的剖分求解功能及丰富的后处理操作,可以快速、准确实现正演模拟,其在地球物理正演模拟中的应用的研究意义重大。     

不同氧化锰矿物对光催化降解苯酚的影响

合成层状结构的酸性和碱性水钠锰矿以及隧道结构的锰钾矿和钙锰矿,将其用于苯酚的光催化降解研究。分别采用X射线衍射(XRD)、原子吸收光谱(AAS)、扫描电镜(SEM)、BET氮气吸附法和紫外可见漫反射光谱(UV-Vis DRS)对供试锰氧化物的晶体结构、化学组成、微观形貌、比表面积以及光吸收性能等进行了表征。研究表明,暗反应条件锰氧化物对苯酚的降解作用较弱,而UV-Vis光照能显著促进锰氧化物对苯酚的降解。光照反应12 h后,锰钾矿、酸性水钠锰矿、钙锰矿以及碱性水钠锰矿的苯酚降解率分别为92.1%、77.3%、57.4%和45.8%;对应的TOC去除率分别由暗反应时的6.3%、11.2%、2.0%和4.6%提高至62.1%、43.1%、25.4%和22.5%。4种供试锰氧化物均具有光催化活性,其大小顺序为:锰钾矿>酸性水钠锰矿>钙锰矿>碱性水钠锰矿。UV-Vis光照下氧化锰矿物光化学降解苯酚主要存在3种降解机制———苯酚的直接光解,锰氧化物的化学氧化和锰氧化物的光化学催化,其中光催化降解起主导作用。     

辽西建昌碱性粗面岩的年代学及岩石成因研究

义县组火山岩在辽话分布广泛,研究区碱性粗面岩位于建昌地区义县组火山岩的顶部,详细的年代学及地球化学研究表明,锆石u—Pb年龄为（120．3±1．5）Ma,具有较高的SiO2：和碱含量,ω（SiO2）=63．52％～65．94％,ω（Na20＋K2O）=9．63％一10．15％,ω（Na20）／ω（K20）为0．96～1．08,属于高钾碱性岩系列,同时具有较低的ω（MgO）（0．75％～1．05％）,稀土配分模式为轻稀土富集,重稀土亏损的右倾型模式（La／Yb）n=8．96～12．02）,较弱的正Eu异常（δEu=1．07—1．16）,相容元素Cr（1．46×10^6～4．15X10^6）、c0（19．8X10^6。～45．9X10^6）和Ni（0．100x10^6～1．55×10^6）含量低。微量元素蛛网图显示明显的Ba和Pb正异常,以及Sr、Ti和Y负异常,此外,zr和Hf显示一定的正异常。认为碱性岩形成于拉张的构造环境,且来源深度较大,是壳幔相互作用的结果,研究区火山岩是经过强烈橄榄石、斜方辉石和单斜辉石结晶分异的富集地幔岩浆上升底侵至下地壳,并经历同化混染和部分熔融,然后沿着深大断裂喷发至地表。     

The U-Pb Geochronology and Lu-Hf Isotope Compositions of Detrital Zircons from the Nanhua Group of the Longsheng Region, South China and their Implications for Pan-African Events

It is unclear whether the South China blocks have an affinity with continental Gondwana due to a lack of direct Pan-African magmatic and metamorphic features. In this study, we conducted U-Pb geochronological and Lu-Hf isotopic analyses for detrital zircons from a sandstone of the Chang’an Formation of the Nanhua Group in the Longsheng region of northern Guangxi, with the aim of constraining the timing of sedimentation and information as to its source, as well as seeking evidence for Pan-African events in the South China blocks. The results show that the ages of detrital zircons peaked at 654.7 ± 6.2 Ma, 773.2 ± 4.1 Ma and 821.9 ± 6.5 Ma, with some at 920–870 Ma; the youngest age indicates the existence of the Pan-African thermal event. The εHf(t) and TDM2 values demonstrate that the study area has experienced three stages of crustal growth at 3.0–2.4 Ga, 2.1–1.5 Ga and 1.3–0.9 Ga. With intensively distributed Neoproterozoic mafic-ultramafic and granitic plutons emplaced at 830–810 Ma along the southwestern section of the Jiangnan Orogenic Belt and positive εHf(t) values from a large group of zircon grains, it is proposed that the sediments of the Chang’an Formation (of Nanhua Group) were largely sourced from the southeastern margin of the Yangtze block. Comparison with the zircon age spectra of the Cathaysian block shows that about 79% of the Pan-African aged detrital zircon grains that have TDM2 = 1352–1031 Ma and εHf(t) = 3.68–8.79, were sourced from the recycled Grenvillian crust of the Cathaysian block, suggesting that the Cathaysian block had a close connection with Gondwana.