循环流化床燃煤脱硫剂技术研究现状及开发前景

本文论述了循环流化床在煤燃烧领域中的优势地位,并着重阐述了国内外循环流化床脱硫技术研究与脱硫剂开发利用状况,指出了在脱硫剂应用方面与国外的差距,提出了脱硫剂生产的产业化发展方向。     

云南墨江金矿含镍金绿色蚀变岩的构造地球化学特征及时空演化

采用构造变形筛分、同位素地球化学定年约束和构造蚀变岩的常量 微量元素地球化学研究等方法,对墨江镍金矿床中含金镍绿色蚀变带进行详细研究,探讨其形成和时 空演化规律,以及与金、镍成矿关系,提出本区含镍金绿色蚀变带形成与演化可分为三个期次:早期含镍金绿色蚀变带形成于(251 9±4 32)Ma,产于韧性剪切带中,形成含铬绢云母 绢云母(S2)组成的切层剪切面理;中期含镍金绿色蚀变岩形成于燕山早期(169 37～180 6Ma),产于高角度脆韧性剪切带中,形成铬绢云母 含铬绢云母组成的透入性剪切面理换(S3)和绿泥石拉伸线理;晚期含金绿色蚀变糜棱岩形成于燕山晚期(71 14～149 98Ma),产于左旋走滑脆韧性剪切带中,发育铬伊利石(S4)和铬绿泥石(S4)组成透入性剪切变形面理置换,与脆韧性剪切带的主体产状一致,韧性剪切构造带内发育,走滑构造带中十分发育,形成褶皱变形带(倾竖褶皱、鞘褶皱)及含金蚀变岩。     

锰矿石脱硫产物处理含铜废水动态实验研究

氧化型锰矿石脱硫产物含大量硫化锰,利用这种材料装填固定床进行净化水中铜离子的动态试验.在材料粒径0.45～0.9mm、进水pH=5.8、进水滤速4.58 m/h条件下,1 t锰矿石脱硫产物可以处理923 tρ(Cu~(2+))=50 mg/L的含铜废水,出水ρ(Cu~(2+))<0.5 mg/L,低于国家一级排放标准.控制进水pH在4～9之间、降低进水滤速、采用较小粒径的材料有利于提高锰矿石脱硫产物处理含铜废水的容量.利用X射线粉末衍射(XRD)和扫描电镜-能谱分析(SEM-EDS)对材料和产物进行表征,证明锰矿石脱硫产物去除水中铜离子是基于离子交换反应的原理.     

Changes of precipitation extremes over South Korea projected by the 5 RCMs under RCP scenarios

The change of extreme precipitation is assessed with the HadGEM2-AO - 5 Regional Climate Models (RCMs) chain, which is a national downscaling project undertaken cooperatively by several South Korean institutes aimed at producing regional climate change projection with fine resolution (12.5 km) around the Korean Peninsula. The downscaling domain, resolution and lateral boundary conditions are held the same among the 5 RCMs to minimize the uncertainties from model configuration. Climatological changes reveal a statistically significant increase in the mid-21st century (2046- 2070; Fut1) and the late-21st century (2076-2100; Fut2) precipitation properties related to extreme precipitation, such as precipitation intensity and average of upper 5 percentile daily precipitation, with respect to the reference period (1981-2005). Changes depending on the intensity categories also present a clear trend of decreasing light rain and increasing heavy rain. In accordance with these results, the change of 1-in-50 year maximum precipitation intensity over South Korea is estimated by the GEV method. The result suggests that the 50-year return value (RV50) will change from -32.69% to 72.7% and from -31.6% to 96.32% in Fut1 and from -31.97% to 86.25% and from -19.45% to 134.88% in Fut2 under representative concentration pathway (RCP) 4.5 and 8.5 scenarios, respectively, at the 90% confidence level. This study suggests that multi-RCMs can be used to reduce uncertainties and assess the future change of extreme precipitation more reliably. Moreover, future projection of the regional climate change contains uncertainties evoked from not only driving GCM but also RCM. Therefore, multi-GCM and multi-RCM studies are expected to provide more robust projection.     

Uncertainty analysis of CO_2 flux components in subtropical evergreen coniferous plantation

We present an uncertainty analysis of ecological process parameters and CO2 flux components (Reco, NEE and gross ecosystem exchange (GEE)) derived from 3 years’ continuous eddy covariance meas-urements of CO2 fluxes at subtropical evergreen coniferous plantation, Qianyanzhou of ChinaFlux. Daily-differencing approach was used to analyze the random error of CO2 fluxes measurements and bootstrapping method was used to quantify the uncertainties of three CO2 flux components. In addition, we evaluated different ...     

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从地理信息系统到虚拟地理环境的认知转变

自20世纪60年代初以来,地理信息系统引领了地理信息的分析与服务。然而,由于地理学家对于地理过程开展多维模拟的需求,同时许多大型工程需要对于不同方案的后果事先开展模拟评估,为此中国学者们在世纪相交之际开始了对于虚拟地理环境的探索。本文从地理信息系统到虚拟地理环境的认识上的转变着手,分析了虚拟地理环境的演进过程、当前的阶段定位与挑战,着重探讨了虚拟地理环境研究的新态势：基于虚拟地理环境的地理空间认知研究、虚拟地理环境与实验地理学新方向、大数据背景下的虚拟地理认知实验方法和虚拟地理环境与地理知识工程,并给出最新研究思路。     

深海浮球内部气压对水下内爆波的抑制机理

深海潜器常携带中空浮球来为其提供浮力。陶瓷因其高强度、低密度等优点成为浮球的理想材料。然而,中空结构在外部高压环境下易发生内爆,产生的内爆波会对周围结构产生毁灭性损害。为了探索浮球内部初始气压对内爆波的影响,首先,利用气泡动力学对其不考虑球壳影响时进行理论分析,得到内爆波压力脉冲沿径向以指数?1 衰减,并指出其物理意义和隐含假设,进而从能量分析得到增加内压使压缩空气消耗的能量增加,从而减弱释放到水中的压力波能量;其次,采用三相流固耦合有限元模型进行计算,考虑水的可压缩性和球壳因挤压引起的脆性破裂的影响,得到更为接近实际的内爆压力的分布。由于两侧挤压球壳,外部的水在不断扩大的缺口处产生向内的射流,造成内部气体非球形塌缩,后续压力波呈现出与球壳碎裂方式有关的方向性差异。通过有限元模型对内部初始气压的研究表明,增加初始内部气体压力到 1 MPa 时,压力脉冲在球壳表面处下降了 15. 6%~24. 8%。这一结果表明,在几乎不增加浮球质量的条件下,增加内部初始气压具有很好地抑制近端内爆波强度的效果。     

Observational evidence for solar coronal decimetric radio pulsations with very short periods

Using the decimetric (700–1500 MHz) radio spectrometer and the synchronous observational system with high temporal resolution at four frequencies (1420, 2130, 2840 and 4260 MHz) of Yunnan Observatory, two rare events were observed on 2001 June 24 and 1990 July 30. The former was a small radio burst exhibiting pulsations with short periods (about 29, 40 and 100 ms) in the impulsive phase. The latter was a large radio burst, which at 2840 MHz produced radio pulsations with period of about 30 ms. This paper focuses on pulsations with very short periods in the range of 29–40 ms. The mechanism of generation of such pulsations may be modulation of radio radiation by the periodic trains of whistler packets originating in unstable regions of the corona. Alternatively, these pulsations can be attributed to wave-wave non-linear interactions of electrostatic upper hybrid waves driven by beams of precipitating electrons in flaring loops.     

工厂化养殖暗纹东方鱼屯致病菌的分离和鉴定

从不同养殖场患病暗纹东方鱼屯(Takifaguobscurus)的鳃、肠、肝、肌肉及溃疡部位分离到9株菌株,经人工感染致病性试验,其T-22、T-11、J-2、H-3、H-5表现出较强的致病性,出现症状与自然发病鱼相同。通过对菌体形态特征、培养特性和API20E细菌生化快速鉴定试条的测定,分别鉴定为温和气单胞菌(Aeromonassobria)、豚鼠气单胞菌(Aeromonascaviae)、嗜水气单胞菌(Aeromonashydrophila)、类志贺邻单胞菌(Plesiomonasshigelloides)、霍乱弧菌(Vibriocholerae)。证实这5株菌为致病菌。药敏试验结果表明9种药物对温和气单胞菌、豚鼠气单胞菌、霍乱弧菌均有较好的抑菌效果;嗜水气单胞菌表现出明显的耐药性。氟嗪酸、环丙沙星、复合磺胺对类志贺邻单胞菌有一定抑菌效果。