Genesis of chlorine and sulphur in fumarolic emissions at Vulcano Island (Italy): assessment of pH and redox conditions in the hydrothermal system

Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P–T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and S_tot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite–magnetite buffer controls the hydrothermal fO₂ values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na–Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl, lowering the pH of the water. The increasing water–rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H₂S and SO₂. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.     

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.     

WEB站点安全性研究

从单密钥加密、公用密钥加密、安全散列、数字签名等网络安全技术出发，讨论了网络通讯中的信息加密、信息完整性以及客户机服务器认证等技术知识。并详细分析了SSL协议工作原理，讨论了如何利用CA数字证书签发机构和SSL协议原理在Internet/Intranet中建立Web安全站点，本文将以Windows NT和UNIX环境为例，详细介绍安全Web站点的配置步骤，充分利用SSL的强大功能，以确保通信双方的信息安全性。     

新04号井、新10号井水位和新10号泉流量地震前兆特征的对比分析

通过分析认为乌鲁木齐地区的年降雨、年气温对新 0 4号井、新 1 0号井水位和新 1 0号泉流量没有明显干扰。新 0 4号井、新 1 0号井和新 1 0号泉的震兆特征是 0 4号井水位为负异常 ,1 0号井水位、1 0号泉流量为正异常 ,产生差异的原因可能与观测点所处的构造环境有关。预测了新疆及邻近地区未来一年或稍长一段时间内有发生 7级左右地震的可能。     

野外简易脱气装置简介

根据水力学原理结合水氡在实验室分析中水样鼓泡脱气的方法 ,进行了大量的野外试验 ,研制开发了野外简易脱气装置。通过几个月的试观测 ,脱气装置气流稳定 ,脱气效率高 ,完全可以满足自动化观测仪器对气量的需求。该装置解决了地下水化学在野外冷水泉无法进行气体观测的难题 ,而且制作简单、费用低廉 ,非常便于推广。     

黄海及其沿岸历史地震初步研究

黄海及其边缘，经历史地震资料整理，地震参数估定与编目，截至1949年8月，共有M≥3级地震2187次，其中M≥43/4级地震259次，资料显示大致有三个相对集中活跃区，16世纪曾有过历史地震活动高潮。     

天山北麓灌溉绿洲的形成和发展

17世纪以前，天山北麓是以牧为主地区，由“兵屯”建立的古代绿洲仅在交通要道呈星、点分布，且屡兴屡废。18－20世纪中叶，由清朝到民国，大力发展屯田，使社会发展进入半农半牧时期，这里形成的旧绿洲，呈断续岛状小片。1949年以后，由大规模农垦建立的新绿洲群，把分散小片旧绿洲联结在一起，形成与天山相平行绿洲带。本区绿洲形成特点是由屯垦和内地移民发展起来，起步虽晚，但发展很快；而且古绿洲、旧绿洲和新绿洲之间有延续性，不象塔里大盆地的很多古代绿洲已沦为沙漠、戈壁或风蚀地。     

金沙江干热河谷土地荒漠化评价方法研究

什么样的退化土地才是荒漠化土地，土地荒漠化的发生发展以及程度和区别等问题的定量确定，至今有关报道甚少。干热河谷是我国西南地区特殊的生态环境类型，自然资源丰富，但土地荒漠化问题十分突出，这一现象的定量认识尤为重要。针对土地景观生态系统的复杂和模糊性，在建立评价指标的基础上，采用模糊综合评判的方法，对土地荒漠化程度进行定量评价，为荒漠化土地的预防和防治提供科学依据和决策支持。     

我国西部地区中小企业发展的环境效应及其约束-引导机制

本文从中小企业发展在我国西部开发中的作用入手 ,针对西部地区生态环境特点及其中小企业发展产生的问题 ,重点分析了中小企业发展与生态环境保护之间的关系 ,对现行的生态环境保护政策的理念进行了全新的思考。明确了促进西部中小企业发展的基本战略 ,并就西部中小企业发展过程中建立非理性作用的约束 -引导机制提出了政策建议。