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A 50-year record of NO<Subscript>x</Subscript> and SO<Subscript>2</Subscript> sources in precipitation in the Northern Rocky Mountains,USA

Ice-core samples from Upper Fremont Glacier (UFG), Wyoming, were used as proxy records for the chemical composition of atmospheric deposition. Results of analysis of the ice-core samples for stable isotopes of nitrogen (δ¹⁵N, ) and sulfur (δ³⁴S, ), as well as and deposition rates from the late-1940s thru the early-1990s, were used to enhance and extend existing National Atmospheric Deposition Program/National Trends Network (NADP/NTN) data in western Wyoming. The most enriched δ³⁴S value in the UFG ice-core samples coincided with snow deposited during the 1980 eruption of Mt. St. Helens, Washington. The remaining δ³⁴S values were similar to the isotopic composition of coal from southern Wyoming. The δ¹⁵N values in ice-core samples representing a similar period of snow deposition were negative, ranging from -5.9 to -3.2 ‰ and all fall within the δ¹⁵N values expected from vehicle emissions. Ice-core nitrate and sulfate deposition data reflect the sharply increasing U.S. emissions data from 1950 to the mid-1970s.     

Lamprophyric lavas in the Colima graben,SW Mexico

The Colima graben, located in SW Mexico, is one of three grabens which intersect about 50 km SSW of Guadalajara, forming a triple junction. The 90 km long, 20–60 km wide Colima graben represents a N-S rift of the E-W trending Mexican Volcanic Belt. Since the Early Pliocene, the Colima graben has served as a locus for the eruption of alkaline lavas, the most recent of which are basanites and minettes erupted from Late Pleistocene cinder cones (Luhr and Carmichael 1981). In this paper, we report on older alkaline lavas which crop out in the graben's walls. These rocks include phlogopite- and hornblende-bearing lamprophyres, a phlogopite-kalsilite-ankaratrite, and high-K andesites. These lavas crop out throughout the Colima graben area, and are intimately associated with calc-alkaline lavas in the field. Compared to these, the alkaline rocks are strikingly enriched in the incompatible elements, particularly Ba, Sr, P, and the LREE. Unlike the younger Late Pleistocene alkaline cinder cone lavas, most of the graben wall lamprophyres and the high-K andesites represent magmas that appear to have undergone significant evolution since their generation, including fractionation, crustal contamination, and possible magma mixing. Least-squares modeling indicates that the cinder cone minettes represent reasonable parental magmas for the graben lamprophyres. The occurrence of these alkaline lavas in an active calc-alkaline volcanic arc is unusual, and we suggest that they are a manifestation of the rifting processes which produced the Colima graben.     

Pseudoleucite in a Tinguaite from the Bearpaw Mountains, Montana

The article presents chemical analyses of the pseudoleuciteand groundmass of a pseudoleucite tinguaite, chemical analysesof the principal minerals, chemical estimates of the mode ofthe groundmass, and both chemical and micrometric modes of thepseudoleucite. The principal minerals are hedenbergitic acmite,a nepheline containing 2.3 per cent Fe₂O₃ and 7.9 per cent K₂O,and K-feldspar containing a little BaO and very little Na₂O.The micrometric mode of the pseudoleucite, in satisfactory agreementwith the chemical mode, is nepheline 29.8 per cent, K-feldspar66.2 per cent, acmite 3.0 per cent; the chemical mode of thegroundmass is nepheline 26.8 per cent, K-feldspar 46.6 per cent,and acmite 26.7 per cent. A new analysis of a nepheline fromthe Bancroft area, made to test the analytical procedure, isalso included.     

Temporal relationship between Holocene human occupation and vegetation change along the northwestern margin of the Central African rainforest

This paper discusses the relationship between patterns of human settlements and environmental change during the Holocene along the northwestern margins of the equatorial rain forest of central Africa. Palaeoenvironmental data from high-resolution sediment cores from lacustrine deposits, plant macro-remains from forest soils, and archaeological data are harnessed to discuss the differential impact of climate and/or humans on the central African rain forest. It is shown that climate change impacted the rain forest well before the widespread expansion of human settlements all over the study area.     

Age and origin of laterite and silcrete duricrusts and their relationship to episodic tectonism in the mid‐north of South Australia∗

Differential earth movements occurred during Eocene, Miocene, and late Caino‐zoic times. The faulting formed basins of sedimentation, led to dissection of land‐surfaces in some localities and burial in others, and faulted the Cainozoic sediments.

Laterite and silcrete cap remnants of relict landsurfaces of two different ages. Laterite formed before the Eocene; it was faulted and dissected during the Eocene in the north but continued to develop until the Miocene in the south. Silcrete formed from Eocene to Miocene times; its dissection was promoted by late Cainozoic tectonism.

Since laterite and silcrete formed on the same strata in warm, very moist environments, lithology and climate are not important genetic factors causing laterite to form at one time and silcrete at another. Only base levels of erosion differed. The silcrete surface was largely developed by streams flowing into mid‐Cainozoic lacustrine basins, whereas there is no evidence that these drainage conditions prevailed for laterite formation.     

Biofilms, microbial mats and microbe-particle interactions: electron microscope observations from diatomaceous sediments

Sediments and diatoms from the mudflats of the Bay of Bourgneuf in western France were examined in an electron microscope study of biofilms and microbial mats. The sediments were kept in an aquarium for study and a diatom culture was made of the benthic diatoms. The sediment biofilm was composed of exopolymeric substances (EPS), incorporated clay particles and, rarely, bacteria. This film coated all particles at the sediment-water interface. Its surface morphology reflected its composition and internal structure. Thin films were smooth, whilst a lumpy structure or incorporated fibrils produced either a mammillated or ropy surface, and clays in the structure gave rise to a flaky morphology. At shallow depths in the sediment column (0.5 cm) the biofilm was already degraded. The biofilm coating degraded diatom frustules in the benthic diatom culture consisted of EPS and bacteria and presented a ragged appearance. Microbial mats occurred on the surface of the fresh littoral sediments as well as those in the aquarium, and on the wall of the aquarium. The mat on the surface of the aquarium sediments had an open structure with webs of fibrils and bacteria in the pore space. It formed in a relatively quiet environment. Pore space was more limited in the mat from the surface of the fresh littoral sediments, in which direct contact between biofilm coated particles was common. In the exposed environment of the aquarium wall there was a thick, resistant coating of EPS. In addition to binding particles together, the presence of mats and biofilms in sediments affects sediment physical properties such as porosity and permeability, the flux of dissolved substances in pore waters and the dissolution of particles and can, therefore, influence early diagenesis. Mats and biofilms seem to be more readily preserved in the geological record than the micro-organisms, such as bacteria, which produce them. Their identification in the sedimentary record would greatly aid interpretation of sediment genesis and evaluation of the microbial role in sediment formation.     

Structure of magnetite lodes at the Estyunino iron deposit in the central Urals

The structure of magnetite lodes is determined by iron and sulfur distribution, as well as texture and structure of ore. These features have been revealed by documentation of cores from ore intervals in exploration boreholes penetrating two main lodes 21 and 22 of the Estyunino iron deposit. The documentation of cores was accompanied by sampling for microscopic examination of texture and structure of ore and selection of Fe and S contents in ore. Then these data were summarized as sections of the lodes. It was established that the structure of magnetite lodes is characterized by conformable ore layers distinguished by texture, structure, and Fe and S contents. Banded and spotty ores containing less than 50% magnetite are predominant. Layers of homogeneous massive ore are infrequent. The textural pattern indicates a volcaniclastic nature of host rocks. The spotty texture is characteristic of hyaloclastites with vitreous shards. The banded texture with oriented distribution of fiamme is inherent to volcaniclastic rocks. In both cases, magnetite selectively replaces dark-colored vitreous fragments and is also dispersed in the salic matrix and lava fragments. No indications of crosscutting superposed relationships are observed. The available data can be satisfactorily explained by an impregnation-metasomatic mode of ore deposition.     

Modelling nitrogen and oxygen isotope fractionation during denitrification in a lacustrine redox-transition zone

The stable isotope composition (δ¹⁵N and δ¹⁸O) of nitrate was measured during Summer 1999 in the anaerobic hypolimnion of eutrophic Lake Lugano (Switzerland). Denitrification was demonstrated by a progressive nitrate depletion coupled to increasing δ¹⁵N and δ¹⁸O values for residual nitrate. Maximum δ¹⁵N and δ¹⁸O values amounted to 27.2 and 15.7‰, respectively.¹⁵N and ¹⁸O enrichment factors for denitrification (ε) were estimated using a closed-system model and a dynamic diffusion-reaction model. Using the Rayleigh equation (closed-system approach), we obtained ε values of −11.2 and −6.6‰ for nitrogen and oxygen, respectively. The average ε values derived using the diffusion-reaction model were determined to be −20.7 ± 3.8 for nitrogen and −11.0 ± 1.7 for oxygen. Both N and O isotope fractionation appeared to be lower when denitrification rates where high, possibly in association with high organic carbon availability. In addition, variations in the isotope effects may be attributed to the variable importance of sedimentary denitrification having only a small isotope effect on the water column. The combined measurement of N and O isotope ratios in nitrate revealed that coupled nitrification-denitrification in the open-water was of minor importance. This is the first study of nitrogen and oxygen isotope effects associated with microbial denitrification in a natural lake. Moreover, this study confirms the high potential of δ¹⁸O of nitrate as a valuable biogeochemical tracer in aquatic systems, complementing nitrate δ¹⁵N.