Vertical geochemical variations and arsenic mobilization in the shallow alluvial aquifers of the Chapai-Nawabganj District, northwestern Bangladesh: implication of siderite precipitation

Core sediments from three disturbed boreholes (JOR, GHAT, and RAJ) and two undisturbed boreholes (DW1 and DW2) were collected in the study area of the Chapai-Nawabganj district of northwestern Bangladesh for geochemical analyses. In the study area, groundwater samples from fourteen As-contained private wells and five nested piezometers at both the DW1 and DW2 boreholes were also collected and analyzed. The groundwater arsenic concentrations in the uppermost aquifer (10–40 m of depth) range from 3 to 315 μg/L (mean 47.73 ± 73.41 μg/L), while the arsenic content in sediments range from 2 to 14 mg/kg (mean 4.36 ± 3.34 mg/kg). An environmental scanning electron microscope (ESEM) with an energy dispersive X-ray spectrometer was used to investigate the presence of major and trace elements in the sediments. Groundwaters in the study area are generally the Ca–HCO₃ type with high concentrations of As, but low levels of Fe, Mn, NO₃ ^? and SO ₄ ^?2 . The concentrations of As, Fe, Mn decrease with depth in the groundwater, showing vertical geochemical variations in the study area. Statistical analysis clearly shows that As is closely associated with Fe and Mn in the sediments of the JOR core (r = 0.87, p < 0.05 for Fe and r = 0.78, p < 0.05 for Mn) and GHAT core (r = 0.95, p < 0.05 for Fe and r = 0.93, p < 0.05 for Mn), while As is not correlated with Fe and Mn in groundwater. The comparatively low Fe and Mn concentrations in some groundwater and the ESEM image revealed that siderite precipitated as a secondary mineral on the surface of the sediment particles. The correlations along with results of sequential extraction experiments indicated that reductive dissolution of FeOOH and MnOOH represents a mechanism for releasing arsenic into the groundwater.     

Geochemistry and Nd,Sr isotopes of the Pohrenk fluorites (Kırsehir-Turkey)

The Pohrenk fluorite mineralisation which makes up Central Anatolia’s most extensive fluorite region is Lutetian aged, and hosted in carbonate rocks that have undergone occasional karstification and silicification along a N–S fault trend. Fluid inclusion values and the position of fluorites in the Tb/La–Tb/Ca diagram show that mineralisation occurred in a hydrothermal environment with homogenisation temperatures ranging from 78.1–363°C. The presence of fluorite as a space filler in carbonate rocks and its association with silicification indicates that the solutions contained considerable amounts of Si alongside F (fluorine). The Pohrenk fluorite samples have ¹⁴³Nd/¹⁴⁴Nd values of between 0.512349 and 0.512497, whilst ⁸⁷Sr/⁸⁶Sr values vary between 0.708161 and 0.708772. These values indicate a mantle origin where continental contamination could occur. When the Nd–Sr values are compared to magmatic and young volcanics, the Pohrenk fluorites are seen to be enriched and exhibit similar isotopic signatures to Upper Cretaceous aged magmatics, Early-Middle Miocene volcanics and Mio-Quaternary volcanics.     

Drop size dependent sulfate distribution in a growing cloud

A simple entraining air parcel model including cloud microphysical and chemical processes is used to calculate the distribution of sulfate over the drop sizes under continental background conditions. Under these conditions the aerosol sulfate is predicted to contribute the largest amount of aqueous sulfate in cloud drops. The sulfate produced by oxidation is found to contribute significantly in drops larger than 10 m radius.     

A fuzzy-Markov-chain-based analysis method for reservoir operation

In this study, a fuzzy-Markov-chain-based stochastic dynamic programming (FM-SDP) method is developed for tackling uncertainties expressed as fuzzy sets and distributions with fuzzy probability (DFPs) in reservoir operation. The concept of DFPs used in Markov chain is presented as an extended form for expressing uncertainties including both stochastic and fuzzy characteristics. A fuzzy dominance index analysis approach is proposed for solving multiple fuzzy sets and DPFs in the proposed FM-SDP model. Solutions under a set of α-cut levels and fuzzy dominance indices can be generated by solving a series of deterministic submodels. The developed method is applied to a case study of a reservoir operation system. Solutions from FM-SDP provide a range of desired water-release policies under various system conditions for reservoir operation decision makers, reflecting dynamic and dual uncertain features of water availability simultaneously. The results indicate that the FM-SDP method could be applicable to practical problems for decision makers to obtain insight regarding the tradeoffs between economic and system reliability criteria. Willingness to obtain a lower benefit may guarantee meeting system-constraint demands; conversely, a desire to acquire a higher benefit could run into a higher risk of violating system constraints.     

Paleomagnetic and palynologic analyses of Albian to Santonian strata at Bayn Shireh, Burkhant, and Khuren Dukh, eastern Gobi Desert, Mongolia

Cretaceous terrestrial sediments deposited in a series of intracratonic basins across the Gobi Desert region of southern Mongolia and northern China contain a unique and diverse vertebrate fauna. In 1996 an expedition jointly sponsored by the Mongolian Paleontological Center and the Hayashibara Museum of Natural Sciences revisited a number of famous vertebrate fossil localities in the eastern Gobi region of Mongolia and, as part of a broad geological and paleontological study, collected a series of paleomagnetic samples from measured sections at Bayn Shireh, Burkhant and Khuren Dukh, as well as from an unmeasured locality adjacent to Khuren Dukh. Expedition members also collected palynologic samples from Khuren Dukh and the adjacent locality. Paleomagnetic analysis shows that all the sites from which samples were collected display detrital remnant magnetization that is consistently normal in polarity. The measured Cretaceous magnetic directions are oriented to the east or northeast of the present day expected direction (declination 356.2°, inclination 65.2°), and they are wholly concordant with that expected for a mid-latitude Northern Hemisphere sampling locality, and with the directions for this period reported by other workers. These results, when considered in tandem with the known biostratigraphy, strongly suggest that the sedimentary deposits at all four localities in the eastern Gobi correlate to the normal polarity chron 34 (the Cretaceous Long Normal), which ranges in age from approximately 121 to 83.5 million years. Previous vertebrate, invertebrate and palynological data from Khuren Dukh suggest that the lower and middle parts of the stratigraphic interval exposed there (which have been assigned to the Shinekhudag Formation) are ‘Khukhtekian’ in age and correspond to the Aptian–Albian interval that can be broadly correlated to the older, Early Cretaceous part of the Cretaceous Long Normal, C34n. New palynologic data presented here indicate that these strata are no older than middle to late Albian. The rocks at Bayn Shireh (the Bayn Shireh Formation) have been assigned a ‘Baynshirenian’ biostratigraphic age that may range from Cenomanian to early Campanian. The magnetostratigraphy results presented here indicate that the strata at both the Bayn Shireh and Burkhant localities do not cross the Santonian/Campanian Stage boundary, however, as this is believed to lie at, or very near, the C34n/C33r reversal boundary. Thus, the Bayn Shireh Formation was most likely deposited near the end of the Cretaceous Long Normal Interval, no later than the latest Santonian.     

Potentiality of Paleocene source rocks and their contribution in generating the accumulated oil in the Eocene Pila Spi Reservoir in Taq Taq Oil Field, Kurdistan Region, Iraq

The organic matters within the Paleocene Aaliji and Kolosh Formations in the well TT-04, Taq Taq Oil Field in Kurdistan Region, NE Iraq have been studied optically and also analytically by means of pyrolysis, Gas Chromatography (GC), and Gas Chromatography/Mass Spectrometry (GC/MS). Amorphous organic matters seemed to be the dominant component of the extracted organic matters within the studied section with an obvious increase of the Phytoclasts at the upper part of Kolosh Formation. Thermal Alteration Index, vitrinite reflectance, pyrolysis, and gas chromatography data all indicated the maturity of the lower part from the studied layers (known generally as Aaliji/Kolosh) and within the early stages of oil generation. Oil–source correlation indicates the possibility of contribution of the Paleocene source rocks in generating the accumulated oil in the Eocene Pila Spi reservoir in the field which also appeared to be a mature and of marine-to-mixed carbonate source. Oil–oil correlation between the oil in Pila Spi and the oil in the Upper Cretaceous reservoirs showed the possibility of existence of more than one source for the two oils. GC/MS analysis for the Pila Spi oil indicated the effect of biodegradation which may be considered as one of the reasons for being the American Petroleum Institute (API) of this oil about 24° while the oil in the Cretaceous reservoirs is of more than 47° API.     

Geotechnical aspects of fine-grained mass flow deposits: California Continental Borderland

Seismic reflection profiling demonstrates the importance of mass movement in the north-central California Borderland. Bulk properties of surficial hemipelagic sediments in the Santa Barbara, Santa Cruz, and San Nicolas basins show that different types of mass-transported sediments have different properties, although their general sedimentologic characteristics are very similar. Slump deposits have moderate water contents (48% wet weight basis), high plasticity indices (46%), and moderate activities (1.6). For debris flows these values are low: 28%, 5%, and 0.3, respectively, and for other types (liquefied flow, mudflows, and turbidities) the values are high: 54 to 63%, 49 to 58%, and 1.2 to 1.5, respectively.     

Wind-driven upwelling and surface chlorophyll blooms in Greater Cook Strait

We present the results of a combined observational and numerical study to investigate cool plumes of nutrient-rich upwelled water that emanate near the Kahurangi Shoals and extend into Greater Cook Strait. Surface temperature and chlorophyll are mapped using satellite observations to produce surface climatologies, to validate a numerical simulation and to show the utility of using spatial temperature differences as a measure of upwelling. We find upwelling near the Kahurangi Shoals is strongly wind-driven in the weather band. Upwelling occurs at all times of the year, but its surface signature is only visible in summer months. The upwelled nutrient-rich water supports increased primary production compared to surrounding waters, particularly in summer when the water column is more stratified and surrounding surface waters are presumably nutrient depleted.     

Advances in the fatigue assessment of wire ropes

This paper presents the findings from an in-depth analysis of the (axial) stiffness data recorded during tension–tension fatigue tests on wire ropes, particularly in relation to how changes in stiffness during testing relate to changes in rope strength. A linear relationship between stiffness and strength is shown to exist and a methodology presented for quantifying residual strength with applied cycles. New lower bound fatigue lines for six-strand rope and spiral strand are presented which are based on a 10% loss of strength. These new lines have the advantage of having been established using a common discard criterion for wire ropes.