Changes in climatic characteristics of Northern Hemisphere extratropical land in the 21st century: Assessments with the IAP RAS climate model

Assessments of future changes in the climate of Northern Hemisphere extratropical land regions have been made with the IAP RAS climate model (CM) of intermediate complexity (which includes a detailed scheme of thermo- and hydrophysical soil processes) under prescribed greenhouse and sulfate anthropogenic forcing from observational data for the 19th and 20th centuries and from the SRES B1, A1B, and A2 scenarios for the 21st century. The annual mean warming of the extratropical land surface has been found to reach 2–5 K (3–10 K) by the middle (end) of the 21st century relative to 1961–1990, depending on the anthropogenic forcing scenario, with larger values in North America than in Europe. Winter warming is greater than summer warming. This is expressed in a decrease of 1–4 K (or more) in the amplitude of the annual harmonic of soil-surface temperature in the middle and high latitudes of Eurasia and North America. The total area extent of perennially frozen ground S _p in the IAP RAS CM changes only slightly until the late 20th century, reaching about 21 million km², and then decreases to 11–12 million km² in 2036–2065 and 4–8 million km² in 2071–2100. In the late 21st century, near-surface permafrost is expected to remain only in Tibet and in central and eastern Siberia. In these regions, depths of seasonal thaw exceed 1 m (2 m) under the SRES B1 (A1B or A2) scenario. The total land area with seasonal thaw or cooling is expected to decrease from the current value of 54–55 million km² to 38–42 in the late 21st century. The area of Northern Hemisphere snow cover in February is also reduced from the current value of 45–49 million km² to 31–37 million km². For the basins of major rivers in the extratropical latitudes of the Northern Hemisphere, runoff is expected to increase in central and eastern Siberia. In European Russia and in southern Europe, runoff is projected to decrease. In western Siberia (the Ob watershed), runoff would increase under the SRES A1B and A2 scenarios until the 2050s–2070s, then it would decrease to values close to present-day ones; under the anthropogenic forcing scenario SRES B1, the increase in runoff will continue up to the late 21st century. Total runoff from Eurasian rivers into the Arctic Ocean in the IAP RAS CM in the 21st century will increase by 8–9% depending on the scenario. Runoff from the North American rivers into the Arctic Ocean has not changed much throughout numerical experiments with the IAP RAS CM.     

Organized bacterial assemblies in manganese nodules: evidence for a role of S-layers in metal deposition

Polymetallic/ferro-manganese nodules (Mn-nodules) reach sizes of up to 10 cm in diameter and are abundantly found on the seabed. To date, the origin of Mn-nodules remains unclear, and both abiogenic and biogenic origins have been proposed. In search of evidence for a contribution of microbial processes to the formation of Mn-nodules, we analyzed those spherical nodules which contain a concentrically banded texture in their interior. The Mn-nodules were collected at a depth of 5,152 m from the Clarion-Clipperton Zone. Our high-resolution scanning electron microscopy analyses reveal first published evidence that endolithic microorganisms exist and are arranged in a highly organized manner on plane mineral surfaces within the nodules. These microorganisms are adorned on their surfaces with S-layers, which are indicative for bacteria. Moreover, the data suggest that these S-layers are the crystallization seeds for the mineralization process. We conclude that the mineral material of the Mn-nodule has a biogenic origin, and hope that these data will contribute to the development of biotechnological approaches to concentrate metals from seawater using bacteria in bioreactors.     

Late Pleistocene to Holocene sedimentation and hydrocarbon seeps on the continental shelf of a steep,tectonically active margin,southern California,USA

Small, steep, uplifting coastal watersheds are prolific sediment producers that contribute significantly to the global marine sediment budget. This study illustrates how sedimentation evolves in one such system where the continental shelf is largely sediment-starved, with most terrestrial sediment bypassing the shelf in favor of deposition in deeper basins. The Santa Barbara–Ventura coast of southern California, USA, is considered a classic area for the study of active tectonics and of Tertiary and Quaternary climatic evolution, interpretations of which depend upon an understanding of sedimentation patterns. High-resolution seismic-reflection data over >570 km² of this shelf show that sediment production is concentrated in a few drainage basins, with the Ventura and Santa Clara River deltas containing most of the upper Pleistocene to Holocene sediment on the shelf. Away from those deltas, the major factor controlling shelf sedimentation is the interaction of wave energy with coastline geometry. Depocenters containing sediment 5–20 m thick exist opposite broad coastal embayments, whereas relict material (bedrock below a regional unconformity) is exposed at the sea floor in areas of the shelf opposite coastal headlands. Locally, natural hydrocarbon seeps interact with sediment deposition either to produce elevated tar-and-sediment mounds or as gas plumes that hinder sediment settling. As much as 80% of fluvial sediment delivered by the Ventura and Santa Clara Rivers is transported off the shelf (some into the Santa Barbara Basin and some into the Santa Monica Basin via Hueneme Canyon), leaving a shelf with relatively little recent sediment accumulation. Understanding factors that control large-scale sediment dispersal along a rapidly uplifting coast that produces substantial quantities of sediment has implications for interpreting the ancient stratigraphic record of active and transform continental margins, and for inferring the distribution of hydrocarbon resources in relict shelf deposits.     

Dependence of the types of coasts and coastal eolian relief on the variations of the sea level using the example of the Caspian Sea

In this work, the history of the development of the Turali area (the Dagestan coast of the Caspian Sea) in the Late Holocene is under consideration. The analysis of the geological structure of the bay bar that separates the Bolshoy Turali lagoon from the sea, the granulometric analysis of the coastal deposits, and the data of geo-radar profiles make it possible to assert that the large eolian relief forms were formed during the New Caspian (Novokaspiyskoe) transgression of the Caspian Sea.     

Diatoms grow faster using ammonium in rapidly flushed eutrophic Dokai Bay,Japan

The importance of the nitrogen source for phytoplankton growth in a highly eutrophic embayment, Dokai Bay, was investigated. The DIN concentration often exceeded 100 μM of which 40–70% was NH₄ ⁺. During two incubation experiments, the natural assemblage of mainly diatoms took up NH₄ ⁺ instead of NO₃ ⁻. The growth of two Skeletonema species isolated in Dokai Bay were significantly faster on NH₄ ⁺ (1.86 and 1.27 div. d⁻¹ respectively) than on NO₃ ⁻ (1.55 and 1.04 div. d⁻¹ respectively). Our results indicated that these diatoms could grow faster by using NH₄ ⁺ compared to NO₃ ⁻ in this eutrophic bay.     

Nonlinear interaction of internal waves in the coastal zone of the Sea of Japan

Nonlinear interactions of the internal waves of a tidal period with low-frequency synoptic-scale internal waves are studied using instrumental measurements of the current in the coastal zone of the Sea of Japan. In the course of spectral analysis of the data of instrumental measurements, it is found that a maximum in the spectrum of the kinetic energy of coastal waters in the vicinity of the semidiurnal frequency ω₀ is surrounded by satellite maxima whose frequencies obey the relation ω _s = ω₀ ± Ω, where Ω is the characteristic frequency of synoptic-scale internal waves. The spectrum of the anticyclonic current component has a similar structure in the vicinities of the frequency ω₀ and its first and second harmonics. The general theory of nonlinear interactions of weakly dispersive waves is used to solve the problem of modulation and the parametric amplification of tidal internal waves in the coastal zone using low-frequency narrow-band internal waviness. As can be judged from the literature, the effect of parametric modulation of tidal internal waves by low-frequency synoptic-scale internal waves has been recorded in the coastal zone of a tidal sea for the first time.     

Winkler's method overestimates dissolved oxygen in seawater: Iodate interference and its oceanographic implications

Dissolved oxygen in seawater has been determined by using the Winkler's reaction scheme for decades. An interference in this reaction scheme that has been heretofore overlooked is the presence of naturally occurring iodate in seawater. Each mole of iodate can result in an apparent presence of 1.5 mol of dissolved oxygen. At the concentrations of iodate in the surface and deep open ocean, it can lead to an overestimation of 0.52 ± 0.15 and 0.63 ± 0.05 μmol kg^− 1 of oxygen in these waters respectively. In coastal and inshore waters, the effect is less predictable as the concentration of iodate is more variable. The solubility of oxygen in seawater was likely overestimated in data sources that were based on the Winkler's reaction scheme for the determination of oxygen. The solubility equation of García and Gordon [Garcia H.E., Gordon, L.I., 1992. Oxygen solubility in seawater: Better fitting equations. Limnol. Oceanogr. 37, 1307–1312] derived from the results of Benson and Krause [Benson, F.B., Krause, D. Jr., 1984. The concentration and isotopic fractionation of oxygen dissolved in freshwater and seawater in equilibrium with the atmosphere. Limnol. Oceanogr. 29, 620–632] is free from this source of error and is recommended for general use. By neglecting the presence of iodate, the average global super-saturation of oxygen in the surface oceans and the corresponding efflux of oxygen to the atmosphere both have been overestimated by about 8%. Regionally, in areas where the degree of super-saturation or under-saturation of oxygen in the surface water is small, such as in the tropical oceans, the net air–sea exchange flux can be grossly under- or overestimated. Even the estimated direction of the exchange can be reversed. Furthermore, the presence of iodate can lead to an overestimation of the saturation anomaly of oxygen in the upper ocean attributed to biological production by 0.23 ± 0.07%. AOU may have been underestimated by 0.52 ± 0.15 and 0.63 ± 0.05 μmol kg^− 1 in the surface mixed layer and deep water, while preformed phosphate and preformed nitrate may have been overestimated by 0.004 ± 0.001 and 0.06 ± 0.02 μmol kg^− 1 in the surface mixed layer, and 0.005 ± 0.0004 and 0.073 ± 0.006 μmol kg^− 1 in the deep water. These are small but not negligible corrections, especially in areas where the values of these parameters are small. At the increasing level of sophistication in the interpretation of oxygen data, this source of error should now be taken into account. Nevertheless, in order to avoid confusion, an internationally accepted standard needs to be adopted before these corrections can be applied.     

Oxidation of copper(I) in seawater at nanomolar levels

The oxidation and reduction of nanomolar levels of copper in air-saturated seawater and NaCl solutions has been measured as a function of pH (7.17–8.49), temperature (5–35 °C) and ionic strength (0.1–0.7 M). The oxidation rates were fitted to an equation valid at different pH and ionic strength conditions in sodium chloride and seawater solutions:

The reduction of Cu(II) was studied in both media for different initial concentrations of copper(II). When the initial Cu(II) concentration was 200 nM, the copper(I) productions were 20% and 9% for NaCl and seawater, respectively. The effect of speciation of copper(I) reduced from Cu(II) on the rates was studied. The Cu(I) speciation is dominated by the CuCl₂⁻ species. On the other hand, the neutral chloride CuCl species dominates the Cu(I) oxidation in the range of 0.1 M to 0.7 M chloride concentrations.     

The tidal flushing of multiple-loop animal burrows

Tidal flushing of animal burrows in mangrove swamps provides an effective and important mechanism for transport of salt and other soluble substances. The burrows have complex morphologies consisting of multiple loops. Using established computational modelling techniques, burrow geometries were simulated from characteristic burrow dimensions and the effect of multiple loops on flushing is studied. The computational models show that flushing is enhanced in multiple-loop burrows as upper loops can be completely evacuated, increasing the volume of burrow water removed. The models indicate that there may be a depth limit to which flushing occurs in complex burrow structures. Periscope loops extend further than one characteristic loop depth and are shown to affect the flushing of burrows if the surface-water plume penetrates to their lower depth. Periscope loops with surface openings on the downstream side of the burrow, relative to the tidal inundation, most frequently experience this condition and thus have a great impact on burrow flushing. Field measurements of salinity agree with the hypothesis that there is a depth limit of flushing for complex burrows that is independent of burrow salinity, and suggest a value of 30–35 cm. The measurements also support the suggestion that significant flushing of burrows occurs within a single tidal event. An experiment considered the movement of animals across the interface created by low-salinity surface water and high-salinity burrow water after a partial flushing event. The motion enhances the effective diffusion coefficient of salt by a factor of at least 10², as compared with free diffusion of salt in water, resulting in a more even distribution of dissolved salt in the burrow water between tidal inundations. This distribution may lead to an increase in the depth to which flushing occurs during subsequent inundations.