Redetermination of the transformation enthalpies of the xanthoconite–proustite, pyrostilpnite–pyrargyrite and trechmannite–smithite phase transitions

 We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol) has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical signals on the amount of substance undergoing the reduction process. Received December 21, 1995/Revised, accepted June 29, 1996     

A Holocene record of climate change,fire ecology and human activity from montane Flat Top Bog,Maui

A sediment core from a high-elevation bog on Maui in the Hawaiian Islands contains evidence for drier conditions between 9.4–5.8 kyr BP, followed by a wetter interval between 5.8–2.2 kyr BP, and a variable late Holocene. These precipitation changes may be a reflection of vertical displacements of the upper boundary of the mid-Pacific Trade Wind Inversion (TWI) cloud layer. Fires, probably volcanically ignited, occurred in the forests prior to human arrival. Polynesian activity in this high-elevation, remote site was apparently limited, with no pollen, charcoal, or sedimentological evidence for local anthropogenic disturbance. After European contact, grass fires increased and introduced plant species invaded the site. Values for Cd, Cu, Pb, and Zn in sediments throughout the Holocene indicate low trace-metal deposition from atmospheric particulates at the site, even in the twentieth century.This paper is one of a series of papers guest edited by Dr. Mark Brenner on tropical paleolimnology     

Wide-angle vibroseis test across the Rhine graben

Summary. As a joint operation of ECORS and DEKORP, a deep wide-angle seismic experiment using vibrators was carried out in the autumn of 1984. The object was to get information on the deep crust under the Rhine graben without crossing through sedimentary layers. Offsets were in the range of 50 to 89 km. In the first phase, two vibration points were executed in the Vosges mountains. A signal was received in the Black Forest from solely the farthest VP. In the second phase, fourteen VPs were executed in the Black Forest. No stacking or correlation was performed in the field in France. The quality of the results is good only if an equalization is applied before vertical stacking and correlation in the computing centre.     

Geochemical processes in a Mediterranean Lake: a high-resolution study of the last 4,000 years in Zoñar Lake,southern Spain

High-resolution geochemical analysis of a 6-m-long sediment core from Zoñar Lake, southern Spain, provides a detailed characterization of major changes in lake and watershed processes during the last 4,000 years. Geochemical variables were used as paleolimnological indicators and complement Zoñar Lakes’s paleoenvironmental reconstruction based on sedimentological and biological proxies, which define periods of increasing allochthonous input to the lake and periods of dominant autochthonous sedimentation. Chemical ratios identify periods of endogenic carbonate formation (higher Ca/Al, Sr/Al and Ba/Al ratios), evaporite precipitation (higher S/Al, Sr/Al ratios), and anoxic conditions (higher Mo/Al, U/Th ratios and Eu anomaly). Higher productivity is marked by elevated organic carbon content and carbonate precipitation (Mg/Ca). Hydrological reconstruction for Zoñar Lake was based on sedimentological, mineralogical and biological proxies, and shows that lower lake levels are characterized by Sr-rich sediments (a brackish lake with aragonite) and S-rich sediments (a saline lake with gypsum), while higher lake levels are characterized by sediments enriched in elements associated with alumino-silicates (Al, K, Ti, Fe, trace and rare earth elements), reflecting fresher conditions. Geochemical indicators also mark periods of higher detrital input to the lake related to human activity in the watershed: (1) during the Iberian Roman Humid Period (650 BC–AD 300), around the onset of the Little Ice Age (AD 1400), during the relatively drier Post-Roman and Middle Ages (AD 800–1400), and over the last 50 years, due to mechanized farming practices. Heavy metal enrichment in the sediments (Cu and Ni) suggests intensification of human activities during the Iberian Roman Period, and the use of fertilizers during the last 50 years.     

Toroidal versus poloidal magnetic fields in Sun-like stars: a rotation threshold

From a set of stellar spectropolarimetric observations, we report the detection of surface magnetic fields in a sample of four solar-type stars, namely HD 73350, HD 76151, HD 146233 (18 Sco) and HD 190771. Assuming that the observed variability of polarimetric signal is controlled by stellar rotation, we establish the rotation periods of our targets, with values ranging from 8.8 d (for HD 190771) to 22.7 d (for HD 146233). Apart from rotation, fundamental parameters of the selected objects are very close to the Sun's, making this sample a practical basis to investigate the specific impact of rotation on magnetic properties of Sun-like stars.
We reconstruct the large-scale magnetic geometry of the targets as a low-order  (ℓ < 10)  spherical harmonic expansion of the surface magnetic field. From the set of magnetic maps, we draw two main conclusions. (i) The magnetic energy of the large-scale field increases with rotation rate. The increase in chromospheric emission with the mean magnetic field is flatter than observed in the Sun. Since the chromospheric flux is also sensitive to magnetic elements smaller than those contributing to the polarimetric signal, this observation suggests that a larger fraction of the surface magnetic energy is stored in large scales as rotation increases. (ii) Whereas the magnetic field is mostly poloidal for low rotation rates, more rapid rotators host a large-scale toroidal component in their surface field. From our observations, we infer that a rotation period lower than ≈12 d is necessary for the toroidal magnetic energy to dominate over the poloidal component.     

A Long-Term Decrease of the Mid-Size Segmentation Lengths Observed in the He <Emphasis Type="SmallCaps">ii</Emphasis> (30.4 nm) Solar EUV Emission

Power spectra of segmentation-cell length (a dominant length scale of EUV emission in the transition region) from full-disk He?ii extreme ultraviolet (EUV) images observed by the Extreme ultraviolet Imaging Telescope (EIT) onboard the Solar and Heliospheric Observatory (SOHO) and the Atmospheric Imaging Assembly (AIA) onboard the Solar Dynamics Observatory (SDO) during periods of quiet-Sun conditions for a time interval from 1996 to 2015 were analyzed. The spatial power as a function of the spatial frequency from about 0.04 to 0.27 (EIT) or up to 0.48 (AIA) Mm^?1 depends on the distribution of the observed segmentation-cell dimensions – a structure of the solar EUV network. The temporal variations of the spatial power reported by Didkovsky and Gurman (Solar Phys. 289, 153, 2014) were suggested as decreases at the mid-spatial frequencies for the compared spectra when the power curves at the highest spatial frequencies of 0.5 pix^?1 were adjusted to match each other. This approach has been extended in this work to compare spectral ratios at high spatial frequencies expressed in the solar spatial frequency units of Mm^?1. A model of EIT and AIA spatial responses allowed us to directly compare spatial spectral ratios at high spatial frequencies for five years of joint operation of EIT and AIA, from 2010 to 2015. Based on this approach, we represent these ratio changes as a long-term network transformation that may be interpreted as a continuous dissipation of mid-size network structures to the smaller-size structures in the transition region. In contrast to expected cycling of the segmentation-cell dimension structures and associated spatial power in the spectra with the solar cycle, the spectra demonstrate a significant and steady change of the EUV network. The temporal trend across these structural spectra is not critically sensitive to any long-term instrumental changes, e.g. degradation of sensitivity, but to the change of the segmentation-cell dimensions of the EUV network structure.     

Comparison of the spatio-temporal dynamics of vegetation between the Changbai Mountains of eastern Eurasia and the Appalachian Mountains of eastern North America

The Changbai Mountains and the Appalachian Mountains have similar spatial contexts. The elevation, latitude, and moisture gradients of both mountain ranges offer regional insight for investigating the vegetation dynamics in eastern Eurasia and eastern North America. We determined and compared the spatial patterns and temporal trends in the normalized difference vegetation index (NDVI) in the Changbai Mountains and the Appalachian Mountains using time series data from the Global Inventory Modeling and Mapping Studies 3rd generation dataset from 1982 to 2013. The spatial pattern of NDVI in the Changbai Mountains exhibited fragmentation, whereas NDVI in the Appalachian Mountains decreased from south to north. The vegetation dynamics in the Changbai Mountains had an insignificant trend at the regional scale, whereas the dynamics in the Appalachian Mountains had a significant increasing trend. NDVI increased in 55% of the area of the Changbai Mountains and in 95% of the area of the Appalachian Mountains. The peak NDVI occurred one month later in the Changbai Mountains than in the Appalachian Mountains. The results revealed a significant increase in NDVI in autumn in both mountain ranges. The climatic trend in the Changbai Mountains included warming and decreased precipitation, and whereas that in the Appalachian Mountains included significant warming and increased precipitation. Positive and negative correlations existed between NDVI and temperature and precipitation, respectively, in both mountain ranges. Particularly, the spring temperature and NDVI exhibited a significant positive correlation in both mountain ranges. The results of this study suggest that human actives caused the differences in the spatial patterns of NDVI and that various characteristics of climate change and intensity of human actives dominated the differences in the NDVI trends between the Changbai Mountains and the Appalachian Mountains. Additionally, the vegetation dynamics of both mountain ranges were not identical to those in previous broader-scale studies.     

Distribution of the indigenous microorganisms and mechanisms of their orientational activation in Daqing Oilfield

The distribution of indigenous microorganisms was surveyed in Block 1 of Daqing Oilfield. Based on this survey, the indigenous microorganisms in the formation water were activated with different activator systems at the simulated stratum ecological environment. The changes of the number of bacteria of various physiological groups were determined during the process of activation. Also changes of pH value and composition of gas productions were analyzed at the end of culturing. The results showed that the selected block formation water contained a great number of saprophytic bacteria, hydrocarbon-oxidizing bacteria, fermentative bacteria, methane-producing bacteria and sulfate-reducing bacteria. Under the conditions that the growth of sulfate-reducing bacteria was controlled the block had the potential to enhance oil recovery by activating beneficial bacteria. The growth of sulfate-reducing bacteria can be inhibited through the activation of nitrate-reducing bacteria. The number of nitrate-reducing bacteria reached 10⁶–10⁷ cells/mL, but sulfate-reducing bacteria reached only 0–45 cells/mL in A system. Methane-producing bacteria can be activated by C, D activators. The relative content of biological methane in the light hydrocarbon gas reached 80% in C, D systems. B activator was conducive to the propagation of acid-producing bacteria, so that the pH value of the culture medium decreased from 7.5 to around 5.0. Hydrocarbon-oxidizing bacteria can be activated by various activator systems. There was low molecular light hydrocarbon in gas production according to the analysis of gas chromatograph. According to the content of methane and the number of methane-producing bacteria, methane only can be generated through activating methane-producing bacteria. By choosing different activator systems, various populations of indigenous microorganisms can be activated accordingly.     

Relationships between Holocene sea-level variations,trophic development,and climatic change in Negra Lagoon,Southern Uruguay

Paleolimnological data are presented on trophic development, climatic change and sea level variations in Negra Lagoon, a 142 km² coastal lagoon in southern Uruguay. Using a sediment core that extended to the early Holocene, analyses of organic matter, carbonate, diatoms and opal phytoliths allowed us to track changes in trophic state and paleosalinity levels, which were closely related to Holocene sea level variation, temperature and humidity. Diatom Association Zones (DAZ) corresponding to transgressive events were dominated by marine/brackish taxa and relatively low organic matter values, while those DAZ corresponding to regressive events showed increases in brackish/freshwater diatoms and organic matter. Opal Phytoliths Association Zones (OPAZ) also were identified, temperature and humidity indices were calculated, and climatic trends were inferred. During the middle Holocene (i.e., ~5000–4000 yr BP), cool–dry climatic conditions were established. After ~4000 yr BP, a transition from cool to warm–humid conditions was observed, but fully warm humid conditions established only after ~1700 yr BP. Such climatic amelioration led to increases in trophic state.     

Photoelectric device for monitoring the movement of a torsion balance beam

Manufactured and tested in his work is a photoelectric device that makes it possible to automatically determine the relative angular position of the beam of a miniature torsion balance, angular readings being discretized with various time step values and stored in a computer. Measurements were taken with this device that captured the occurrence of the partial solar eclipse on September 11, 2007, and confirmed the fact, established previously through visual observation, that the position of torsion balance beams changed at the instant an eclipse took place.