Seasonal variations in the speciation of dissolved iodine in the Chesapeake Bay

The speciation of dissolved iodine and the distributions of the iodine species in the deep Chesapeake Bay underwent seasonal variations in response to changes in the prevailing redox condition. In the deep water, the ratios of iodate to iodide and iodate to inorganic iodine decreased progressively from the Winter through the Summer as the deep water became more poorly oxygenated before they rebounded in the Fall when the deep water became re-oxygenated again. The composition of the surface water followed the same trend. However, in this case, the higher biological activities in the Spring and the Summer could also have enhanced the biologically mediated reduction of iodate to iodide by phytoplankton and contributed to the lower ratios found during those seasons. Superimposed on this redox cycle was a cycle of input and removal of dissolved iodine probably as a result of the interactions between the water column and the underlying sediments. Iodine was added to the Bay during the Summer when the deep water was more reducing and removed from the Bay in the Fall when the deep water became re-oxygenated. A third cycle was the inter-conversion between inorganic iodine and ‘dissolved organic iodine’, or ‘‘DOI’’. The conversion of inorganic iodine to ‘DOI’ was more prevalent in the Spring. As a result of these biogeochemical reactions in the Bay, during exchanges between the Bay and the North Atlantic, iodate-rich and ‘DOI’-poor water was imported into the Bay while iodide- and ‘DOI’-rich water was exported to the Atlantic. The export of iodide from these geochemically reactive systems along the land margins contributes to the enrichment of iodide in the surface open oceans.     

The effect of copper pollution on mitochondrial degeneration

The authors describe the effect of copper pollution on the mitochondria from various areas of the Torpedo marmorata central nervous system. A high percentage of swollen mitochondria has been observed in neurons from animals experimentally exposed to high level of copper (4 ppm). The correlation with age pigment granules is discussed.     

Remote determination of momentum-flux profiles in the lower atmospheric boundary layer

An acoustic locator—a sodar—is a unique instrument for getting the objective characteristics of the current state of the atmospheric boundary layer (ABL) owing to a combination of such properties as remoteness, mobility, resolution, and information content. This study demonstrates the capabilities of a sodar to obtain data on the second moments of the field of wind-velocity fluctuations, in particular, the profiles of momentum flux in the lower ABL, which are very important in practical applications. A corresponding method is described, and the results of its experimental verification and some examples of its application under the conditions of different ABL stratification are presented.     

Nitrate assimilation by zooxanthellae maintained in laboratory culture

The ability of cultured zooxanthellae to use ammonium and nitrate was tested. The zooxanthellae were initially isolated from the anemone Aiptasia pulchella. The zooxanthellae were able to grow on media supplemented with either form of dissolved inorganic nitrogen (DIN) although ammonium was inhibitory above 300 μM. In accord with the intact symbiosis and freshly isolated algae, the cultured zooxanthellae took up ammonium. In contrast, the cultured algae demonstrated nitrate uptake and utilization. This was enhanced with DIN deprivation. Nitrate reductase was found in the algae and appeared to be inducible. Within the animal host, excretory ammonium may repress this induction.     

Oxidative stress in ecotoxicology: from the analysis of individual antioxidants to a more integrated approach

An integrate approach will be discussed for investigations on oxidative stress in xenobiotic toxicity. While the analysis of individual antioxidants is useful for their sensitivity and to understand the mode of action of a stressor, the integration with the analysis of the total antioxidant capacity provides a more holistic assessment of the overall biological significance of such variations. TOSC has a greater predictive value on the health condition of the organisms and allows to discriminate the different role of specific ROS in oxidative stress syndrome.     

Distribution of trace and major elements in sediment and pore waters of the Lena Delta and Laptev Sea

Sediment cores collected during the SPASIBA expedition in 1991 were analysed for their trace- and major element concentrations. Leachable (0.1 N HCl) as well as residual concentrations were determined. Fe and Mn were measured in the interstitial waters to characterize redox conditions. Lateral distribution patterns of solid phase Cu, Cd, Ni, Pb and Zn show a small increase in concentration from the Lena Delta in seaward direction. In general concentrations of these metals are very low and similar to natural background values. With some exceptions, solid phase profiles with depth of all investigated elements do not show strong variations. No enrichment of Pb and Zn in surface layers was found. Remobilization processes and transport of particles enriched in Mn are responsible for Mn accumulation in a particular area. Pore-water concentrations of dissolved Mn in the latter sediments are very high (> 700 μM) and suggest strong Mn reduction directly below the sediment-water interface. In contrast to Mn, the depth profiles of Cd show a surface layer with lower concentrations and an increase deeper down the sediment. The C/N ratio in the sediment decreases from 13 in the Lena mouth to 9 in the more marine part of the Laptev Sea. Surface sediments in the Laptev Sea are very uniform and homogeneous and show only small concentration gradients.     

X-band sea-clutter nonstationarity: influence of long waves

In this paper, we deal with the problem of modeling the backscattering from sea surface for low-grazing-angle and high-resolution radar systems. Based on the electromagnetic two-scale model, we analyzed both the amplitude and frequency modulations induced on the small-scale Bragg resonant waves by the large-scale surface tilt and advection due to the swell presence. Evidence of sea-clutter nonstationarity has been verified and the relationship between the variations of clutter spectral features, such as texture, Doppler centroid, and bandwidth, have been studied by processing real sea-clutter data recorded by the IPIX radar of McMaster University, Hamilton, ON, Canada. An autoregressive nonstationary process is proposed and validated to model the physical phenomenon.     

Design of a tri-axial thrust anemometer for measurement of atmospheric turbulence over water

The BIO Mark 8 thrust anemometer measures the drag of the wind on a perforated table tennis ball mounted on a vertical beam. The tri-axial displacement of the beam is sensed by eddy current proximity sensors. This anemometer has a flat frequency response from 0 to 10 Hz and can measure wind from 0 to 28 m s⁻¹ at temperature from − 19 to + 28°C. It is designed for remote operation for extended periods of time such as on stable towers at sea.     

Nitrate reductase activity and the speciation of selenium at the mouth of Chesapeake bay

Nitrate reductase activity and the concentrations of selenite and selenate were monitored for six months at the mouth of Chesapeake Bay (USA). A positive correlation was found between nitrate reductase activity and the concentration of selenite, suggesting that selenite may be formed in coastal waters and nitrate reductase may be involved in the process.