The role of organic coatings in the enrichment of marine particles with selenium. The fixation of selenite on an adsorbed amino acid

The enrichment of marine particles with selenium cannot be explained as that with metals present in cationic form by complexation with anionic functional groups of adsorbed organic matter. Physicochemical data obtained using a model system are reported. The surface of the particles is modelized by a mercury electrode whose surface charge density can be easily changed, covered by a layer of adsorbed polymers. Studies with different kinds of macromolecules and salts show a specific interaction between adsorbed polyalanine and selenite. The results can be explained by the concordance of the distances between two oxygen atoms in this oxyanion and between two amine groups of the adsorbed polypeptide. A similar mechanism could occur in marine aggregates whatever their nature, as long as they contain amine groups at their surface which result in this concordance. Some prospects derived from the results are discussed.     

Interaction of internal waves with a horizontally inhomogeneous density field area overlying a ridge

In the context of the general linear theory, we consider the propagation of an internal tide across a frontal zone overyling an oceanic ridge. For a uniformly stratified ocean, the solution was derived using Riemann's technique. The dependences of the generated internal wave amplitudes on the stratification parameters and bottom topography were determined. We have found that wave disturbances of high intensity inside and in the neighbourhood of the ridge may be concentrated in raytype areas. An increase of the horizontal density gradient in the frontal zone results in a perceptible deformation of these areas.Translated by Vladimir A. Puchkin.     

Mediterranean outflow through the Strait of Gibraltar since 18,000 Years B.P.: Mineralogical and geochemical arguments

Data obtained from mineralogical and geochemical analyses of piston and gravity cores, recovered from an area off Lisbon (Portugal) to the Alboran Sea (Mediterranean), serve as a basis for better understanding the past 18,000 years of hydrological exchanges at Gibraltar. Tracers used in this study are smectite, kaolinite, Ta, Th, La. One of the primary sources of particles both into and out of the Mediterranean is the Guadalquivir River. These particles are transported back into the Atlantic in the Mediterranean outflow water, and deposited along the Iberian slope. No evidence for reversal of this outflow current was found in those cores, since 18,000 years B.P.     

Metal accumulation in mussels of the Kuril Islands, north-west Pacific Ocean

Concentrations of cadmium, copper, iron, lead, manganese, nickel and zinc were investigated in two species of mussel from the Kuril Islands in the north-western Pacific Ocean: the short-lived mussel Mytilus trossulus and the much larger and longer-lived Crenomytilus grayanus. The concentrations of most elements were low, and these reported levels are believed to reflect background values for pristine locations. However, both iron and zinc concentrations were elevated in some samples taken from areas of hydrothermal vent activity, and these are believed to reflect the enrichment of the two metals in solution at such sites. Furthermore, the concentrations of cadmium were unusually elevated in both species of mussel, especially in the longer-lived C. grayanus. The high accumulation of cadmium in mussels from the Kuril Islands is believed to reflect regional upwelling, but it is also postulated that filtration rates of the mussels are high due to low levels of suspended matter, and this leads to a high assimilation efficiency for cadmium. The distribution of cadmium amongst the tissues of C. grayanus is also reported, and the need for further ecotoxicological studies in the area is proposed.     

Significance of pteropods in deciphering the late Quaternary sea-level history along the southwestern Indian shelf

The paper evaluates the usefulness of pteropods in palaeobathymetric synthesis along the southwestern continental shelf of India. Core samples collected from the shelf off north Kerala (SW coast of India) were studied for faunal assemblages (pteropods and foraminifers), calcium carbonate contents and lithological characteristics. A fundamental precept for considering any organism as a bathometer is that it should be highly sensitive to changing water depths. To ascertain this, the bathymetric distribution patterns of modern pteropods as well as planktonic and benthic foraminifers were recorded in core-top samples. The results reveal that certain pteropod species (Limacina inflata, Creseis acicula, Creseis virgula, and Creseis chierchiae) are highly depth sensitive. The response of these species to depth changes was assessed in terms of the L. inflata and Creseis spp. abundance ratio. A model for the relationship between water depths and the L. inflata/Creseis spp. ratio is proposed for the southwestern shelf of India. Variations of benthic/planktonic foraminifers (BF/PF) and pteropods/planktonic foraminifers (Pt/PF) in the modern sediments were also found to be depth controlled. Two sediment cores, representing the last 36,000 and 23,000 years, were collected to investigate past sea-level changes. These cores comprised two distinct lithological units, the upper unit corresponding to the Holocene, and the lower unit to the last glacial period. The L. inflata/Creseis spp. model was successfully applied to the fossil record for reconstructing the palaeobathymetry of the shelf study locations. Down-core variations in the BF/PF and Pt/PF ratios support these inferred sea-level changes. Major periods of sea-level oscillations were also found to have a strong influence on the calcium carbonate distribution. For both core sites, the palaeobathymetric curves reflect consistency in terms of changing sea level. The results suggest that the sea level stood around 100 m below the present mean sea level during the last glacial maximum. A rapid rise in sea level was documented between 15 and 10 ka B.P. The sea-level rise has been slower since 7 ka B.P.     

Tectonics at the intersection of the East Pacific Rise with Tamayo Transform fault

During the Fall of 1979, a manned submersible program, utilizing DSRV ALVIN, was carried out at the intersection of the East Pacific Rise (EPR) with the Tamayo Transform boundary. A total of seven dives were completed in the vicinity of the EPR/Tamayo intersection depression and documented the geologic relationships that characterize the juxtaposition of these types of plate boundaries. The young volcanic terrain of the EPR axis can be traced into and across the Tamayo Transform valley but becomes buried by sedimentary talus that is being shed from sediment scarps along the unstable sediment slope that defines the north side of the intersection depression. Within 4 km of the transform boundary, the dominant trend (000°) of the fissures and faults that disrupt the rise-generated volcanics is markedly oblique to the regional direction of sea floor spreading (120°). Since no evidence was found to suggest that these structures accommodate significant amounts of strike-slip displacement, they are taken to reflect a distortion of the EPR extensional tectonic regime by a transform generated shear couple. The floor of the Tamayo Transform valley in this area is inundated by mass-wasted sediment, and the principal transform displacement zone is characterized at the surface by a narrow (<1.5 km) interval of fault scarps in sediment that trends parallel with the transform valley. Extrapolated to the west, this zone links with zones of transform deformation investigated during earlier submersible studies (CYAMEX and Pastouret, 1981). Evidence of low-level hydrothermal discharge was seen at one locality on the EPR axis and at another 8 km west of the axis at the edge of the zone of transform deformation.     

A hydrodynamic model of a submerged lenticular wave energy device

The wavemaking capability and energy absorbing characteristics of a single submerged body, constrained to move horizontally in a surge mode, are examined. The body possesses both a vertical axis of symmetry and a horizontal plane of symmetry and is ‘thin’ in the sense that the body draft is small compared to the length. The behaviour of a single body subject to a constraint being placed upon the amplitude of its displacement and the properties of an array of interacting identical devices are also discussed.     

3,4-benzopyrene and perylene in mussels, Mytilus sp., from the Laguna Veneta,North-East Italy

From July, 1975 to November, 1976 mussels from the Laguna Veneta, north-east Italy, and the adjacent Adriatic Sea were collected bimonthly at ten stations and analysed for 3,4-benzopyrene (BaP) and perylene (Pe) content. Mean concentrations were in the range 12·0–135·1 μg/kg dry weight for BaP and 1·5–16·9 μg/kg for Pe, but values as high as 327 μg/kg for BaP and 71 μg/kg for Pe have been measured. The distribution of BaP and Pe closely matches previous results on petroleum hydrocarbon contamination in mussels from this area and indicates that the major portion of BaP and Pe in these bivalves is due principally to human activities.