Simple determination of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) using solid-phase microextraction and gas chromatography-mass spectrometry

Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide (DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity (minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation ≤7%) and linearity (r ² > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity.     

High-resolution measurements of chromophoric dissolved organic matter in the Mississippi and Atchafalaya River plume regions

Chromophoric dissolved organic matter (CDOM) was measured in the spring and summer in the northern Gulf of Mexico with the ECOShuttle, a towed, instrumented, undulating vehicle. A submersible pump mounted on the vehicle supplied continuously flowing, uncontaminated seawater to online instruments in the shipboard laboratory and allowed discrete samples to be taken for further analysis. CDOM in the northern Gulf of Mexico was dominated by freshwater inputs from the Mississippi River through the Birdfoot region and to the west by discharge from the Atchafalaya River. CDOM was more extensively dispersed in the high-flow period in the spring but in both time periods was limited by stratification to the upper 12 m or so. Thin, subsurface CDOM maxima were observed below the plume during the highly stratified summer period but were absent in the spring. However, there was evidence of significant in situ biological production of CDOM in both seasons.The Mississippi River freshwater end member was similar in spring and summer, while the Atchafalaya end member was significantly higher in the spring. In both time periods, the Atchafalaya was significantly higher in CDOM and dissolved organic carbon (DOC) than the Mississippi presumably due to local production and exchange within the coastal wetlands along the lower Atchafalaya which are absent along the lower Mississippi. Nearshore waters may also have higher CDOM due to outwelling from coastal wetlands. High-resolution measurements allow the differentiation of various water masses and are indicative of rapidly varying (days to weeks) source waters. Highly dynamic but conservative mixing between various freshwater and marine end members apparently dominates CDOM distributions in the area with significant in situ biological inputs (bacterial degradation of phytoplankton detritus), evidence of flocculation, and minor photobleaching effects also observed. It is clear that high-resolution measurements and adaptive sampling strategies allow a more detailed examination of the processes that control CDOM distributions in river-dominated systems.     

Record-breaking chemical destruction of ozone in the arctic during the winter of 2004/2005

The extremely cold winter of 2004/2005 was accompanied by an intensive formation of polar stratospheric clouds and a significant chemical destruction of ozone. The results of calculating chemical losses of ozone in the polar cyclone from the SAGE-III satellite data are given. Over the period January 1–March 25, 2005, at the isentropic levels 450–500 K, about 60% of ozone was destroyed. During that winter, the zone of formation of polar stratospheric clouds went down to levels with very low values of potential temperature (down to 350 K), thus resulting in a noticeable destruction of ozone at low altitudes. By March 25, 2005, the chemical losses of total ozone attained 116 ± 10 DU (128 ± 10 DU at the cyclone boundary), which is a recordbreaking value of the Arctic.     

Numerical simulation of a quasi-tropical cyclone over the Black Sea

The paper describes results of numerical experiments on the simulation of a mesoscale quasi-tropical cyclone, a rare event for the Black Sea, with the MM5 regional atmospheric circulation model. General characteristics of the cyclone and its evolution and physical formation mechanisms are discussed. The balances of the momentum components have been estimated, and sensitivity experiments have been performed. It is shown that, according to its main physical properties and energy supply mechanisms, the cyclone can be related to quasi-tropical cyclones.     

Determination of temperature and humidity of air,wind speed,and sensible and latent heat fluxes on the ocean surface according to the satellite data

Formulas for the evaluation of temperature and humidity of air, wind speed, and sensible and latent heat fluxes on the ocean surface according to the satellite data on the sea-surface temperature and cloudiness are deduced on the basis of the analysis of many-year radiosonde, meteorological, shipborne, and satellite data. The proposed formulas can also be used for the interpretation of the results of remote sensing of the ocean and atmosphere by radiometers in the visible, infrared, and microwave regions. The transformations of radiation and sensible and latent heat fluxes are described depending on the sea-surface temperature for various cloudiness conditions. The computed values of the amount of water in the atmosphere agree with the radiosonde data obtained throughout the Earth, including the data of research vessels and stationary weather ships, as well as the data obtained in the ATEP test ranges and in the Arctic. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 2, pp. 56–70, March–April, 2007.     

Method and results of assimilation of climatic data on temperature,salinity, and sea level into a numerical model of the Black Sea

A method for combined assimilation of climatic hydrologic fields of temperature, salinity, and the climatic dynamic level of the Black Sea into a model of sea dynamics is proposed. The monthly mean fields of the dynamic sea level were obtained from the results of assimilation of satellite altimetry data into the model. The statistical characteristics of errors in the forecasts of the level, salinity, and temperature were assumed to be proportional to the statistical characteristics of the differences between monthly mean climatic fields of temperature, salinity, and sea level calculated by means of assimilating altimetry observations of the sea level and analogous climatic hydrologic fields. The climatic fields of currents are reconstructed and analyzed. The assimilation of the climatic altimetry level allows the reproduction (in current fields) of quasi-stationary synoptic anticyclonic eddies located along the periphery of the Black Sea Rim Current.     

Spatial variability in growth and reproduction of the Pacific oyster Crassostrea gigas (Thunberg, 1793) along the west European coast

The Pacific oyster Crassostrea gigas was introduced in Europe for commercial purposes in the mid 1960s. It was initially thought that low winter temperatures would restrain this species' reproduction and settlement; however, its present distribution in areas where no introduction has taken place suggests that natural invasion and expansion has occurred. Along the European coast, wild populations of Pacific oysters are already found from northern Germany to southern Portugal. Whether C. gigas will continue to further expand through northern waters will depend on its physiological performance. In this study, the performance of wild oyster populations has been studied in terms of growth and reproduction at three stations: La Rochelle (France; 46°N), Yerseke (Oosterschelde estuary, The Netherlands, 51°N), and Texel (Wadden Sea estuary, The Netherlands, 53°N). The French population had the lowest somatic-shell mass ratio and an increase in maximum shell length, somatic and gonadal mass was observed from France to the Netherlands. In addition, mean oocyte diameter decreased significantly from south to north. The combination of increasing gonadal mass and decreasing oocyte volume suggests an increasing reproductive output in terms of egg numbers from France to The Netherlands. Differences in temperature between locations will at least be partly responsible for the observed patterns; however, other environmental factors (such as food availability, predation pressure, sediment type and/or seston concentration) cannot be excluded. Since smaller eggs (oocytes) are thought to have a longer development time, the environmental conditions along the Dutch coast may result in increased larval dispersal and possibly in further population expansion.     

Growth and reproduction of the bivalve Spisula subtruncata (da Costa) in Dutch coastal waters

The bivalve Spisula subtruncata is usually abundant in shallow coastal waters along the Dutch coast. However, its biomass has been decreasing since 1995. In order to assess whether reproductive failure may be the cause of the observed decline over the last decades, the energy investment in reproduction of a population of S. subtruncata from central Dutch coastal waters was studied. The population studied consisted of individuals of up to four years old. Shell length reached maximum values of around 32 mm and individual total body, somatic and gonadal ash-free dry mass reached maximum values of about 278 mg AFDM, 252 mg AFDM and 76 mg AFDM, respectively. A clear seasonal cycle in somatic and gonadal mass was observed. Somatic and gonadal mass indices increased in early spring and reached maximum values during summer, followed by a decrease to minimum values at the beginning of the following year. Spawning was in June–July and settlement of spat seems to have occurred in July–August. Mean oocyte diameter was 57.43 ± 0.03 μm, corresponding to a volume of 98972 μm³. These results suggested that reproductive failure was not the cause of the current population decline. Most likely, unsuccessful settlement of spat and/or severe predation during the first months of life were responsible for the observed patterns.