Thermal history of the Hodgkinson Province and Laura Basin,Queensland: Multiple cooling episodes identified from apatite fission track analysis and vitrinite reflectance data

Apatite fission track analysis and vitrinite reflectance data from outcrop and well samples in the Hodgkinson Province and Laura Basin reveal regional Cretaceous cooling. Apatite fission track analysis appears to define two discrete cooling episodes, in the mid‐Cretaceous (110–100 Ma) and Late Cretaceous (80–70 Ma), although in most samples data allow only definition of a single episode. Rocks now at outcrop cooled from Cretaceous palaeotemperatures generally between 50 and 130°C in the south of the region, and from >100°C in the north. Some samples from the Hodgkinson Province also show evidence for an Early Jurassic cooling episode, characterised by maximum palaeotemperatures varying from at least 95°C (from apatite fission track analysis) to ～200–220°C (from vitrinite reflectance), with cooling beginning at around 200 Ma. Apatite fission track analysis data do not reveal the earlier event in the Laura Basin, but on the basis of vitrinite reflectance data from Permian? units this event is also inferred to have affected the pre‐Jurassic basin units in this region. The regional extent of the Cretaceous cooling episode in the Hodgkinson Province suggests that the elevated palaeotemperatures in this region were most likely due to greater depth of burial, with subsequent cooling due to kilometre‐scale denudation. For a palaeogeothermal gradient of 30°C/km and a palaeosurface temperature of 25°C the total degree of Cretaceous cooling experienced by the samples corresponds to removal of between ～0.8 and >3.0 km of Triassic and younger section removed by denudation, beginning some time between ca 110 and 80 Ma. Higher palaeogradients would require correspondingly lower amounts of removed section. The geology of the Laura Basin suggests that an explanation of the observed Cretaceous palaeotemperatures in this region in terms of deeper burial may be untenable. Heating due to hot fluid flow may be a more realistic mechanism for producing the observed Cretaceous palaeothermal effects in the Laura Basin.     

A flood vulnerability index for coastal cities and its use in assessing climate change impacts

Worldwide, there is a need to enhance our understanding of vulnerability and to develop methodologies and tools to assess vulnerability. One of the most important goals of assessing coastal flood vulnerability, in particular, is to create a readily understandable link between the theoretical concepts of flood vulnerability and the day-to-day decision-making process and to encapsulate this link in an easily accessible tool. This article focuses on developing a Coastal City Flood Vulnerability Index (CCFVI) based on exposure, susceptibility and resilience to coastal flooding. It is applied to nine cities around the world, each with different kinds of exposure. With the aid of this index, it is demonstrated which cities are most vulnerable to coastal flooding with regard to the system??s components, that is, hydro-geological, socio-economic and politico-administrative. The index gives a number from 0 to 1, indicating comparatively low or high coastal flood vulnerability, which shows which cities are most in need of further, more detailed investigation for decision-makers. Once its use to compare the vulnerability of a range of cities under current conditions has been demonstrated, it is used to study the impact of climate change on the vulnerability of these cities over a longer timescale. The results show that CCFVI provides a means of obtaining a broad overview of flood vulnerability and the effect of possible adaptation options. This, in turn, will allow for the direction of resources to more in-depth investigation of the most promising strategies.     

Determination of Selenium in Thirty-Two Geochemical Reference Materials by Continuous - Flow Hydride Generation Atomic Absorption Spectrophotometry

A continuous-flow hydride atomic absorption spectrophotometric method has been applied to 32 geochemical reference materials for the determination of selenium. The sample is decomposed with a mixture of nitric, perchloric and hydrofluoric acids. Selenium values obtained in this study are in general agreement with literature values and provide additional certification for these reference materials. The precision of the method is generally better than 5% relative standard deviation. The lower limit of determination of selenium in the sample is 12 ppb.     

Carbonate ramp-to-deeper shale shelf transitions of an Upper Cambrian intrashelf basin, Nolichucky Formation, Southwest Virginia Appalachians

The Nolichucky Formation (0–300 m thick) formed on the Cambrian pericratonic shelf in a shallow intrashelf basin bordered along strike and toward the regional shelf edge by shallow water carbonates and by nearshore clastics toward the craton. Lateral facies changes from shallow basinal rocks to peritidal carbonates suggest that the intrashelf basin was bordered by a gently sloping carbonate ramp. Peritidal facies of the regional shelf are cyclic, upward-shallowing stromatolitic carbonates. These grade toward the intrashelf basin into shallow ramp, cross-bedded, ooid and oncolitic, intraclast grain-stones that pass downslope into deeper ramp, subwave base, ribbon carbonates and thin limestone conglomerate. Ribbon limestones are layers and lenses of trilobite packstone, parallel and wave-ripple-laminated, quartzose calcisiltite, and lime mudstone arranged in storm-generated, fining upward sequences (1–5 cm thick) that may be burrowed. Shallow basin facies are storm generated, upward coarsening and upward fining sequences of green, calcareous shale with open marine biota; parallel to hummocky laminated calcareous siltstone; and intraformational flat pebble conglomerate. There are also rare debris-flow paraconglomerate (10–60 cm thick) and shaly packstone/wackestone with trace fossils, glauconite horizons and erosional surfaces/hardgrounds. A 15-m thick tongue of cyclic carbonates within the shale package contains subtidal digitate algal bioherms which developed during a period of shoaling in the basin. Understanding the Nolichucky facies within a ramp to intrashelf basin model provides a framework for understanding similar facies which are widely distributed in the Lower Palaeozoic elsewhere. The study demonstrates the widespread effects of storm processes on pericratonic shelf sedimentation. Finally, recognition of shallow basins located on pericratonic shelves is important because such basins influence the distribution of facies and reservoir rocks, whose trends may be unrelated to regional shelf-edge trends.     

Large-scale farming as a cultural dilemma in U.S. rural development— The role of capital

Although agressive economic traditions have benefited U.S. agricultural fortunes enormously in the past, expanding farming scale now also seriously threatens equally-prized rural traditions extolling the values of family farming. To see in detail how strongly and in what ways large-scale farming is exerting its influence across the nation, a multivariate model was applied to county census data. Emphasized were forces of capital accumulation rather than traditional single criteria like farm size or incorporation. Results uniformly dispute the argument for continued vigor of the family farm. Smaller operators are not only disadvantaged in all production factors, but also are no longer protected by such traditional recourses as labor intensification and production efficiency. Far more farmers are also subjected to large-scale farming pressures well beyond the “factory farm” areas, and in several places to pressures as intense. One of these centers is the Western Corn Belt, a bastion of both technology and rural tradition, and thus quite possibly the place where the foremost dilemma in American agriculture is finally resolved.     

The characterisation and origin of graphite in cratonic lithospheric mantle: a petrological carbon isotope and Raman spectroscopic study

Graphite-bearing peridotites, pyroxenites and eclogite xenoliths from the Kaapvaal craton of southern Africa and the Siberian craton, Russia, have been studied with the aim of: 1) better characterising the abundance and distribution of elemental carbon in the shallow continental lithospheric mantle; (2) determining the isotopic composition of the graphite; (3) testing for significant metastability of graphite in mantle rocks using mineral thermobarometry. Graphite crystals in peridotie, pyroxenite and eclogite xenoliths have X-ray diffraction patterns and Raman spectra characteristic of highly crystalline graphite of high-temperature origin and are interpreted to have crystallised within the mantle. Thermobarometry on the graphite-peridotite assemblages using a variety of element partitions and formulations yield estimated equilibration conditions that plot at lower temperatures and pressures than diamondiferous assemblages. Moreover, estimated pressures and temperatures for the graphite-peridotites fall almost exclusively within the experimentally determined graphite stability field and thus we find no evidence for substantial graphite metastability. The carbon isotopic composition of graphite in peridotites from this and other studies varies from δ¹³ C_PDB = ? 12.3 to ? ?3.8%o with a mean of-6.7‰, σ=2.1 (n=22) and a mode between-7 and-6‰. This mean is within one standard deviation of the-4‰ mean displayed by diamonds from peridotite xenoliths, and is identical to that of diamonds containing peridotite-suite inclusions. The carbon isotope range of graphite and diamonds in peridotites is more restricted than that observed for either phase in eclogites or pyroxenites. The isotopic range displayed by peridotite-suite graphite and diamond encompasses the carbon isotope range observed in mid-ocean-ridge-basalt (MORB) glasses and ocean-island basalts (OIB). Similarity between the isotopic compositions of carbon associated with cratonic peridotites and the carbon (as CO₂) in oceanic magmas (MORB/OIB) indicates that the source of the fluids that deposited carbon, as graphite or diamond, in catonic peridotites lies within the convecting mantle, below the lithosphere. Textural observations provide evidence that some of graphite in cratonic peridotites is of sub-solidus metasomatic origin, probably deposited from a cooling C-H-O fluid phase permeating the lithosphere along fractures. Macrocrystalline graphite of primary appearance has not been found in mantle xenoliths from kimberlitic or basaltic rocks erupted away from cratonic areas. Hence, graphite in mantle-derived xenoliths appears to be restricted to Archaean cratons and occurs exclusively in low-temperature, coarse peridotites thought to be characteristic of the lithospheric mantle. The tectonic association of graphite within the mantle is very similar to that of diamond. It is unlikely that this restricted occurrence is due solely to unique conditions of oxygen fugacity in the cratonic lithospheric mantle because some peridotite xenoliths from off-craton localities are as reduced as those from within cratons. Radiogenic isotope systematics of peridotite-suite diamond inclusions suggest that diamond crystallisation was not directly related to the melting events that formed lithospheric peridotites. However, some diamond (and graphite?) crystallisation in southern Africa occurred within the time span associated with the stabilisation of the lithospheric mantle (Pearson et al. 1993). The nature of the process causing localisation of carbon in cratonic mantle roots is not yet clearly understood.     

Geochemical characteristics of Cocos Plate seamount lavas

A wide compositional continuum of basalts has been erupted from near-ridge seamounts constructed on the Cocos Plate between the Clipperton and Orozco Francture Zones. They range from highly evolved to moderately primitive (3.0–7.8% MgO), LREE-enriched alkali basalts, to moderately evolved to near-primary (5.2–9.5% MgO) tholeiites indistinguishable from N-type MORB. The data set of 159 quench glass analyses exhibits a remarkably consistent variation in both major and trace element composition that is keyed to variations in (La/Sm). Modeling of potential liquid lines of descent at pressures ranging from 1 bar to 8 kbar shows that this covariation is partially due to systematic differences in liquid lines of descent, where the alkaline lavas have undergone substantially more high pressure clinopyroxene fractionation and substantially less low pressure plagioclase fractionation than the tholeiites. In addition, systematic variation in the composition of the more primitive glasses indicates that they were derived from mixing of discrete enriched and depleted melts in the heterogenous seamount mantle source at pressures of 8–10 kbar and greater, and that clinopyroxene may be a residual phase during partial melting. These results show that porous media flow in the seamount mantle source is minor and that melt transport is accomplished primarily through cracking and diking. This study supports suggestions that the general homogeneity of basalt along the EPR is due to mixing in sub-axial magma chambers and mush zones, with additional mixing during partial mantle melting and melt segregation.     

Stratiform copper deposits and interactions with co-existing atmospheres, hydrospheres, biospheres and lithospheres

Fundamental evidence from world-class stratiform copper deposits repeatedly indicates that they originated by a two-stage mineralization process: a syn-diagenetic enrichment of the host sediment in iron sulfide, followed by a sub-surface addition of copper during early diagenesis of the sediment. In contrast to the previously favored syngenetic hypothesis, which suggested an open equilibration between atmosphere, hydrosphere, biosphere and upper lithosphere during mineralization, the two-stage model implies that only the initial deposition of iron sulfides should take place with open exchanges between the upper “spheres”. The sub-surface emplacement of copper should occur in relative isolation from surface environments and, therefore, the occurrence and distribution of stratiform copper deposits through time and space should not be used to make direct interpretations of contemporaneous conditions in the upper “spheres”.