Stable isotope evidence for the atmospheric origin of CO2 involved in carbonation of MSWI bottom ash

Stable isotopes were used to constrain the origin of CO₂ involved in the ageing process of municipal solid waste incineration (MSWI) bottom ash under open-air conditions. The δ¹³C and δ¹⁸O values of CaCO₃ occurring in MSWI bottom ash samples of variable age and the δ¹³C of the residual organic matter content were measured, and laboratory assessments made of the isotopic fractionation accompanying CaCO₃ neo-formation during accelerated carbonation experiments of bottom ash or pure lime with atmospheric or industrial CO₂. The results indicate that stable isotopic compositions exhibited by fresh and aged bottom ash samples reflect non-equilibrium processes resembling those described in the carbonation of concrete and mortar. They also lead to conclusions on the prevalent involvement of atmospheric CO₂ in the open-air carbonation of MSWI bottom ash.     

An integrated wavelet concept of physical geodesy

For the determination of the earth's gravity field many types of observations are nowadays available, including terrestrial gravimetry, airborne gravimetry, satellite-to-satellite tracking, satellite gradio-metry, etc. The mathematical connection between these observables on the one hand and gravity field and shape of the earth on the other is called the integrated concept of physical geodesy. In this paper harmonic wavelets are introduced by which the gravitational part of the gravity field can be approximated progressively better and better, reflecting an increasing flow of observations. An integrated concept of physical geodesy in terms of harmonic wavelets is presented. Essential tools for approximation are integration formulas relating an integral over an internal sphere to suitable linear combinations of observation functionals, i.e. linear functionals representing the geodetic observables. A scale discrete version of multiresolution is described for approximating the gravitational potential outside and on the earth's surface. Furthermore, an exact fully discrete wavelet approximation is developed for the case of band-limited wavelets. A method for combined global outer harmonic and local harmonic wavelet modelling is proposed corresponding to realistic earth's models. As examples, the role of wavelets is discussed for the classical Stokes problem, the oblique derivative problem, satellite-to-satellite tracking, satellite gravity gradiometry and combined satellite-to-satellite tracking and gradiometry. Received: 28 February 1997 / Accepted: 17 November 1997     

Towards a direct collapse–load method of design for concrete frames subjected to severe ground motions

Most current methods of design for concrete structures under earthquake loads rely on highly idealized ‘equivalent’ static representations of the seismic loads and linear‐elastic methods of structural analysis. With the continuing development of non‐linear methods of dynamic analysis for the overload behaviour and collapse of complete concrete structures, a more direct and more accurate design procedure becomes possible which considers conditions at system collapse. This paper describes an evaluation procedure that uses non‐linear dynamic collapse–load analysis together with global safety coefficients. A back‐calibration procedure for evaluating the global safety coefficients is also described. The aim of this paper is to open up discussion of alternative methods of design with improved accuracy which are necessary to move towards a direct collapse–load method of design. Copyright © 2002 John Wiley & Sons, Ltd.     

Geochronology and geochemistry of Grenvillian igneous suites in the northern Oaxacan Complex, southern Mexico: tectonic implications

Chemical and U–Pb isotopic analyses of metaigneous rocks in the northern Oaxacan Complex in southern Mexico indicate that they form part of two granitic–gabbroic suites intruded at 1157–1130 and 1012 Ma, which were metamorphosed under granulite facies conditions between 1004 and 980 Ma. Although the older suite has both within-plate and arc geochemical signatures, the arc characteristics (enrichment of La and Ce relative to Nb, Ta, and Th) are inferred to result from crustal contamination, a conclusion consistent with their negative _Nd signatures. The younger suite is spatially associated with anorthosites (from which we were unable to acquire a protolith age), suggesting that collectively it forms part of anorthosite–mangerite–charnockite–granite (AMCG) suites. The tholeiitic nature of the mafic rocks along with the within-plate character of the felsic rocks suggests that they were intruded during extension related to either farfield backarc rifting, rifting above a slab window, or anorogenic intercontinental rifting. Potentially correlative AMCG suites are widespread in Mexico, the Grenville Province of eastern Canada and northeastern USA, and the Andean massifs of Colombia, however, Pb isotopic data most closely resemble those in South America. These data are consistent with published hypotheses that suggest Oaxaquia represents an exotic terrane derived from Amazonia.     

Peak response of 2-DOF uncoupled oscillator under two-directional base motion

This paper investigates the peak response of a 2-DOF uncoupled linear oscillator under arbitrarily oriented two-component horizontal earthquake motion. Input data consist of 22 two-component acceleration records from the magnitude 6.6, October 15, 1979 Imperial Valley earthquake. One-directional response spectra for each principal direction of the oscillator, and two-directional response spectra (amplitude of the peak resultant response and its direction with respect to principal directions) are calculated by considering all angles of incidence of the excitation. The results indicate that, for oscillators that are not too flexible (i.e. with natural frequencies greater than 0.8 Hz), the two-directional peak response is controlled by the weaker direction of the oscillator. For flexible oscillators the two-directional peak response is controlled by the direction whose natural frequency is closer to dominant ground motion frequencies. The results also show that when the two-directional peak response is expressed as a weighted sum of one-directional peak responses, the weighting factors are not constants, but functions of oscillator and dominant ground motion frequencies.     

Changes in the hydrography of Central California waters associated with the 1997–98 El Niño

Oceanographic conditions off Central California were monitored by means of a series of 13 hydrographic cruises between February 1997 and January 1999, which measured water properties along an oceanographic section perpendicular to the California Coast. The 1997–98 El Niño event was defined by higher than normal sea levels at Monterey, which began in June 1997, peaked in November 1997, and returned to normal in March 1998. The warming took place in two distinct periods. During June and July 1997, the sea level increased as a result of stronger than normal coastal warming below 200 dbars and within 100 km of the coast, which was associated with poleward flow of saltier waters. During this period, deeper (400–1000 dbar) waters between 150–200 km from shore were also warmed and became more saline. Subsequently, sea level continued to rise through January 1998, mostly as a result of the warming above 200 dbars although, after a brief period of cooling in September 1997, waters below 200 dbar were also warmer than normal during this period. This winter warm anomaly was also coastally trapped, extending 200 km from shore and was accompanied by cooler and fresher water in the offshore California current. In March and April 1998, sea level dropped quickly to normal levels and inshore waters were fresher and warmer than the previous spring and flowed southward.The warming was consistent with equatorial forcing of Central California waters via propagation of Kelvin or coastally-trapped waves. The observed change in heat content associated with the 1997–98 El Niño was the same as that observed during the previous seasonal cycle. The warming and freshening events were similar to events observed during the 1957–58 and 1982–83 El Niños.     

Residential segregation and housing in Berlin: changes since unification

This paper examines the spatial patterns and extent of residential segregation in Berlin at the time of unification, and also considers changes since that date. Residential segregation is differentiated into three components - demographic, socio-economic and ethnic. For all these dimensions, segregation depends on housing provision and the rules of admission to various segments of the housing market. The former differences in housing regulations in East and West Berlin are therefore of importance, as well as changes since unification. The paper shows that before unification demographic segregation was more prominent in East Berlin, whilst socio-economic segregation was more pronounced in West Berlin. Ethnic minority communities in West Berlin had developed from the immigration of guestworkers and their families, with moderate levels of segregation: however in East Berlin there were very few foreign contract workers present throughout the 1980s. In spite of the short time-period since unification, there are clear signs of convergence between the segregation patterns in the two parts of the city. Nevertheless, it is argued that population movements between East and West are still remarkably low, so that differences in the population patterns will continue to exist for some time to come. This revised version was published online in August 2006 with corrections to the Cover Date.     

The hydrological response of soil surfaces to rainfall as affected by cover and position of rock fragments in the top layer

Rainfall experiments have been conducted in the laboratory in order to assess the hydrological response of top soils very susceptible to surface sealing and containing rock fragments in different positions with respect to the soil surface. For a given cover level, rock fragment position in the top soil has an ambivalent effect on water intake and runoff generation. Compared to a bare soil surface rock fragments increase water intake rates as well as time of runoff concentration and decrease runoff volume if they rest on the soil surface. For the same cover level, rock fragments reduce infiltration rate and enhance runoff generation if they are well embedded in the top layer. The effects of rock fragment position on infiltration rate and runoff generation are proportional to cover percentage. Micromorphological analysis and measurements of the saturated hydraulic conductivity of bare top soils and of the top layer underneath rock fragments resting on the soil surface reveal significant differences supporting the mechanism proposed by Poesen (1986): i.e. runoff generated as rock flow or as Horton overland flow can (partly) infiltrate into the unsealed soil surface under the rock fragments, provided that they are not completely embedded in the top layer. Hence, rock fragment position, beside other rock fragment properties, should be taken into account when assessing the hydrological response of soils susceptible to surface sealing and containing rock fragments in their surface layers. A simple model, based on the proportions of bare soil surface, soil surface occupied by embedded rock fragments, and soil surface covered with rock fragments resting on the soil surface, describes the runoff coefficient data relatively well.     

Distribution and possible sources of organochlorine residues in sediments of a large urban estuary,Port Jackson,Sydney

Sydney Harbour is surrounded by a large capital city of about four million people and its highly urbanised (86%) catchment supports a substantial industrial base and an extensive transport infrastructure. Large commercial and naval ports occupy the waterway and the harbour is an important recreational area. Surficial sediment in Sydney Harbour contains high concentrations of PCBs, HCB, total chlordane, total DDT, aldrin, dieldrin, heptachlor and heptachlor‐epoxide, but low concentrations of lindane. PCBs, total chlordane, and to a lesser extent dieldrin, are most elevated in sediment in creeks on the southern shores of the harbour suggesting sources within older, highly urbanised/industrialised catchments of western‐central Sydney. There are high concentrations of total DDT and HCB in sediments of the upper harbour and Homebush Bay suggesting that chemical industries on the shores of the estuary in this area are sources of these contaminants. Although no sediment quality guidelines apply in Australia, empirically derived biological effects criteria suggest that sediment over extensive areas of Sydney Harbour may have an adverse impact on biota. Especially of concern are sediments containing high concentrations of chlordane and DDT.     

Changes in current regime and turbidity in response to a freshwater pulse in the eastmain estuary

In September 1984, the freshwater input to the Eastmain River (James Bay, Canada) was increased by a factor of 50 over a 6-d period during a controlled reservoir discharge. Changes to the current, salinity and turbidity regimes were monitored during the peak runoff. Estuarine salinity values fell rapidly with increasing mean flow, as did the amplitude of the semi-diurnal tidal currents. A large increase in bottom shear stress dispersed the settled suspension layer into the water column, raising concentrations of suspended matter in the estuary by a factor of 4 in 3 d. The peak values exceeded 150 mg I^?1. This led to erosion of the river silt deposits, with the export of an estimated 6 × 10⁴ metric tons of sediments. After the reduction of discharge, current values returned to their normal range within a day, whereas upstream salinity intrusion occurred at a slower rate. Horizontal diffusivities of about 100 m² s^?1 were required to match the observed lag.