Comparative Re-Os systematics of chondrites: Implications regarding early solar system processes

A suite of 47 carbonaceous, enstatite, and ordinary chondrites are examined for Re-Os isotopic systematics. There are significant differences in the ¹⁸⁷Re/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os ratios of carbonaceous chondrites compared with ordinary and enstatite chondrites. The average ¹⁸⁷Re/¹⁸⁸Os for carbonaceous chondrites is 0.392 ± 0.015 (excluding the CK chondrite, Karoonda), compared with 0.422 ± 0.025 and 0.421 ± 0.013 for ordinary and enstatite chondrites (1σ standard deviations). These ratios, recast into elemental Re/Os ratios, are as follows: 0.0814 ± 0.0031, 0.0876 ± 0.0052 and 0.0874 ± 0.0027, respectively. Correspondingly, the ¹⁸⁷Os/¹⁸⁸Os ratios of carbonaceous chondrites average 0.1262 ± 0.0006 (excluding Karoonda), and ordinary and enstatite chondrites average 0.1283 ± 0.0017 and 0.1281 ± 0.0004, respectively (1σ standard deviations). The new results indicate that the Re/Os ratios of meteorites within each group are, in general, quite uniform. The minimal overlap between the isotopic compositions of ordinary and enstatite chondrites vs. carbonaceous chondrites indicates long-term differences in Re/Os for these materials, most likely reflecting chemical fractionation early in solar system history.A majority of the chondrites do not plot within analytical uncertainties of a 4.56-Ga reference isochron. Most of the deviations from the isochron are consistent with minor, relatively recent redistribution of Re and/or Os on a scale of millimeters to centimeters. Some instances of the redistribution may be attributed to terrestrial weathering; others are most likely the result of aqueous alteration or shock events on the parent body within the past 2 Ga.The ¹⁸⁷Os/¹⁸⁸Os ratio of Earth’s primitive upper mantle has been estimated to be 0.1296 ± 8. If this composition was set via addition of a late veneer of planetesimals after core formation, the composition suggests the veneer was dominated by materials that had Re/Os ratios most similar to ordinary and enstatite chondrites.     

Physical and chemical properties of the waters of saline lakes and their importance for deep-water renewal: Lake Issyk-Kul, Kyrgyzstan

The relationships between electrical conductivity, temperature, salinity, and density are studied for brackish Lake Issyk-Kul. These studies are based on a newly determined major ion composition, which for the open lake shows a mean absolute salinity of 6.06 g kg⁻¹. The conductivity-temperature relationship of the lake water was determined experimentally showing that the lake water is about 1.25 times less conductive than seawater diluted to the same absolute salinity as that of the lake water. Based on these results, an algorithm is presented to calculate salinity from in-situ conductivity measurements. Applied to the field data, this shows small but important vertical salinity variations in the lake with a salinity maximum at 200 m and a freshening of the surface water with increasing proximity to the shores. The algorithm we adopt to calculate density agrees well with earlier measurements and shows that at 20°C and 1 atm Lake Issyk-Kul water is about 530 g m⁻³ denser than seawater at the same salinity. The temperature of maximum density at 1 atm is about 0.15°C lower than that for seawater diluted to the same salinity. Despite its small variations, salinity plays an important role, together with temperature changes, in the static stability and in the production of deep-water in this lake. Changes in salinity may have had important consequences on the mixing regime and the fate of inflowing river water over geological time. Uncharged silicic acid is negligible for the stability of the water column except near an ∼15 m thick nepheloid layer observed at the bottom of the deep basin.     

Climate change impacts on U.S. Coastal and Marine Ecosystems

Increases in concentrations of greenhouse gases projected for the 21st century are expected to lead to increased mean global air and ocean temperatures. The National Assessment of Potential Consequences of Climate Variability and Change (NAST 2001) was based on a series of regional and sector assessments. This paper is a summary of the coastal and marine resources sector review of potential impacts on shorelines, estuaries, coastal wetlands, coral reefs, and ocean margin ecosystems. The assessment considered the impacts of several key drivers of climate change: sea level change; alterations in precipitation patterns and subsequent delivery of freshwater, nutrients, and sediment; increased ocean temperature; alterations in circulation patterns; changes in frequency and intensity of coastal storms; and increased levels of atmospheric CO₂. Increasing rates of sea-level rise and intensity and frequency of coastal storms and hurricanes over the next decades will increase threats to shorelines, wetlands, and coastal development. Estuarine productivity will change in response to alteration in the timing and amount of freshwater, nutrients, and sediment delivery. Higher water temperatures and changes in freshwater delivery will alter estuarine stratification, residence time, and eutrophication. Increased ocean temperatures are expected to increase coral bleaching and higher CO₂ levels may reduce coral calcification, making it more difficult for corals to recover from other disturbances, and inhibiting poleward shifts. Ocean warming is expected to cause poleward shifts in the ranges of many other organisms, including commercial species, and these shifts may have secondary effects on their predators and prey. Although these potential impacts of climate change and variability will vary from system to system, it is important to recognize that they will be superimposed upon, and in many cases intensify, other ecosystem stresses (pollution, harvesting, habitat destruction, invasive species, land and resource use, extreme natural events), which may lead to more significant consequences.     

A decade of change in the Skidaway River estuary I. Hydrography and nutrients

The Skidaway River estuary is a tidally-dominated subtropical estuary in the southeastern USA surrounded by extensiveSpartina salt marshes. Weekly smapling at high and low tide began in 1986 for hydrography, nutrients, chlorophylla, particulate matter, and microbial and plankton biomass and composition; hydrographic and nutrient data during 1986–1996 are reported here. Salinity varied inversely with river discharge and exhibited variability at all time scales but with no long-term trend. Water temperature typically ranged over 25°C and was without apparent long-term frend. Seasonal cycles in concentrations of NO₃, NH₄, PO₄, Si(OH)₄, and DON were observed, with annual maxima generally occurring in late summer. Superimposed on seasonal cycles, all five nutrients exhibited steady increases in minimum, mean, and maximum concentrations; mean concentrations increased c. 50–150% during the decade. Nutrient concentrations were highly correlated with water temperature over the ten-year period, but weakly related to salinity and discharge. Nutrients were strongly correlated with one another, and the relative ratios among inorganic nutrients showed little long-term trend. Correlations among temperature and nutrient concentrations exhibited considerable inter-annual variability. Major spikes in organic and inorganic nutrient concentrations coincided with significant rainfall events; concentrations increased hyperbolically with rainfall. Although pristine compared to more heavily impacted waterways primarily outside the region, residential development and population density have been increasing rapidly during the past 15–20 years. Land use is apparently altering nutrient loading over the long-term (months-years), and superimposed on this are stochastic meteorological events that accelerate these changes over the short term (days-weeks).     

Celestite formation, bacterial sulphate reduction and carbonate cementation of Eocene reefs and basinal sediments (Igualada, NE Spain)

Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO₄) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr²⁺ and SO₄^2? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO₄^2? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, ⁸⁷Sr/⁸⁶Sr data also suggest that Sr²⁺ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in ¹⁸O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits.     

Cretaceous and Tertiary terrane accretion in the Cordillera Occidental of the Andes of Ecuador

New field, geochronological, geochemical and biostratigraphical data indicate that the central and northern parts of the Cordillera Occidental of the Andes of Ecuador comprise two terranes. The older (Pallatanga) terrane consists of an early to late (?) Cretaceous oceanic plateau suite, late Cretaceous marine turbidites derived from an unknown basaltic to andesitic volcanic source, and a tectonic mélange of probable late Cretaceous age. The younger (Macuchi) terrane consists of a volcanosedimentary island arc sequence, derived from a basaltic to andesitic source. A previously unidentified, regionally important dextral shear zone named the Chimbo-Toachi shear zone separates the two terranes. Regional evidence suggests that the Pallatanga terrane was accreted to the continental margin (the already accreted Cordillera Real) in Campanian times, producing a tectonic mélange in the suture zone. The Macuchi terrane was accreted to the Pallatanga terrane along the Chimbo-Toachi shear zone during the late Eocene, probably in a dextral shear regime. The correlation of Cretaceous rocks and accretionary events in the Cordillera Occidental of Ecuador and Colombia remains problematical, but the late Eocene event is recognised along the northern Andean margin.     

Aeromagnetic signatures over western Marie Byrd Land provide insight into magmatic arc basement, mafic magmatism and structure of the Eastern Ross Sea Rift flank

Aeromagnetic signatures over the Edward VII Peninsula (E7) provide new insight into the largely ice-covered and unexplored eastern flank of the Ross Sea Rift (RSR). Positive anomalies, 10–40 km in wavelength and with amplitudes ranging from 50 to 500 nT could reveal buried Late Devonian(?)–Early Carboniferous Ford Granodiorite plutons. This is suggested by similar magnetic signature over exposed, coeval Admiralty Intrusives of the Transantarctic Mountains (TAM). Geochemical data from mid-Cretaceous Byrd Coast Granite, contact metamorphic effects on Swanson Formation and hornblende-bearing granitoid dredge samples strengthen this magnetic interpretation, making alternative explanations less probable. These magnetic anomalies over formerly adjacent TAM and western Marie Byrd Land (wMBL) terranes resemble signatures typically observed over magnetite-rich magmatic arc plutons. Shorter wavelength (5 km) 150 nT anomalies could speculatively mark mid-Cretaceous mafic dikes of the E7, similar to those exposed over the adjacent Ford Ranges. Anomalies with amplitudes of 100–360 nT over the Sulzberger Bay and at the margin of the Sulzberger Ice Shelf likely reveal mafic Late Cenozoic(?) volcanic rocks emplaced along linear rift fabric trends. Buried volcanic rock at the margin of the interpreted half-graben-like “Sulzberger Ice Shelf Block” is modelled in the Kizer Island area. The volcanic rock is marked by a coincident positive Bouguer gravity anomaly. Late Cenozoic volcanic rocks over the TAM, in the RSR, and beneath the West Antarctic Ice Sheet exhibit comparable magnetic anomaly signature reflecting regional West Antarctic Rift fabric. Interpreted mafic magmatism of the E7 is likely related to mid-Cretaceous and Late Cenozoic regional crustal extension and possible mantle plume activity over wMBL. Magnetic lineaments of the E7 are enhanced in maximum horizontal gradient of pseudo-gravity, vertical derivative and 3D Euler Deconvolution maps. Apparent vertical offsets in magnetic basement at the location of the lineaments and spatially associated mafic dikes and volcanic rocks result from 2.5D magnetic modelling. A rift-related fault origin for the magnetic lineaments, segmenting the E7 region into horst and graben blocks, is proposed by comparison with offshore seismic reflection, marine gravity, on-land gravity, radio-echo sounding, apatite fission track data and structural geology. The NNW magnetic lineament, which we interpret to mark the eastern RSR shoulder, forms the western margin of the “Alexandra Mountains horst”. This fundamental aeromagnetic feature lies on strike with the Colbeck Trough, a prominent NNW half-graben linked to Late Cretaceous(?) and Cenozoic(?) faulting in the eastern RSR. East–west and north–north–east to NE magnetic trends are also imaged. Magnetic trends, if interpreted as reflecting the signature of rift-related normal faults, would imply N–S to NE crustal extension followed by later northwest–southeast directed extension. NW–SE extension would be compatible with Cenozoic(?) oblique RSR rifting. Previous structural data from the Ford Ranges have, however, been interpreted to indicate that both Cretaceous and Cenozoic extensions were N–S to NE–SW directed.     

Transient foundation solution of saturated soil to impulsive concentrated loading

The transient dynamic response of saturated soil under suddenly applied normal and horizontal concentrated loading is studied in this paper. The behavior of saturated soil is governed by Biot's consolidation theory. The general solutions for Biot equations of equilibrium are derived in terms of displacements and variations of fluid volume, using Laplace–Hankel integral transforms. The solutions in the time domain can be evaluated by numerical inverse Laplace–Hankel transforms. Selected numerical results for displacements, stresses, and pore pressures are presented. Comparisons with existing closed-form solutions for the elastic half-space are made to confirm the accuracy of the present solutions. The solutions can be used to study a variety of transient wave propagation problems and dynamical interactions between saturated soil and structures.