Neoproterozoic ophiolitic peridotites along the Allaqi-Heiani suture, South Eastern Desert, Egypt

The Wadi Allaqi ophiolite along the Egyptian-Sudanese border defines the southernmost ophiolitic assemblage and suture zone in the Eastern Desert. Ophiolite assemblages comprise nappes composed mainly of mafic and ultramafic rocks that were tectonically emplaced and replaced by serpentine and carbonates along shear zones probably due to CO₂-metasomatism. Serpentinites, altered slices of the upper mantle, represent a distinctive lithology of dismembered ophiolites of the western YOSHGAH suture. Microscopically, they are composed of more than 90 % serpentine minerals with minor opaque minerals, carbonate, brucite and talc. The mineral chemistry and whole-rock chemical data reported here indicate that the serpentinized peridotites formed as highly-depleted mantle residues. They show compositions consistent with formation in a suprasubduction zone environment. They are depleted in Al₂O₃ and CaO similar to those in fore-arc peridotites. Also, high Cr# (Cr/ (Cr+Al)) in the relict chrome spinels (average ~0.72) indicates that these are residual after extensive partial melting, similar to spinels in modern fore-arc peridotites. Therefore, the studied serpentinites represent fragments of an oceanic lithosphere that formed in a fore-arc environment, which belongs to an ophiolitic mantle sequence formed in a suprasubduction zone.     

Investigation of groundwater mineralization in the Hammamet–Nabeul unconfined aquifer,north-eastern Tunisia: geochemical and isotopic approach

Detailed hydrogeochemical and isotopic data of groundwaters from the Hammamet–Nabeul unconfined aquifer are used to provide a better understanding of the natural and anthropogenic processes that control the groundwater mineralization as well as the sources of different groundwater bodies. It has been demonstrated that groundwaters, which show Na–Cl and Ca–SO₄–Cl water facies, are mainly influenced by the dissolution of evaporates, the dedolomitization and the cation-exchange process; and supplementary by anthropogenic process in relation with return flow of irrigation waters. The isotopic signatures permit to classify the studied groundwaters into two different groups. Non-evaporated groundwaters that are characterized by depleted δ ¹⁸O and δ ²H contents highlighting the importance of modern recharge at higher altitude. Evaporated groundwaters with enriched contents reflecting the significance infiltration of return flow irrigation waters. Tritium data in the studied groundwaters lend support to the existence of pre-1950 and post-1960 recharge. Carbon-14 activities in shallow wells that provide evidence to the large contamination by organic ¹⁴C corroborate the recent origin of the groundwaters in the study area.     

Future trends in transport and fate of diffuse contaminants in catchments,with special emphasis on stable isotope applications

A summary is provided of the first of a series of proposed Integrated Science Initiative workshops supported by the UNESCO International Hydrological Programme. The workshop brought together hydrologists, environmental chemists, microbiologists, stable isotope specialists and natural resource managers with the purpose of communicating new ideas on ways to assess microbial degradation processes and reactive transport at catchment scales. The focus was on diffuse contamination at catchment scales and the application of compound‐specific isotope analysis (CSIA) in the assessment of biological degradation processes of agrochemicals. Major outcomes were identifying the linkage between water residence time distribution and rates of contaminant degradation, identifying the need for better information on compound specific microbial degradation isotope fractionation factors and the potential of CSIA in identifying key degradative processes. In the natural resource management context, a framework was developed where CSIA techniques were identified as practically unique in their capacity to serve as distributed integrating indicators of process across a range of scales (micro to diffuse) of relevance to the problem of diffuse pollution assessment. Copyright © 2006 John Wiley & Sons, Ltd.     

塔里木西克尔基性麻粒岩捕虏体的发现及其地质意义

在塔里木西部新生代碧玄岩中新发现了基性麻粒岩捕虏体。其原生矿物组合为Cpx+Opx+Pl (An=30~50)+Sp+Ilm+Tim,次生矿物组合为Ol+Pl (An>50)+alkaline feldspar+glass。原生矿物组合的温度和压力分别为1005~1059℃ 和 0.6~1.1GPa; 次生矿物组合形成于近等温减压过程和固相线上熔融以及之后的近地表快速冷却。这些麻粒岩捕虏体代表了早期底侵到塔里木板块下地壳的幔源岩浆。     

Oceanic influence on the sub-seasonal to interannual timing and frequency of extreme dry spells over the West African Sahel

Intra-seasonal drought episodes (extreme dry spells) are strongly linked to crop yield loss in the West African Sahel, especially when they occur at crop critical stages such as juvenile or flowering stage. This paper seeks to expose potentially predictable features in the sub-seasonal to inter-annual occurrence of “extreme dry spells” (extDS) through their links to sea surface temperature anomalies (SSTAs). We consider two kinds of extreme dry spells: more than 2 weeks of consecutive dry days following a rain event (often found at the beginning of the rainy season, after the first rain events) and more than a week (observed towards the end of the rainy season, before the last rain events). We extract dry spells from daily rainfall data at 43 stations (31 stations in Senegal over 1950–2010 and 12 stations in Niger over 1960–2000) to identify the intra-seasonal distribution of extDS and their significant correlation with local rainfall deficits. Seasonality of distribution and high spatial coherence are found in the timing and the frequency of occurrence of extDS in different rainfall regions over Niger and Senegal. The correlation between the regional occurrence index (ROI), necessary to capture the spatial extent of extDS, and observed global sea surface temperature anomalies (SSTAs) sheds light on the influence of the external factors on the decadal, interannual and sub-seasonal variability of extDS over the West African Sahel. When the global tropics and the Atlantic are warmer than normal, more coherent and delayed June–July extDS are observed after onset of rainy season, as well as early cessation type in August–September. When the Indo-Pacific is cooler and the equatorial south Atlantic is warmer than normal little to no extDS are found in the onset sub-period of the monsoon season. Mostly late types of extDS occur in October as a result of late cessation. These results show potential predictability of extreme dry spells after onset and before cessation of monsoonal rain based on global patterns of sea surface temperature anomalies.     

Climate change impact projections at the catchment scale in Tunisia using the multi-model ensemble mean approach

In this work, we developed a mean projection for climate change and assessed its impact on some hydro-meteorological indicators relevant to climatic condition, precipitation extremes magnitude and frequency for the Siliana catchment in Tunisia based on an ensemble of seven combinations of global circulation models (GCMs) and regional climate models (RCMs) derived from the EU-FP6 ENSEMBLES project. We performed quantile-based mapping (QM) bias correction technique of climate model projection using local observations. Because there is no warranty that the best climate model based on its performances in reproducing historic climate will be superior to other models in simulating future climate, we used the multi-model ensemble (MME) mean approach to derive a mean projection as the best guess for climate change projection for the Siliana catchment. We also quantified the uncertainty of the MME in the projected change in the selected indicators by comparing their values in the reference period (1981–2010) to these in the future period (2041–2070). Results reveal that the Siliana catchment will be prone to drier and warmer climate in the future with less rainy days for each month. The uncertainty associated with the MME projection suggests that no clear general tendency for extreme rainy days in the future is expected. These findings highlight the need to consider an ensemble of multi-climate models with an uncertainty framework if reliable climate change impact study is sought at the catchment scale.     

A novel platform to evaluate the dampening of water and solute transport in an experimental channel under unsteady flow conditions

This paper presents a novel platform to study the dampening of water and solute transport in an experimental channel under unsteady flow conditions, where literature data are scarce. We address the question about what could be the smallest size of experimental platform that is useful for research, project studies, and teaching activities and that allows to do rational experiments characterized by small space occupation, short experimental duration, high measurement precision, high quality and reproducible experimental curves, low water and energy consumption, and the possibility to test a large variety of hydrograph scenarios. Whereas large scale hydraulic laboratories have focused their studies on sediment transport, our platform deals with solute transport. The objectives of our study are (a) building a platform that allows to do rational experiments, (b) enriching the lack of experimental data concerning water and solute transport under unsteady state conditions, and (c) studying the dampening of water and solute transport. We studied solute transport in a channel with lateral gain and lateral loss under different experimental configurations, and we show how the same lateral loss flow event can lead to different lateral loss mass repartitions under different configurations. In order to characterize water and solute dampening between the input and the output of the channel, we calculate dampening ratios based on peak coordinates of time flow curves and time mass curves and that express the decrease of peak amplitude and the increase of peak occurrence time between the input and output curves. Finally, we use a solute transport model coupling the diffusive wave equation for water transfer and the advection–diffusion equation for solute transport in order to simulate the experimental data. The simulations are quite good with a Nash–Sutcliffe efficiency NSE > 0.98 for water transfer and 0.84 < NSE < 0.97 for solute transport. This platform could serve hydrological modellers because it offers a variety of measured parameters (flow, water height, and solute concentration), at a fine time step under unsteady flow conditions.     

Implementation of an automatic calibration procedure for HYDROTEL based on prior OAT sensitivity and complementary identifiability analysis

Efficiency of hydrological models mostly depends on the quality of the calibration performed prior to use. In this paper, an automatic calibration framework for the distributed hydrological model HYDROTEL is proposed. The calibration procedure was performed for three watersheds characterized with different hydroclimatological conditions: the Sassandra located in Ivory Coast, Africa, and the Montmorency and Beaurivage watersheds located in Quebec (Canada). Results of one‐a‐time (OAT) sensitivity analysis showed that the order of the most sensitive parameters differs for each watershed. Thus, the sensitivity depends on the hydroclimatic and physiographic characteristics of the watersheds. Co‐linearity indices showed that all model parameters were identifiable, that is, none of the studied parameters could be explained by a combination of the other parameters. Following these findings, an automatic calibration was run. Results indicated there was good agreement between simulated and measured streamflows at the outlet of each watershed; Nash–Sutcliffe efficiency (NSE) ranging between 0.77 and 0.92 and R² ranging from 0.87 to 0.97. When comparing NSE and R² values obtained using a process‐oriented, multiple‐objective, manual calibration strategy, a slight increase in model efficiency was reached with the automatic calibration procedure (4.15% for NSE and 2.95% for R²) improving predictions of peak flows for the Montmorency and Beaurivage watersheds (temperate climate conditions) and flows beyond the rainfall season in the Sassandra watershed. The proposed automatic calibration procedure introduced in this paper may be applied to other distributed hydrological model. Copyright © 2013 John Wiley & Sons, Ltd.