A Lateglacial–early Holocene tephrochronology for SW Sweden

Four cores from southwestern Sweden are presented together with their tephra geochemistry. Two cryptotephra horizons were confirmed geochemically in the cores, the Vedde Ash and the Hässeldalen Tephra. The Lateglacial Hässeldalen Tephra (11 360–11 300 cal. a BP) offers great potential as a regional isochrone to add a new degree of certainty to the deglaciation chronology of southern Sweden, including the extent of glacial Lake Bolmen. In addition, the geographical distribution of the Hässeldalen Tephra has recently been extended outside of Sweden, making it an important time‐marker horizon in northern Europe. There are potential difficulties, however. Proper identification of the actual isochrone is complicated by the vertical pattern of shard distribution, which could be the result of several eruptive events, as well as by the fact that shards from the 10‐ka Askja horizon (10 500–10 350 cal. a BP) were found in close stratigraphical proximity. The geochemical data presented are the result of improved EPMA methodology, which significantly reduces sodium mobilization. The results therefore have slightly altered values, which has consequences for classifying new finds when they are compared with previous data for geochemically similar tephras. Finally, potential indications of the Borrobol/Penifiler horizon are presented, although the existence of the horizon could not be confirmed geochemically. This highlights the need to retrieve cores from different locations within a basin based on an analysis of basin morphology if horizons are to be located.     

Molecular and isotopic characterization of organic samples from the wreck of the Saint-Etienne merchant ship (XVIIIth century): Identification of pitch,fat, hair and sulfur

The wreck U Pezzo, excavated within the Saint Florent Gulf in northern Corsica was identified as the pink, Saint Etienne, a merchant ship which sank on January 31, 1769. In order to determine the composition of organic materials used to coat the hull or to waterproof different parts of the pink, a study of several samples, using molecular biomarker and carbon isotopic analysis, was initiated. The results revealed that the remarkable yellow coat, covering the outside planks of the ship’s bottom under the water line, is composed of sulfur, tallow (of ox and not of cetacean origin) and black pitch which corresponds to a mixture called “couroi” or “stuff”. Onboard ropes had been submitted to a tarring treatment with pitch. Hairs mixed with pitch were identified in samples collected between the two layers of the hull or under the sheathing planking. The study also provides a key model for weathering of pitch, as different degrees of degradation were found between the surface and the heart of several samples. Accordingly, molecular parameters for alteration were proposed. Furthermore novel mixed esters between terpenic and diterpenic alcohols and the free major fatty acids (C_14:0, C_16:0, C_18:0) were detected in the yellow coat.     

The circulation, water masses and sea-ice of Baffin Bay

The oceanographic, meteorological and sea-ice conditions in Baffin Bay are studied using historical hydrographic, satellite and meteorological data, and a set of current meter data from a mooring program of the Bedford Institute of Oceanography. Baffin Bay is partially covered by sea-ice all year except August and September. The interannual variation of the ice extent is shown to be correlated with winter air temperature. Available hydrographic data were used to study the water masses and the horizontal and vertical distribution of temperature/salinity. Three water masses can be identified – Arctic Water in the upper 100–300 m of all regions except the southeast, West Greenland Intermediate Water at 300–800 m in most of the interior of Baffin Bay, and Deep Baffin Bay Water in all regions below 1200 m. The temperature and salinity in Baffin Bay have limited seasonal variability except in the upper 300 m of eastern Davis Strait, northern Baffin Bay and the mouth of Lancaster Sound. Summer data have a temperature minimum at 100 m, which suggests winter convection does not penetrate deeper than this depth. Current meter data and results of a circulation model indicate that the mean circulation is cyclonic. The seasonal variation of the currents is complex. Overall, summer and fall tend to have stronger currents than winter and spring at all depths. Among the different regions, the largest seasonal variation occurs at the mouth of Lancaster Sound and the Baffin Island slope. Model generated velocity fields show a basic agreement with the observed currents, and indicate strong topographic control in the vicinity of Davis Strait and on the Greenland shelves. The model also produces a southward counter current on the Greenland slope, which may explain the observed high horizontal shears over the Greenland slope. Estimates of the volume and fresh water transports through Lancaster, Jones and Smith Sounds are reviewed. Transports through Davis Strait are computed from the current meter data. The balance of freshwater budget and sensitivity of the thermohaline circulation to freshwater transport are discussed.     

Determination of volatile concentrations in fluorapatite of Martian shergottite NWA 2975 by combining synchrotron FTIR,Raman spectroscopy,EMPA, and TEM,and inferences on the volatile budget of the apatite host‐magma

We combined the focused ion beam sample preparation technique with polarized synchrotron‐based FTIR (Fourier transform infrared) spectroscopy, laser‐Raman spectroscopy, electron microprobe analysis (EMPA), and transmission electron microscope (TEM) analysis to identify and quantify structurally bound OH, F, Cl, and CO₃ groups in fluorapatite from the Northwest Africa 2975 (NWA 2975) shergottite. In this study, the first FTIR spectra of the OH‐stretching region from a Martian apatite are presented that show characteristic OH‐bands of a F‐rich, hydroxyl‐bearing apatite. Depending on the method of apatite‐formula calculation and whether charge balance is assumed or not, the FTIR‐based quantification of the incorporated OH, expressed as wt% H₂O, is in variably good agreement with the H₂O concentration calculated from electron microprobe data. EMP analyses yielded between 0.35 and 0.54 wt% H₂O, and IR data yielded an average H₂O content of 0.31 ± 0.03 wt%, consistent with the lower range determined from EMP analyses. The TEM observations implied that the volatiles budget of fluorapatite is magmatic. The water content and the relative volatile ratios calculated for the NWA 2975 magma are similar to those established for other enriched or intermediate shergottites. It is difficult to define the source of enrichment: either Martian wet mantle or crustal assimilation. Comparing the environment of parental magma generation for NWA 2975 with the terrestrial mantle in terms of water content, it displays a composition intermediate between enriched and depleted MORB.     

Occurrence of winter air temperature extremes in Central Spitsbergen

The occurrence of daily air temperature extremes in winter in Central Spitsbergen in the period 1975–2008 was analysed. The mean winter temperature was found to be increasing by approximately 1.65°C per decade. Negative extremes were becoming less frequent, decreasing at a rate of approximately 5 days per decade, whereas the frequency of positive extremes showed a small (2 days per decade) but insignificant positive trend. Furthermore, circulation patterns responsible for positive and negative temperature extremes were analysed. Composite maps of the sea level pressure (SLP) and 500-hPa geopotential heights (z500 hPa) means and anomalies were constructed for the days with positive and negative extremes. Circulation patterns causing extremely warm winter days are characterised by a cyclonic centre or a low pressure trough over the Fram Strait. Cyclones located west of Spitsbergen with a warm sector over the archipelago bring warm air masses from the southern quadrant. On extremely cold days, the cyclone centres are usually located over the Barents Sea. This SLP pattern implies airflow from the north and northeast that brings cold Arctic air to the North Atlantic. Another factor in the occurrence of the temperature extremes in Central Spitsbergen is the sea-ice cover. Negative temperature extremes usually occur together with a high concentration of sea ice, particularly in the middle and end of winter.     

Episodes of extreme rainwater pollution and its relationship with synoptic situation (Wielkopolski National Park,Poland)

Synoptic conditions of extreme rainwater pollution episodes, evidenced by maximum values of parameters measured in the protected area of Wielkopolski National Park (western-central Poland), were analysed in this study. Precipitation samples were tested for the following parameters: pH, electrical conductivity and the concentration of the following elements: F^-, Cl^-, NO₂^-, NO₃^-, PO₄^3-, SO₄^2- and Na⁺, NH₄⁺, K⁺, Mg²⁺, Ca²⁺. It was assumed, that in winter, western advection of Atlantic air masses was the most frequent aerosol and pollution transport scenario for the investigated area. In summer the most heavily pollution occur at the intensified meridional flow over the central Europe, indicating advection of cooler air from northern Europe and the North Sea. In most of cases, the weather conditions causing extreme concentration of examined pollutants, were determined by the movement of weather fronts over considerable parts of Poland and by precipitation caused by those fronts.     

The mass and anisotropy profiles of galaxy clusters from the projected phase-space density: testing the method on simulated data

We present a new method of constraining the mass and velocity anisotropy profiles of galaxy clusters from kinematic data. The method is based on a model of the phase-space density, which allows the anisotropy to vary with radius between two asymptotic values. The characteristic scale of transition between these asymptotes is fixed and tuned to a typical anisotropy profile resulting from cosmological simulations. The model is parametrized by two values of anisotropy, at the centre of the cluster and at infinity, and two parameters of the NFW density profile, the scale radius and the scale mass. In order to test the performance of the method in reconstructing the true cluster parameters, we analyse mock kinematic data for 20 relaxed galaxy clusters generated from a cosmological simulation of the standard Λ cold dark matter model. We use Bayesian methods of inference and the analysis is carried out following the Markov Chain Monte Carlo approach. The parameters of the mass profile are reproduced quite well, but we note that the mass is typically underestimated by 15 per cent, probably due to the presence of small velocity substructures. The constraints on the anisotropy profile for a single cluster are in general barely conclusive. Although the central asymptotic value is determined accurately, the outer one is subject to significant systematic errors caused by substructures at large clustercentric distance. The anisotropy profile is much better constrained if one performs joint analysis of at least a few clusters. In this case, it is possible to reproduce the radial variation of the anisotropy over two decades in radius inside the virial sphere.     

Radial hypothesis

The axial ratio distribution for a sample of SBc galaxies deviates from a flat distribution in ways that are consistent with predictions of the projection effect model for barred spiral galaxies. The axial ratio distribution for a corresponding sample of non-barred Sc galaxies is shown to have, bin for bin, a reciprocal set of deviations from a flat distribution. When the two samples are combined, the deviations counterbalance each other and a nearly flat axial ratio distribution is recovered. This latter result is also consistent with predictions of the projection effect model.