Distribution of trace metals in the Odra River system: Water–suspended matter–sediments

Extensive investigations of trace metals concentrations in water, suspended particulate matter (SPM) and bottom sediments of the whole Odra River system were carried out over the years 1997–2000. The vertical distribution of selected metals and their mobility were also studied in the sediment cores from upper and middle river sections. Significant levels of metal contamination were found. Median concentrations (Cd, Pb, Cu, Zn and As) in the SPM and sediments were (mg kg⁻¹) 7.1 and 8.9 Cd, 128 and 146 Pb, 81 and 119 Cu, 1198 and 1204 Zn, 48 and 54 As, respectively. The highest metal pollution of the Odra River solids was found with cadmium, zinc, lead and arsenic, showing high similarity in their frequency distributions in both SPM and sediments. Cd, Zn and As appear to be of particular concern because of the high levels, that appear to be bioavailable, and their high mobility. The exchangeable and carbonate chemical forms of Cd and Zn reached up to 50% of their total amount. Besides the determination of total metal concentration, the metal chemical forms in river solids were investigated. The results of very wide studies of the Odra River system through 4 years suggest that metal pollution decreased, especially for Zn, Pb and Cu. Among all metals studied in the Odra River sediments, substantial reductions of Cd contamination were observed neither in the period after ’97 flood, nor if compared with the earlier results obtained before ’97. No essential differences of the metal contents were observed among the samples for the same river compartment, from the same locality, taken within the five sampling campaigns. The pattern of spatial and vertical metal distributions in the river solids indicates that a variety of sources might be responsible for the contamination; very intensive, historical and current mining and smelting activities probably are the most important ones.     

Synoptic conditions for rapid snowmelt in the Polish-German lowlands

Circulation patterns favourable for rapid snowmelt in the Polish-German lowlands are described in the study. Composite maps of the SLP and 500 hPa geopotential heights means and composite anomaly maps, constructed for the days with the decrease in snow cover depth of ≥5 cm/day, show deeper than usual low-pressure systems over the northern Atlantic and slightly higher than usual pressure over the Mediterranean. Such pressure patterns corresponds to the positive NAO phase with large pressure gradients, which intensify west and south-west air flows over Central Europe. Warm and humid air masses from the west and south-west contribute to substantial daily temperature increases and, frequently, to higher-than-usual precipitation, which speeds up ablation.     

Assimilation of sea surface temperature into CECOM by flux correction

Sea surface temperature (SST) from a near real-time data set produced from satellites data has been assimilated into a coupled ice–ocean forecasting model (Canadian East Coast Ocean Model) using an efficient data assimilation method. The method is based on an optimal interpolation scheme by which SST is melded into the model through the adjustment of surface heat flux. The magnitude and space–time variation of the adjustment depend on the depth of heat diffusion into the water column in response to changes in surface flux, the correlation time scale of the data, and model and data errors. The diffusion depth is scaled by the eddy diffusivity for temperature. The ratio of the model and data errors is treated as an adjustable parameter. To evaluate the quality of the assimilation, the results from the model with and without assimilation are compared to independent ship data from the Atlantic Zone Monitoring Program and the World Ocean Circulation Experiment. It is shown that the assimilation has a significant impact on the modeled SST, reducing the root mean square difference (RMSD) between the model SST and the ship SST by 0.63°C or 37%. The RMSD of the assimilated SST is smaller than that of the satellite SST by 0.23°C. This suggests that model simulations or predictions with data assimilation can provide the best estimate of the true SST. A sensitivity study is performed to examine the change of the model RMSD with the adjustable parameter in the assimilation equation. The results show that there is an optimal value of the parameter and the model SST is not very sensitive to the parameter.     

Probabilistic seismic hazard evaluation in underground mines

Stress concentrations produced by rock deformation due to extraction in underground mines induce seismicity that can take the shape of violent and quite dangerous rockbursts.The hazard evaluation presented in this paper is based on a Bayesian probabilistic synthesis of information determined from mining situations during excavation, with previous and present data from microseismicity and seismoacustics.The method proposed in this study is an example of time-dependent on-line seismic hazard evaluation. All results presented were obtained retrospectiely for different underground coal mines in Poland and Czechoslovakia.On leave from Institute of Geophysics, Polish Academy of Sciences 01-452 Warszawa, ul. Ksiecia Janusza 64, Poland.     

Motion of salt water and associated fronts in tideless estuaries

The hydrodynamics of saline water in Polish estuaries are addressed in this paper. The phenomena are described on the basis of field data from several types of estuaries along the Polish Baltic Coast. Field measurements were made to reveal and to characterize the physical processes in these estuaries; this information was then used for analytic testing and verification of mathematical models. The results demonstrate the unsteady and changeable nature of both the flow conditions and the motion of salt water in tideless estuaries. The magnitudes and directions of the barotropic and baroclinic horizontal pressure gradients have a marked influence on the flow characteristics and motion of salt water in these tideless estuaries.     

Plant assemblage from Opole,southern Poland: New data on Late Cretaceous vegetation of the northern part of the European Province

This paper presents the results of studies on plant macroremains found in the upper Turonian of the Folwark Quarry, Opole, Poland, associated with palynological studies of the host rocks. In addition to a few macrofossils (gymnosperm wood, conifer Geinitzia reichenbachii and fern ?Didymosorus) rich sporomorphs (bryophyte, lycopod and fern spores, conifer and angiosperm pollen grains) and marine palynomorphs (mainly dinoflagellate cysts) were recorded. The palynological analysis revealed that the vegetation on the neighbouring land (the East Sudetic Island) in the late Turonian was much more diverse than could be reconstructed based on only macrofossil remains. The latter are taxonomically restricted and dominated by one gymnosperm species (Geinitzia reichenbachii), which make them similar to most neighbouring, coeval Central European assemblages. Its over representation is, thus, a result of taphonomy.     

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.     

Dynamics of the circulation in the Sea of Marmara: numerical modeling experiments and observations from the Turkish straits system experiment

During September 2008 and February 2009, the NR/V Alliance extensively sampled the waters of the Sea of Marmara within the framework of the Turkish Straits System (TSS) experiment coordinated by the NATO Undersea Research Centre. The observational effort provided an opportunity to set up realistic numerical experiments for modeling the observed variability of the Marmara Sea upper layer circulation at mesoscale resolution over the entire basin during the trial period, complementing relevant features and forcing factors revealed by numerical model results with information acquired from in situ and remote sensing datasets. Numerical model solutions from realistic runs using the Regional Ocean Modeling System (ROMS) produce a general circulation in the Sea of Marmara that is consistent with previous knowledge of the circulation drawn from past hydrographic measurements, with a westward meandering current associated with a recurrent large anticyclone. Additional idealized numerical experiments illuminate the role various dynamics play in determining the Sea of Marmara circulation and pycnocline structure. Both the wind curl and the strait flows are found to strongly influence the strength and location of the main mesoscale features. Large displacements of the pycnocline depth were observed during the sea trials. These displacements can be interpreted as storm-driven upwelling/downwelling dynamics associated with northeasterly winds; however, lateral advection associated with flow from the Straits also played a role in some displacements.