Effects of temperature on strength and compressibility of sand-bentonite buffer

Dense sand-bentonite buffer (γ_d = 1.67Mg/m³) has been proposed in Canada as one of several barriers for isolating nuclear fuel waste. The buffer will be required to function under conditions of high total pressures and elevated temperatures approaching 100°C. Summary results are presented from two test programs: (1) isothermal consolidated undrained triaxial (CIU¯) tests; and (2) isothermal drained constant-p′ (CID) triaxial tests. Specimens were consolidated at effective stresses up to 9.0 MPa and temperatures up to 100°C.

The results indicate parallel hardening lines at systematically lower values of specific volume at elevated temperatures. In shear, increased temperatures produced lower values of maximum deviator stressq_f, and higher pore water pressure changesΔu_f. The net result is curved peak strength envelops in plots ofq_f versusp_f′ that are higher at elevated temperatures, even though the strengths,q_f of individual specimens are lower. The critical state strength envelope is curved inq, p′-planes.

The effect of drained heating on buffer to 100°C is not marked. Compressibilities, stiffnesses, strengths, and pore water pressure generation are all affected, but none of the changes are great.     

Nature, origin and evolution of the granitoid-hosted early Proterozoic copper-molybdenum mineralization at Malanjkhand, Central India

At Malanjkhand, Central India, lode-type copper (-molybdenum) mineralization occurs within calcalkaline tonalite-granodiorite plutonic rocks of early Proterozoic age. The bulk of the mineralization occurs in sheeted quartz-sulfide veins, and K-silicate alteration assemblages, defined by alkali feldspar (K-feldspar ≫ albite) + dusty hematite in feldspar ± biotite ± muscovite, are prominent within the ore zone and the adjacent host rock. Weak propylitic alteration, defined by albite + biotite + epidote/zoisite, surrounds the K-silicate alteration zone. The mineralized zone is approximately 2 km in strike length, has a maximum thickness of 200 m and dips 65°–75°, along which low-grade mineralization has been traced up to a depth of about 1 km. The ore reserve has been conservatively estimated to be 92 million tonnes with an average Cu-content of 1.30%. Supergene oxidation, accompanied by limited copper enrichment, is observed down to a depth of 100m or more from the surface. Primary ores consist essentially of chalcopyrite and pyrite with minor magnetite and molybdenite. δ³⁴S (‰) values in pyrite and chalcopyrite (−0.38 to +2.90) fall within the range characteristic of granitoid-hosted copper deposits. δ¹⁸O (‰) values for vein quartz (+ 6.99 to +8.80) suggest exclusive involvement of juvenile water. Annealed fabrics are common in the ore. The sequence of events that led to the present state of hypogene mineralization is suggested to be as follows: fracturing of the host rock, emplacement of barren vein quartz, pronounced wall-rock alteration accompanied by disseminated mineralization and the ultimate stage of intense silicification accompanied by copper mineralization. Fragments of vein quartz and altered wall rocks and striae in the ore suggest post-mineralization deformation. The recrystallization fabric, particularly in chalcopyrite and sphalerite, is a product of dynamic recrystallization associated with the post-mineralization shearing. The petrology of the host rocks, hydrothermal alteration assemblages, ore mineral associations, fluid inclusions and the sulfur and oxygen isotopes of ores are comparable to those in Phanerozoic (and reported Precambrian) porphyry-copper systems, and the Malanjkhand deposit has important implications for both metallogenic models for, and mineral exploration in, Precambrian terrains.     

Modelling of soil temperature profiles using data from the pilot experiment at Anand

We present some preliminary results from a multi-layer soil temperature finite-difference model using the data set obtained during the pilot experiment on land surface processes at Anand. We hope that the present results will prove useful during the final field experiments scheduled for the coming monsoon season.     

Stratigraphy of the upper cretaceous and lower tertiary strata in the Tethyan Himalayas of Tibet (Tingri area,China)

The 1500-m-thick marine strata of the Tethys Himalaya of the Zhepure Mountain (Tingri, Tibet) comprise the Upper Albian to Eocene and represent the sedimentary development of the passive northern continental margin of the Indian plate. Investigations of foraminifera have led to a detailed biozonation which is compared with the west Tethyan record. Five stratigraphic units can be distinguished: The Gamba group (Upper Albian - Lower Santonian) represents the development from a basin and slope to an outer-shelf environment. In the following Zhepure Shanbei formation (Lower Santonian - Middle Maastrichtian), outer-shelf deposits continue. Pebbles in the top layers point to beginning redeposition on a continental slope. Intensified redeposition continues within the Zhepure Shanpo formation (Middle Maastrichtian - Lower Paleocene). The series is capped by sandstones of the Jidula formation (Danian) deposited from a seaward prograding delta plain. The overall succession of these units represents a sea-level high at the Cenomanian/Turonian boundary followed, from the Turonian to Danian, by an overall shallowing-upward megasequence. This is followed by a final transgression — regression cycle during the Paleocene and Eocene, documented in the Zhepure Shan formation (?Upper Danian - Lutetian) and by Upper Eocene continental deposits. The section represents the narrowing and closure of the Tethys as a result of the convergence between northward-drifting India and Eurasia. The plate collision started in the Lower Maastrichtian and caused rapid changes in sedimentation patterns affected by tectonic subsidence and uplift. Stronger subsidence and deposition took place from the Middle Maastrichtian to the Lower Paleocene. The final closure of remnant Tethys in the Tingri area took place in the Lutetian.     

Trace element and isotope geochemistry of depleted peridotites from an N-MORB type ophiolite (Internal Liguride,N. Italy)

 Mantle peridotites of the Internal Liguride (IL) units (Northern Apennines) constitute a rare example of the depleted lithosphere of the Jurassic Ligurian Tethys. Detailed chemical (ICP-MS and SIMS techniques) and isotopic investigations on very fresh samples have been performed with the major aim to constrain the timing and mechanism of their evolution and to furnish new data for the geodynamic interpretation. The data are also useful to discuss some general geochemical aspects of oceanic-type mantle. The studied samples consist of clinopyroxene-poor spinel lherzolites, showing incipient re-equilibration in the plagioclase-facies stability field. The spinel-facies assemblage records high (asthenospheric) equilibration temperatures (1150–1250° C). Whole rocks, and constituent clinopyroxenes, show a decoupling between severe depletion in highly incompatible elements [light rare earth elements (LREE), Sr, Zr, Na, Ti] and less pronounced depletion in moderate incompatible elements (Ca, Al, Sc, V). Bulk rocks also display a relatively strong M(middle)REE/H(heavy)REE fractionation. These compositional features indicate low-degree (<10%) fractional melting, which presumably started in the garnet stability field, as the most suitable depletion mechanism. In this respect, the IL ultramafics show strong similarity to abyssal peridotites. The Sr and Nd isotopic compositions, determined on carefully handpicked clinopyroxene separates, indicate an extremely depleted signature (⁸⁷Sr/⁸⁶Sr=0.702203–0.702285; ¹⁴³Nd/¹⁴⁴Nd=0.513619–0.513775). The Sm/Nd model ages suggest that the IL peridotites melted most likely during Permian times. They could record, therefore, the early upwelling and melting of mid ocean ridge basalt (MORB) type asthenosphere, in response to the onset of extensional mechanisms which led to the opening of the Western Tethys. They subsequently cooled and experienced a composite subsolidus evolution testified by multiple episodes of gabbroic intrusions and HT-LP retrograde metamorphic re-equilibration, prior to their emplacement on the sea floor. The trace element chemistry of IL peridotites also provides useful information about the composition of oceanic-type mantle. The most important feature concerns the occurrence of Sr and Zr negative anomalies (relative to “adjacent” REE) in both clinopyroxenes and bulk rocks. We suggest that such anomalies reflect changes in the relative magnitude of Sr, Zr and REE partition coefficients, depending on the specific melting conditions. Received: 15 February 1995/Accepted: 4 August 1995     

Nature of the crust in Maine,USA: evidence from the Sebago batholith

 Neodymium and lead isotope and elemental data are presented for the Sebago batholith (293±2 Ma), the largest exposed granite in New England. The batholith is lithologically homogeneous, yet internally heterogeneous with respect to rare earth elements (REE) and Nd isotopic composition. Two-mica granites in the southern/central portion of the batholith (group 1) are characterized by REE patterns with uniform shapes [Ce_N/Yb_N (chondrite normalized) = 9.4–19 and Eu/Eu* (Eu anomaly) = 0.27–0.42] and ɛ _Nd(t) = −3.1 to −2.1. Peripheral two-mica granites (group 2), spatially associated with stromatic and schlieric migmatites, have a wider range of total REE contents and patterns with variable shapes (Ce_N/Yb_N = 6.1–67, Eu/Eu* = 0.20–0.46) and ɛ _Nd(t) = −5.6 to −2.8. The heterogeneous REE character of the group 2 granites records the effects of magmatic differentiation that involved monazite. Coarse-grained leucogranites and aplites have kinked REE patterns and low total REE, but have Nd isotope systematics similar to group 2 granites with ɛ _Nd(t) = −5.5 to −4.7. Rare biotite granites have steep REE patterns (Ce_N/Yb_N = 51–61, Eu/Eu* = 0.32–0.84) and ɛ _Nd(t) = −4.6 to −3.8. The two-mica granites have a restricted range in initial Pb isotopic composition (²⁰⁶Pb/²⁰⁴Pb = 18.41–18.75; ²⁰⁷Pb/²⁰⁴Pb = 15.60–15.68; ²⁰⁸Pb/²⁰⁴Pb = 38.21–38.55), requiring and old, high U/Pb (but not Th/U) source component. The Nd isotope data are consistent with magma derivation from two sources: Avalon-like crust (ɛ _Nd>−3), and Central Maine Belt metasedimentary rocks (ɛ _Nd<−4), without material input from the mantle. The variations in isotope systematics and REE patterns are inconsistent with models of disequilibrium melting which involved monazite. Received: 8 December 1995 / Accepted: 29 April 1996     

Utilization of lime,slag and fly ash for improvement of a colluvial soil in New South Wales,Australia

In Australia, colluvial soils form large terrains which are often subjected to considerable erosion and mass movement. This study presents a laboratory evaluation of the improvement effected by hydrated lime, milled blast furnace slag and fly ash on a fine grained (erosive) colluvial soil in New South Wales, Australia. Geotechnical tests were conducted to determine the compaction and consolidation characteristics and the compressive and shear strength properties of the blended and natural soil specimens. The effect of these additives on the Atterberg limits and pH levels is also investigated. As large amounts of fly ash and steel slag are produced in New South Wales, it is economically attractive to utilize these industrial by-products for ground improvement rather than employing conventional methods such as lime treatment. This study demonstrates that for the colluvial soil tested, milled slag is the most effective in terms of improving the internal friction angle of the treated soil, while lime is the most suitable for achieving the optimum compressive strength. Non-pozzolanic fly ash is found to be inappropriate as a soil improving agent. The cost of ground treatment using the various additives is also estimated and compared.     

Hydrodynamics and sediment dynamics of The Wash embayment, eastern England

Water and sediment movement in The Wash embayment has been determined from an extensive set of data, consisting of tidal current readings and suspended sediment concentration measurements. Instantaneous and residual currents in the embayment show a distinct lateral inhomogeneity, whereas vertically the water column is almost homogenous. The central deep water area (30–40 m) of the embayment is dominated by a residual landward water movement, whilst on the margins, the residual movement is seaward. Sediment is supplied predominantly in suspension from the north, through the northern extremity of Boston Deep. Suspended sediment pathways are coincident with the spring tide water movements and the subtidal channels act as the main conduits. Approximately 6·8 × 10⁶ tonnes yr^?1 of suspended sediments are supplied to the embayment from offshore areas. Bedload sediment supply is of lesser importance, ～ 1·4 × 10⁴ tonnes yr^?1. Whereas suspended sediment movement appears to be the dominant mode of transport throughout the embayment, bedload transport is important in reforming the sea bed into a variety of bedforms which are particularly well developed on the margins of channels and shoals.     

Self-sedimentation of phytoplankton blooms in the geologic record

Understanding the formation of laminated, organic-rich sediments is an essential topic for researchers interested in fossil fuels, biogeochemical cycles, Earth's environmental history and global change. Biologists have very recently demonstrated that some marine phytoplankton blooms actively govern their own sedimentation by the formation of sticky transparent gels that facilitate rapid aggregation, accelerated sinking and efficient export flux. Here we present fossil evidence of unfragmented, low-diversity phytoplankton assemblages preserved as sedimentary laminae and irregular flocs that are attributable to a similar phytoplankton-driven sedimentary mechanism we term ‘self-sedimentation’. The geological evidence suggests that self-sedimentation precludes significant heterotrophic grazing, propels the formation of some conspicuous hemipelagic sedimentary laminae and results in efficient carbon and opal flux to the sediments. We suggest that the self-sedimentation phenomenon may have broad implications for the geological history of biogeochemical cycling, oceanic ecological dynamics, and abrupt atmospheric/environmental change. Broader recognition of the self-sedimentation phenomenon as explicitly defined here is a prerequisite to testing these unconventional hypotheses.