美国犹他州中部Green River流域农业区硒的淋出速度和形态

尽管硒(Se)是一种重要的生命元素,但是即使浓度很低,也有可能会造成危害。在美国西部,包括犹他州中部GreenRiver流域斯图尔特湖水鸟管理区,大面积的农业排水区中都存在硒。为了对该场地进行地球化学研究和进行修复,取未受扰动的岩芯分析了硒的形态、浓度和迁移。用酸消解进行前处理对土壤和曼柯斯页岩风化壳进行了分析,结果表明,硒的最高浓度为3ppm,采用连续萃取法的分析结果表明,有19%~79%的硒是以有机物形式存在的,有17%~67%的硒是以元素形式存在的。柱实验研究结果表明,硒可以从深部土壤迅速淋出,可溶性硒的质量分数很高,达到了292×10-9。表层土壤中硒的淋出速度最初很慢,但是非常稳定,最终淋出速度会超过深部土壤。当对岩心通过放射灭菌后,表层土壤和深部土壤的淋出速度都会加快。计算结果表明,在修复富含硒的土壤时,所需的水量很大,每kg土壤需要约500L的水量。     

Interplanetary Coronal Mass Ejections Resulting from Earth-Directed CMEs Using SOHO and ACE Combined Data During Solar Cycle 23

In this work a total of 266 interplanetary coronal mass ejections observed by the Solar and Heliospheric Observatory/Large Angle and Spectrometric Coronagraph (SOHO/LASCO) and then studied by in situ observations from Advanced Composition Explorer (ACE) spacecraft, are presented in a new catalog for the time interval 1996?–?2009 covering Solar Cycle 23. Specifically, we determine the characteristics of the CME which is responsible for the upcoming ICME and the associated solar flare, the initial/background solar wind plasma and magnetic field conditions before the arrival of the CME, the conditions in the sheath of the ICME, the main part of the ICME, the geomagnetic conditions of the ICME’s impact at Earth and finally we remark on the visual examination for each event. Interesting results revealed from this study include the high correlation coefficient values of the magnetic field \(B_{z}\) component against the Ap index (\(r = 0.84\)), as well as against the Dst index (\(r = 0.80\)) and of the effective acceleration against the CME linear speed (\(r = 0.98\)). We also identify a north–south asymmetry for X-class solar flares and an east–west asymmetry for CMEs associated with strong solar flares (magnitude ≥ M1.0) which finally triggered intense geomagnetic storms (with \(\mathrm{Ap} \geq179\)). The majority of the geomagnetic storms are determined to be due to the ICME main part and not to the extreme conditions which dominate inside the sheath. For the intense geomagnetic storms the maximum value of the Ap index is observed almost 4 hours before the minimum Dst index. The amount of information makes this new catalog the most comprehensive ICME catalog for Solar Cycle 23.     

Deformation patterns in the southwestern part of the Mediterranean Ridge (South Matapan Trench,Western Greece)

Seismic reflection data and bathymetry analyses, together with geological information, are combined in the present work to identify seabed structural deformation and crustal structure in the Western Mediterranean Ridge (the backstop and the South Matapan Trench). As a first step, we apply bathymetric data and state of art methods of pattern recognition to automatically detect seabed lineaments, which are possibly related to the presence of tectonic structures (faults). The resulting pattern is tied to seismic reflection data, further assisting in the construction of a stratigraphic and structural model for this part of the Mediterranean Ridge. Structural elements and stratigraphic units in the final model are estimated based on: (a) the detected lineaments on the seabed, (b) the distribution of the interval velocities and the presence of velocity inversions, (c) the continuity and the amplitudes of the seismic reflections, the seismic structure of the units and (d) well and stratigraphic data as well as the main tectonic structures from the nearest onshore areas. Seabed morphology in the study area is probably related with the past and recent tectonics movements that result from African and European plates’ convergence. Backthrusts and reverse faults, flower structures and deep normal faults are among the most important extensional/compressional structures interpreted in the study area.     

Study of water renewal and sedimentation of a square harbor encapsulated in a coastal front with seawalls due to wind-induced hydrodynamic circulation

In the current study in the middle of a coastal zone,a harbor basin in the form of a square area recessed to the front is considered.A breakwater of variable length and position offers protection from waves.The water renewal time and the self-purification capacity of the harbor under the influence of alongshore currents due to wind-induced water circulation of varying intensities were examined.Furthermore,the transport of particulate matter released from the upstream side of the coastal zone and the possible influence(via sedimentation)on the lateral basin was investigated.The current study was based on the use of a two-dimensional depth-averaged hydrodynamic model and a quasi-three-,dimensional transport model while the effect of partial closing of the harbor's entrance was examined.The(1)adjustment and(2)validation of the reliability of the numerical model at a laboratory level were done using a recent research based on the use of a particle image velocimetry(PIV)measurements ensuring very good agreement between numerical and experimental results.The current study showed that the partial closing of the opening between the harbor basin and the extended coastal zone,with a breakwater of length equal to 1/3 of the opening,seems to be the most acceptable technical solution.     

Assessment of global wave models on regular and unstructured grids using the Unresolved Obstacles Source Term

Ocean Dynamics - The Unresolved Obstacles Source Term (UOST) is a general methodology for parameterizing the dissipative effects of subscale islands, cliffs, and other unresolved features in ocean...     

EC8-based earthquake record selection procedure evaluation: Validation study based on observed damage of an irregular R/C building

This study investigates the applicability and limitations of the Eurocode 8 earthquake ground motion selection framework for the assessment of both elastic and inelastic structural response of multi-storey, irregular R/C buildings subjected to bi-directional loading. In order to minimize modelling uncertainties inherent in the quantification of structural damage and the consideration of the supporting soil–foundation system for complex structural systems, an existing building damaged by the 2003 Lefkada earthquake was adopted as case study. This selection has an advantage in that ground excitation, soil profile and damage observations are all available, thus permitting calibration of the finite element model with the observed response, especially in terms of use of appropriate plasticity models and damage indices, plus the assessment of soil–structure interaction effects. After establishing a reliable finite element model of the structure under study, extensive parametric analyses for different EC8 compliant sets of records were conducted, permitting quantification of the discrepancy of the structural response due to record-to-record and set-to-set variability (i.e., intra-set and inter-set scatter, respectively). The results confirm that many of the observations found in the literature regarding the effect of ground motion selection on the predicted seismic performance of SDOF systems are also valid for bi-directionally excited, multi-storey, irregular buildings. Finally, the results also highlight specific limitations of the EC8 provisions that may lead to erroneous results in many practical cases.     

P-T estimates and timing of the sapphirine-bearing metamorphic overprint in kyanite eclogites from Central Rhodope, northern Greece

Sapphirine-bearing symplectites that replace kyanite in eclogites from the Greek Rhodope Massif have previously been attributed to a high-pressure granulite-facies metamorphic event that overprinted the eclogitic peak metamorphic assemblage. The eclogitic mineralogy consisted of garnet, omphacitic pyroxene, rutile and kyanite and is largely replaced by low-pressure minerals. Omphacite was initially replaced by symplectites of diopside and plagioclase that were subsequently replaced by symplectites of amphibole and plagioclase. Garnet reacted during decompression to form a corona of plagioclase, amphibole and magnetite. Rutile was partly transformed to ilmenite and kyanite decomposed to produce a high-variance mineral assemblage of symplectitic spinel, sapphirine, plagioclase and corundum. The presence of quartz and corundum in the kyanite eclogites is evidence for the absence of bulk equilibrium and obviates a conventional analysis of phase equilibria based on the bulk-rock composition. To circumvent this difficulty we systematically explored the pressure-temperature-composition (P-T-X) space of a thermodynamic model for the symplectites in order to establish the pressure-temperature (P-T) conditions at which the symplectites were formed after kyanite. This analysis combined with conventional thermometry indicates that the symplectites were formed at amphibolite-facies conditions. The resulting upper-pressure limit (～0.7 GPa) of the sapphirine-producing metamorphic overprint is roughly half the former estimate for the lower pressure limit of the symplectite forming metamorphic event. Temperature was constrained (T ～ 720°C) using garnet-amphibole mineral thermometry. The P-T conditions inferred here are consistent with thermobarometry from other lithologies in the Rhodope Massif, which show no evidence of granulite-facies metamorphism. Regional geological arguments and ion-probe (SHRIMP) zircon dating place the post-eclogite-facies metamorphic evolution in Eocene times.     

Multivariate statistics and hydrogeochemical modeling for source identification of major elements and heavy metals in the groundwater of Qareh-Ziaeddin plain,NW Iran

The present study aims to evaluate the possible source of major and some minor elements and heavy metals in the groundwater of Qareh-Ziaeddin plain, NW Iran with respect to chemical elements, saturation index, and multivariate statistics including correlation coefficient, cluster analysis, and factor analysis. Groundwater samples were collected in Jun 2016 and measured with respect to EC, pH, major and some minor elements and heavy metals including Fe, Mn, Zn, Cr, Pb, Cd, Al, and As. Among all the measured parameters, some of the samples exceed the World Health Organization (WHO) guideline value for EC, Na, Mg, HCO₃, SO₄, Cl, NO₃, F, As, Zn, and Pb. The results of correlation analysis show that weathering and dissolution of minerals especially evaporites and silicates, water-rock interaction, and cation exchange are dominant occurred processes in the groundwater of the study area. Also, denitrification process is occurred in the groundwater system. Cluster analysis categorizes the samples into three distinct groups which are different based on their EC and dependent variables, e.g., Na, Ca, Cl, SO₄ and pH, Pb, Cd, and As. It can be found that volcanic, evaporite, and clay formations have the least impact on the chemistry of the cluster 1 samples while clay and evaporite formations have the highest impact on the cluster 3 and also calcareous formations on cluster 2. Factor analysis shows that five factors, with total variance of 83%, are effective in the release of heavy metals and groundwater chemistry which are mostly geogenic.     

Slug test in confined aquifers, the over-damped case: quasi-steady flow analysis

In the great majority of slug tests performed in wells fully penetrating confined geologic formations, and for over-damped conditions, the response data are evaluated with the transient-flow model of Cooper et al. (1967) when the radial hydraulic conductivity K(r) and the coefficient of specific storage S(s) are to be estimated. That particular analytical solution, however, is computationally involved and awkward to use. Thus, groundwater professionals often use a few pre-prepared type-curves to fit the data by a rough matching procedure, visually or computationally. On the other hand, the method of Hvorslev (1951), which assumes the flow to be quasi-steady, is much simpler but yields only K(r) estimates. In this work, we develop a complete quasi-steady flow model that includes a storage balance inside the aquifer and allows estimating K(r) and S(s) simultaneously, through matching of the well response data to a type-curve. The new model approximates the model of Cooper et al. closely and has the practical advantage that its solution type-curves are generated easily using an electronic spreadsheet, so that the optimal fit of data by a type-curve can be readily automated.     

Metamorphic conditions and structural evolution of the Kesebir-Kardamos dome: Rhodope metamorphic complex (Greece-Bulgaria)

International Journal of Earth Sciences - The synmetamorphic nappe system of the Rhodope Metamorphic Complex has been deformed into dome-and-basin structures attributed to syn- to post-convergent...