Geochemistry of the Merensky reef, Rustenburg Section, Bushveld Complex: controls on the silicate framework and distribution of trace elements

This whole rock and silicate mineral study focuses on the genesis of the Merensky reef sequence, as well as the footwall and hanging wall norites at an area of Rustenburg Platinum Mines in a demonstrably normal (undisturbed) environment. Continuous sampling provides major and trace element variations and mineral compositions and allows an evaluation of the post- liquidus processes which affected the sequence. Following the formation of liquidus phases three stages are envisaged to have modified the rocks. These are (a) migration of fluid during early compaction of cumulates, (b) circulation of fluids within the crystal mush, and (c) reaction and solidification of trapped liquid. Liquidus compositions are nowhere preserved in the sequence. A strong link is demonstrated between orthopyroxene compositions (e.g. Mg# and TiO₂) and the incompatible trace element content of the whole rocks. The final amount of trapped liquid is shown to have been variable but never exceeded 10%. Calculated liquidus (pre-equilibration) orthopyroxene compositions show an up- sequence progression of evolving compositions from the footwall norite to the hanging wall norite. Initial Sr isotopic values do not support a simple magma mixing model by which radiogenic Main Zone magma mixes with that of the Critical Zone at the level of the Merensky reef. There is evidence that the hanging wall norite formed from a much more evolved magma. These conclusions have implications for the distribution and origin of the PGE-enriched Merensky reef package. Received: 7 October 1998 / Accepted: 5 March 1999     

Ocean urea fertilization for carbon credits poses high ecological risks

The proposed plan for enrichment of the Sulu Sea, Philippines, a region of rich marine biodiversity, with thousands of tonnes of urea in order to stimulate algal blooms and sequester carbon is flawed for multiple reasons. Urea is preferentially used as a nitrogen source by some cyanobacteria and dinoflagellates, many of which are neutrally or positively buoyant. Biological pumps to the deep sea are classically leaky, and the inefficient burial of new biomass makes the estimation of a net loss of carbon from the atmosphere questionable at best. The potential for growth of toxic dinoflagellates is also high, as many grow well on urea and some even increase their toxicity when grown on urea. Many toxic dinoflagellates form cysts which can settle to the sediment and germinate in subsequent years, forming new blooms even without further fertilization. If large-scale blooms do occur, it is likely that they will contribute to hypoxia in the bottom waters upon decomposition. Lastly, urea production requires fossil fuel usage, further limiting the potential for net carbon sequestration. The environmental and economic impacts are potentially great and need to be rigorously assessed.     

A comparison of classification systems for the conservation of sparsely wooded plains on Melville Island,Northern Australia

A floristic quadrat study of sparsely wooded plains on western Melville Island was conducted and used to define and describe floristic and structural vegetation types and identify their associated environmental correlates. The results were compared with an existing land‐unit survey of the area in order to identify the relative merits of these schemes for conservation planning. All schemes identify a range of broad structural types including Acacia shrubland, Grevillea pteridifolia low woodland, Lophostemon lactifluus low woodland, and Banksia dentata low woodland. However, some of the structural and land‐unit types are composed of two plant communities with distinctive environmental relations. Despite being structurally distinctive, some community types are floristically indistinguishable from surrounding forest dominated by Eucalyptus miniata and E. tetrodonta. The number of species captured by randomly selecting sites from each classificatory type revealed little difference between schemes. All the classificatory approaches were less effective at species capture than a simple iterative procedure. Some of the plant communities seem to be unique and require preservation initiatives in the face of current forestry operations and planned horticultural development.     

Hydrochemical and isotopic evidence of recharge,apparent age,and flow direction of groundwater in Mayo Tsanaga River Basin,Cameroon: bearings on contamination

Unplanned exploitation of groundwater constitutes emerging water-related threats to MayoTsanaga River Basin. Shallow groundwater from crystalline and detrital sediment aquifers, together with rain, dams, springs, and rivers were chemically and isotopically investigated to appraise its evolution, recharge source and mechanisms, flow direction, and age which were used to evaluate the groundwater susceptibility to contamination and the basin’s stage of salinization. The groundwater which is Ca–Na–HCO₃ type is a chemically evolved equivalent of surface waters and rain water with Ca–Mg–Cl–SO₄ chemistry. The monsoon rain recharged the groundwater preferentially at an average rate of 74 mm/year, while surface waters recharge upon evaporation. Altitude effect of rain and springs show a similar variation of −0.4‰ for δ¹⁸O/100 m, but the springs which were recharged at 452, 679, and 773 m asl show enrichment of δ¹⁸O through evaporation by 0.8‰ corresponding to 3% of water loss during recharge. The groundwater which shows both local and regional flow regimes gets older towards the basins` margin with coeval enrichment in F⁻ and depletion in NO₃ ⁻. Incidentally, younger groundwaters are susceptible to anthropogenic contamination and older groundwaters are sinks of lithologenic fluoride. The basins salinization is still at an early stage.     

Structural and timing constraints on molybdenum and tungsten mineralisation at Yea,Victoria

The molybdenite and scheelite mineralisation in the Native Dog Pluton at Monkey Gully near Yea is hosted within an I-type (post-orogenic) pluton, which shows extensive fractionation and magma mixing, and was emplaced in an extensional environment. The pluton comprises four principal rock types: tonalite, granodiorite, dacite and leucogranite. Emplacement of the pluton was in an extensional northwest to southeast paleostress field. Early extensional quartz veins, related to cooling, are overprinted by both dacitic dykes and late-stage quartz sheeted veins. The late-stage veins host the molybdenum and tungsten mineralisation in the deposit. ²⁰⁶Pb/²³⁸U zircon ages of 356 ±14 Ma and 375 ± 22 Ma place pluton formation and mineralisation at the onset of the Kanimblan Orogeny and later than other major molybdenum deposits in Victoria. Key factors governing the source for the granite and its associated mineralisation are: (1) the presence of a highly fractionated and sulfur-rich leucogranite; and (2) the pluton's location in a regional jog overlying the Selwyn basement block. Finally, a model is developed to explain the differences between this Melbourne Zone molybdenum and tungsten deposit compared with other metallogenic porphyry deposits.     

Modelled palaeo-temperature on Vøring, offshore mid-Norway — The effect of the Lower Crustal Body

The Vøring area, offshore mid-Norway has a complex geological history, has experienced several extensional phases and was significantly influenced by the break-up of the North Atlantic. We have modelled a cross-section over the Vøring Basin aiming to 1) reconstruct the basin evolution in a realistic way, and 2) to investigate the heat flow and temperature history in the basin.For the modelling we used the following tectonic events: the opening of the basin during the Permo-Triassic, an event during the Middle to Late Cretaceous and an event in the Late Cretaceous/Paleocene. The theoretical effects of the lithospheric stretching are depending on the palaeo-water depths of the area. We present a prediction of the palaeo-water depth, and a sensitivity analysis of the influence of the palaeo-water depth on the estimated beta-factors in the area.A lower crustal high-velocity body found in the area is often interpreted as magmatic underplating related to the break-up of the Norwegian Sea. We show the temperature history calculated by models that were run with and without assumption of underplating by a magmatic body emplaced during the Early Tertiary. The observed vitrinite reflectance in the Vøring area is best explained by numerical calculations of the vitrinite reflectance without a magmatic underplating. Our conclusion is that the Lower Crustal Body is not related to magmatic underplating or to significant sill intrusions. The body may consist of older mafic rocks, or a mixture of old continental crust and mafic intrusions.     

Developments in high-resolution solid-state13C NMR spectroscopy of coals

The recent development of “second generation” NMR experiments on coals is discussed in this paper. Such experiments have three aims: (1) To determine the extent to which quantitative aromaticity measurements can be made on coals by cross polarization-magic angle spinning (CP/MAS); (2) To obtain more detailed information on coal structure and reactivity than that given by the simple aromaticity measurements possible at the time; (3) To follow reaction pathways when coal is chemically modified. In this plenary lecture the relevant literature is reviewed, and new experimental work in all three areas outlined above is reported. Experimental evidence is presented which shows that aromaticity measurements on a bituminous coal by cross polarization (CP) or single pulse techniques give identical results. Relaxation data for naphthalene polymers suggest that these structures in coal are seen in CP experiments. Dipolar dephasing experiments suggest that the average size of the coal vitrinite molecule does not increase with increase in coal rank due to aromatic substitution reactions. Various relaxation experiments demonstrate how different carbon types can be distinguished in both¹³C-labelled and unlabelled coals.     

Rearing Shrimps in Pens: A Predictive Model for Impact Assessment

A predictive model for impact assessment of shrimp (Farfantepenaeus paulensis) culture in pen enclosures was developed. Experiments were carried out at Saco da Mangueira, a small embayment at the Patos Lagoon estuarine area (southern Brazil). Nitrogen budget was assessed considering inputs and outputs from the culture system. The measured parameters were water flow, shrimp density, pen mesh size and clogging effect, artificial diet quality, and food conversion rates. Shrimp excretion was estimated from literature available. A N-NT concentration of 0.07 mg L⁻¹ of was assumed as a conservative critical reference value to assess environmental impact and water deterioration. Trials showed that for Saco da Mangueira conditions, a total number of 70 pen enclosures of 0.3 ha (i.e., a total production of 32.2 ton) is recommended as a maximal number. This model is a useful tool for impact assessment and coastal management and may be applied to other estuarine areas.     

Easing conservation? Conservation easements, public accountability and neoliberalism

This paper examines the use of conservation easements, with a focus on California. Conservation easements are now the dominant tool used for private land conservation in the United States. Easements are in many ways a paradigmatic neoliberal environmental policy tool. They privatize and re-scale a great deal of land conservation decision-making authority; they are market-based; they provide financial incentives for participation rather than punishment for non-compliance; and they commodify new property rights. However, these neoliberalisms are incorporated in uneven, and sometimes contradictory, ways that emphasize the gulf between neoliberal ideologies and “actually existing neoliberalisms.” Most critically, as a result of extensive public funding and management, conservation easements are not nearly as private (and thus not as neatly neoliberal) as they sometimes seem. Conservation easements are often heralded as a “win–win” land conservation strategy. I argue that the extent to which conservation easements may be construed as win–win solutions depends a great deal on who is included in the calculation of winners and losers. I contend that using and governing easements as if they are private elides complex questions about larger public costs and benefits. This obscures the large number of people and institutions (both state and private) that will likely need to be involved in governing conservation easements in the long term.     

Explosive volcanic eruptions — V. Observations of plume dynamics during the 1979 Soufrière eruption, St Vincent

Summary During the 1979 eruption of the Soufrière of St Vincent, West Indies, a 14 min period of explosive activity occurred on April 22. The first three minutes of this activity were filmed. Five individual explosions formed distinct plumes which fed an eruption column which eventually ascended to a height of over 18 km. The ascent velocities of the fronts of these plumes ranged from 8.5 to 61.7 ms^-1. The half-angle of spreading of the plume fronts ranged from 21.5 to 24°. One of the plumes was observed to 8 km height and decelerated steadily from 51.5 to 23 ms^-1. The main column fed by individual explosions was, however, observed to accelerate from 8.5 to 58 m s^-1 in the same height interval.
A theoretical treatment of volcanic plume motion is presented. Measurements of dimensions, velocities and spreading rates from the film are used to estimate plume parameters such as temperature, particle content and volume discharge rate of magma from the theoretical relationships. These calculations show that the individual plumes became hotter and richer in juvenile ash with time. The acceleration of the main eruption column was the result of being fed by increasingly hotter and more ash-rich explosions. An average volume discharge rate of 12600m³ s^-1 is estimated from the analysis of the plume motions. This value agrees closely with an estimate of discharge rate based on the heat flux required to form an 18 km high column. This agreement suggests that theories of convective motions in plumes can be successfully adapted to the volcanic case, as long as the effect of hot entrained ash particles is considered.