An assessment of the utility of regional diatom‐based tidal‐level transfer functions

In order to understand natural sea‐level variability, and to enhance future predictions, accurate and precise estimates of Holocene tidal levels are required. Although the application of diatom‐based transfer functions can yield such data, these work best when underpinned by local training sets. Urbanized estuaries offer little prospect of obtaining local training sets and, instead, the reliability of regional transfer functions has to be assessed. The performance of a published regional (UK) diatom‐based tidal‐level transfer function applied to fossil assemblages from two contrasting core sites in the Mersey Estuary, UK, is assessed using modern analogue techniques and sediment isotope data. We find that, although estimated tidal levels coincide with changes in organic matter source, the frequent lack of modern analogues mean that palaeotide estimates are without basis. This is likely a consequence of the site‐specific nature of diatom assemblages in higher intertidal and supratidal areas in particular, where local factors are expected to exert a greater control on their ecology. This situation may be partly resolved by constructing and applying much larger regional training sets from multiple higher intertidal and supratidal sites (where intact). Otherwise the application of alternative techniques, such as regional foraminiferal tidal‐level transfer functions, may be more appropriate. Copyright © 2011 John Wiley & Sons, Ltd.     

Uncertainty assessment in river flow projections for Ethiopia’s Upper Awash Basin using multiple GCMs and hydrological models

ABSTRACT

Uncertainty in climate change impacts on river discharge in the Upper Awash Basin, Ethiopia, is assessed using five MIKE SHE hydrological models, six CMIP5 general circulation models (GCMs) and two representative concentration pathways (RCP) scenarios for the period 2071–2100. Hydrological models vary in their spatial distribution and process representations of unsaturated and saturated zones. Very good performance is achieved for 1975–1999 (NSE: 0.65–0.8; r: 0.79–0.93). GCM-related uncertainty dominates variability in projections of high and mean discharges (mean: –34% to +55% for RCP4.5, – 2% to +195% for RCP8.5). Although GCMs dominate uncertainty in projected low flows, inter-hydrological model uncertainty is considerable (RCP4.5: –60% to +228%, RCP8.5: –86% to +337%). Analysis of variance uncertainty attribution reveals that GCM-related uncertainty occupies, on average, 68% of total uncertainty for median and high flows and hydrological models no more than 1%. For low flows, hydrological model uncertainty occupies, on average, 18% of total uncertainty; GCM-related uncertainty remains substantial (average: 28%).     

Airports and Environment: Proposal of Wastewater Reclamation at São Paulo International Airport

One way to reduce water consumption in urban areas is by using alternative sources of supply that can be provided by collecting rainwater and reusing wastewater for less restricted purposes. Thus, this study evaluated the characteristics of effluents produced by the wastewater treatment plant (WWTP) of São Paulo International Airport (SPIA), Brazil, in order to reuse it in non‐potable situations. The results achieved, indicated high efficiency in the biological system utilized by SPIA. The removal rates is equal to or >90% for most of the parameters analyzed, among them, fluoride, salinity, nitrite, nitrate, ammonium nitrogen, total nitrogen, phosphorus, sedimentable solids, turbidity, conductivity, apparent color, chemical oxygen demand, biochemical oxygen demand, total organic carbon, fecal coliforms, and oils and greases. Despite the final effluents were good enough to be launched in the local streams, they shall be submitted to a complementary treatment in order to fit some quality parameters to be reused for specific demands (landscape irrigation, toilet flushing, vehicle washing, fire fighting, and dust control).     

Use of GIS for a spatial and temporal analysis of Kenyan wildlife with generalised linear modelling

This paper applies generalised linear statistical techniques in a GIS to analyse wildlife data from a Kenyan wildlife reserve and its surrounding areas. Attention focuses on the spatial distribution of elephant during nine successive surveys, analysing their temporal and spatial relationship to 12 environmental covariates. A principal component analysis identifies five major determining factors, thereby reducing dimensionality in the data, while a simple spatial analysis procedure, suitable for wildlife data obtained from airborne surveys, quantfies clustering for different animal species. The number of explanatory variables appearing in abundance models is found to be subject to large variations during successive surveys with a minimum and maximum of four and eight variables, respectively. Species from highly clustered populations are found to have over 20 times more observations within short distances compared to the rest. The study concludes that a combination of generalised linear modelling and GIS gives deeper insight into the dynamics of wildlife species in and around well-defined nature reserves.     

Engaging stakeholders in fisheries and marine research

Despite knowledge-brokering being of high interest to public policy, there is a lack of research integrating the knowledge of stakeholders and scientists, principally because public policies remain viewed as top-down controlled. To help European research policies make a positive difference to society, there is a need to better engage stakeholders with the delivery of research and to demonstrate an impact and value that it brings. The pertinent question addressed by this communication is: how can a deeper and more systematic engagement of stakeholders be enabled through European research activities? Enabling stakeholder participation in European research activities requires there to be an incentive for researchers and stakeholders to engage, and the capacity of stakeholders to operate effectively in the research framework. Unsurprisingly, the establishment of communications and cultures conducive to shared problem solving is high priority, as is the need to work towards a governance structure that helps link research with policy outcomes, while at the same time resonating directly with stakeholders. The Regional Advisory Councils could be a strong force in bringing stakeholders knowledge to bear on the scientific issues relevant to management, but their strategy and capacity to mobilise the skills to do so are not yet ready.     

A fundamental theorem for eco-environmental surface modelling and its applications

We propose a fundamental theorem for eco-environmental surface modelling(FTEEM) in order to apply it into the fields of ecology and environmental science more easily after the fundamental theorem for Earth's surface system modeling(FTESM). The Beijing-Tianjin-Hebei(BTH) region is taken as a case area to conduct empirical studies of algorithms for spatial upscaling, spatial downscaling, spatial interpolation, data fusion and model-data assimilation, which are based on high accuracy surface modelling(HASM), corresponding with corollaries of FTEEM. The case studies demonstrate how eco-environmental surface modelling is substantially improved when both extrinsic and intrinsic information are used along with an appropriate method of HASM. Compared with classic algorithms, the HASM-based algorithm for spatial upscaling reduced the root-meansquare error of the BTH elevation surface by 9 m. The HASM-based algorithm for spatial downscaling reduced the relative error of future scenarios of annual mean temperature by 16%. The HASM-based algorithm for spatial interpolation reduced the relative error of change trend of annual mean precipitation by 0.2%. The HASM-based algorithm for data fusion reduced the relative error of change trend of annual mean temperature by 70%. The HASM-based algorithm for model-data assimilation reduced the relative error of carbon stocks by 40%. We propose five theoretical challenges and three application problems of HASM that need to be addressed to improve FTEEM.     

Factors Controlling In Situ Biogeochemical Transformation of Trichloroethene: Column Study

In situ biogeochemical transformation involves biological formation of reactive minerals in an aquifer that can destroy chlorinated solvents such as trichloroethene (TCE) without accumulation of intermediates such as vinyl chloride. There is uncertainty regarding the materials and geochemical conditions that are required to promote biogeochemical transformation. The objective of this study was to identify amendments and biogeochemical conditions that promote in situ biogeochemical transformation. Laboratory columns constructed with plant mulch were supplemented with different amendments and were operated under varying conditions of water chemistry and hydraulic residence time. Four patterns of TCE removal were observed: (1) no removal, (2) biotic transformation of TCE to cis‐1,2‐dichloroethene (cis‐1,2‐DCE), (3) biogeochemical transformation of TCE without accumulation of reductive dechlorination products, and (4) mixed behavior where a combination of patterns was observed either simultaneously or over time. Principal coordinates analysis and analysis of variance (ANOVA) identified factors that promoted biogeochemical transformation: (1) high influent sulfate concentration, (2) relatively high hydraulic retention time, (3) supplementation of mulch with vegetable oil, and (4) addition of hematite or magnetite. The combination of the first three factors promoted complete sulfate reduction and a high volumetric sulfate consumption rate. The fourth factor provided a source of ferrous iron and/or a surface to which sulfide could react to form reactive iron sulfides. Many columns demonstrated either no TCE removal or a biotic TCE transformation pattern. Modification of column operation to include all four factors identified above promoted biogeochemical transformation in these columns. These results support the importance of the factors in biogeochemical transformation.     

Morphology of the Blanco Transform Fault Zone-NE Pacific: Implications for its tectonic evolution

The right-lateral Blanco Transform Fault Zone (BTFZ) offsets the Gorda and the Juan de Fuca Ridges along a 350 km long complex zone of ridges and right-stepping depressions. The overall geometry of the BTFZ is similar to several other oceanic transform fault zones located along the East Pacific Rise (e.g., Siquieros) and to divergent wrench faults on continents; i.e., long strike-slip master faults offset by extensional basins. These depressions have formed over the past 5 Ma as the result of continual reorientation of the BTFZ in response to changes in plate motion. The central depression (Cascadia Depression) is flanked by symmetrically distributed, inward-facing back-tilted fault blocks. It is probably a short seafloor spreading center that has been operating since about 5 Ma, when a southward propagating rift failed to kill the last remnant of a ridge segment. The Gorda Depression on the eastern end of the BTFZ may have initially formed as the result of a similar occurrence involving a northward propagating rift on the Gorda ridge system. Several of the smaller basins (East Blanco, Surveyor and Gorda) morphologically appear to be oceanic analogues of continental pull-apart basins. This would imply diffuse extension rather than the discrete neovolcanic zone associated with a typical seafloor spreading center. The basins along the western half of the BTFZ have probably formed within the last few hundred thousands years, possibly as the result of a minor change in the Juan de Fuca/Pacific relative motion.     

A New Method for Low‐Temperature Decomposition of Chromites and Dichromium Trioxide using Bromic Acid Evaluated by Chromium Isotope Measurements

In recent years, routine application of the stable isotope determination of chromium (Cr) in environmental and health protection research has led to the search for simpler chromite decomposition techniques. As the range of Cr isotope abundance ratios in nature is very narrow, conventional chromite decomposition techniques are no longer suitable, due to the relatively high risk of contamination during laboratory procedures. We have developed a protocol for the decomposition of chromites based on oxidation by bromic acid at room temperature. The procedure takes 15 d and requires two doses of bromic acid during the reaction period (day 1 and 8), due to the limited stability of the reagent. Chromium extracted by alkaline oxidative fusion and by bromic acid decomposition yielded statistically indistinguishable δ⁵³Cr values, measured by multi‐collector inductively coupled plasma‐mass spectrometry following addition of a ⁵⁰Cr‐⁵⁴Cr double‐spike.