Adsorptive Separation of 1, 2‐Dichloroethane from Model Wastewater by Natural Clinoptilolite

The adsorptive separation of 1, 2‐dichloroethane from model wastewater by different Slovak natural and octadecylammonium‐modified clinoptilolites has been studied. It was found that the 1, 2‐dichloroethane will be adsorbed by natural as well as by surfactant‐modified clinoptilolites; all clinoptilolites have a similar adsorption loading. There was also no remarkable difference between the natural and surfactant‐modified clinoptilolites in respect to the adsorption kinetics.     

Effective Roughness Calculated from Satellite-Derived Land Cover Maps and Hedge-Information used in a Weather Forecasting Model

In numerical weather prediction, climate and hydrologicalmodelling, the grid cell size is typically larger than the horizontal length scales of variations in aerodynamicroughness, surface temperature and surface humidity. These local land cover variations give rise to sub-gridscale surface flux differences. Especially the roughness variations can give a significantly differentvalue between the equilibrium roughness in each of the patches as compared to the aggregated roughness value,the so-called effective roughness, for the grid cell. The effective roughness is a quantity that secures thephysics to be well-described in any large-scale model. A method of aggregating the roughness step changesin arbitrary real terrain has been applied in flat terrain (Denmark) where sub-grid scale vegetation-drivenroughness variations are a dominant characteristic of the landscape. The aggregation model is a physicaltwo-dimensional atmospheric flow model in the horizontal domain based on a linearized version of theNavier Stoke equation. The equations are solved by the Fast Fourier Transformation technique, hence the codeis very fast. The new effective roughness maps have been used in the HIgh Resolution Limited Area Model(HIRLAM) weather forecasting model and the weather prediction results are compared for a number of casesto synoptic and other observations with improved agreement above the predictions based on currentstandard input. Typical seasonal springtime bias on forecasted winds over land of +0.5 m s^-1 and-0.2 m s^-1 in coastal areas is reduced by use of the effective roughness maps.     

Compositional classification of “kimberlitic” and “non-kimberlitic” ilmenite

Ilmenite is one of the common kimberlitic indicator minerals recovered during diamond exploration, and its distinction from non-kimberlitic rock types is important. This is particularly true for regions where these minerals are present in relatively low abundance, and they are the dominant kimberlitic indicator mineral recovered. Difficulty in visually differentiating kimberlitic from non-kimberlitic ilmenite in exploration concentrates is also an issue, and distinguishing kimberlitic ilmenite from those derive from other similar rocks, such as ultramafic lamprophyres, is practically impossible. Ilmenite is also the indicator mineral whose compositional variety has the most potential to resolve provenance issues related to mineral dispersions with contributions from multiple kimberlite sources.

Various published data sets from selected kimberlitic (including kimberlites, lamproites, and various ultramafic lamprophyres) and non-kimberlitic rock types have been compiled and evaluated in terms of their major element compositions. Compositional fields and bounding reference lines for ilmenites derived from kimberlites (sensu stricto), ultramafic lamprophyres, and other non-kimberlitic rock types have been defined primarily on MgO–TiO₂ graphs as well as MgO–Cr₂O₃ relationships.     

Intercomparison of Boron Isotope and Concentration Measurements. Part II: Evaluation of Results

The Istituto di Geoscienze e Georisorse (IGG), on behalf and with the support of the International Atomic Energy Agency (IAEA), prepared eight geological materials (three natural waters and five rocks and minerals), intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials were distributed to twenty seven laboratories - virtually all those performing geochemical boron isotope analyses in the world -which agreed to participate in the intercomparison exercise. Only fifteen laboratories, however, ultimately submitted the isotopic and/or concentration results they obtained on the intercomparison materials. The results demonstrate that interlaboratory reproducibility is not well reflected by the precision values reported by the individual laboratories and this observation holds true for both boron concentration and isotopic composition. The reasons for the discrepancies include fractionations due to the chemical matrix of materials, relative shift of the zero position on the δ¹¹B scale and a lack of well characterized materials for calibrating absolute boron content measurements. The intercomparison materials are now available at the IAEA (solid materials) and IGG (waters) for future distribution.     

Bridging Political Expectations and Scientific Limitations in Climate Risk Management – On the Uncertain Effects of International Carbon Sink Policies*

Despite great advances in carbon cycle research during the past decade the climatic impact of terrestrial ecosystems is still highly uncertain. Although contemporary studies suggest that the terrestrial biosphere has acted as a net sink to atmospheric carbon during the past two decades, the future role of terrestrial carbon pools is most difficult to foresee. When land use change and forestry activities were included into the Kyoto Protocol in 1997, the requirements for scientific precision increased significantly. At the same time the political expectations of carbon sequestration as climate mitigation strategy added uncertainties of a social kind to the study of land-atmosphere carbon exchange that have been difficult to address by conventional scientific methods. In this paper I explore how the failure to take into account the effects of direct human activity in scientific projections of future terrestrial carbon storage has resulted in a simplified appreciation of the risks embedded in a global carbon sequestration scheme. I argue that the social limits to scientific analysis must be addressed in order to accommodate these risks in future climate governance and to enable continued scientific authority in the international climate regime.     

Stresses induced by loading of an artificial basin

Geomagnetic effects related to the stresses induced by the water load of the Chiotas reservoir (NW Italy) were studied, with measurements of the geomagnetic field at different stages of filling. The highest effect, mean 7 nT, was recorded at three-quarters full; subsequently, as the volume of water increased, the anomalous variations fell to about 2 nT.     

Detection of a 50-day oscillation in the Wolf number

Резюме Вaрuaцuu с nерuо?rt;ом около 50 ?rt;неŭ (коmорые ?rt;aвно обнaружены в uзмененuях nро?rt;олжumельносmu суmок u во мно uх меmеороло uческuх велuчuнaх, особенно в моменmе колuчесmвa ?rt;вuженuя amмосферы) былu рaскрыmы в солнечноŭ aкmuвносmu, оnuсaнноŭ чuслом Вольфa.      

Aspects of the distribution, population structure and reproduction of the gastropod Tibia delicatula (Nevill, 1881) inhabiting the oxygen minimum zone of the Oman and Pakistan continental margins

The present study describes some aspects of the distribution and biology of Tibia delicatula (Nevill), a gastropod belonging to the family Strombidae. This species has been found in large numbers in the upper oxygen minimum zone (OMZ) of the Oman margin, and has also been collected from the OMZ of the Pakistan margin. The highest abundance of adult specimens in the Oman OMZ was found between 300 and 450 m. Numbers dropped rapidly below 450 m, to zero below 500 m depth. Similarly dense populations were not observed in the Pakistan OMZ. Multiple regression with oxygen concentration and depth indicates that depth (and its related variables) is the main factor explaining the variation in abundance of T. delicatula. The populations from the Oman and Pakistan OMZs were dominated by juveniles. This suggests a unimodal size structure with evidence of a marked recruitment event. Basic reproductive aspects were analysed. All specimens had a penis and sperm groove. The gonad wall consisted of reticular tissue that might be used for nutrient storage or as an irrigation system. Only vitellogenic oocytes were present. The large oocyte sizes observed (200–300 μm) suggest a lecithotrophic larval development.     

Development of methods to collect and analyze gasoline range (C5–C12) hydrocarbons from seabed sediments as indicators of subsurface hydrocarbon generation and entrapment

Gasoline range hydrocarbons (C₅–C₁₂) are usually associated with petroleum generation, yet few surface geochemical surveys have attempted to evaluate the gasoline range hydrocarbons in near-surface marine sediments. This is due to the difficulty in capturing and analyzing this volatile range of hydrocarbons with minimum loss and evaporative fractionation. In this study, a Headspace Solid Phase Microextraction (HSPME) method was developed and evaluated for the purpose of capturing the gasoline range of hydrocarbons within unconsolidated sediment using a solventless protocol.