CH4/N2/H2-spark hydrophobic tholins: A systematic approach to the characterisation of tholins. Part II

Two different simulation experiments of prebiotic synthesis were carried out in a CH₄/N₂/H₂ atmosphere with spark discharge activation of aqueous aerosols and liquid water. In both cases, a hydrophilic tholin and a hydrophobic tholin were obtained. The methodology developed by our group for the characterisation of hydrophilic tholins [Ruiz-Bermejo, M., Menor-Salván, C., Mateo-Martí, E., Osuna-Esteban, S., Martín-Gago, J.A., Veintemillas-Verdaguer, S., 2008. Icarus 198, 232-241] was used in order to study the hydrophobic tholins. The gas precursors of the tholins from mixtures containing CH₄, with and without H₂, were studied. We propose that the formation of the hydrophobic tholins involves the formation of unsaturated oligomeric hydrocarbon chains from vinyl and acetylene monomers, as well as allene derivatives formed in the gas phase after the incorporation of polar groups into these hydrocarbon chains. Finally, we compare our results concerning hydrophobic tholins with HCN polymers, since it is generally suggested that the polymeric material formed in spark experiments are possible oligomers of HCN, and that Titan’s tholins could be poly-HCN.     

Comparison of modelled- and remote sensing- derived daily snow line altitudes at Ulugh Muztagh,northern Tibetan Plateau

The ice cap Ulugh Muztagh in the central Kunlun Shan at the northern fringe of the Tibetan Plateau is a very isolated region with arid cold conditions. No observational, meteorological or glaciological ground truth data is available. Using the Moderate-resolution Imaging Spectroradiometer(MODIS) Level 1 radiance Swath Data(MOD02QKM) with a spatial resolution of 250 m, transient snow lines during the months of July to September in 2001 to 2014 are derived. Results are used to calibrate the physical based Coupled Snowpack and Ice surface energy and Mass balance model(COSIMA). The model runs on a representative detail region of Ulugh Muztagh(UM) on a digital elevation model with the same spatial resolution as the MODIS bands. In the absence of field observations, the model is driven solely by dynamically downscaled global analysis data from the High Asia Refined analysis(HAR). We compare remote sensing derived and modelled mean regional transient snow line altitudes in the course of consecutive summer seasons in 2008 to 2010. The resulting snow line altitude(SLA) and annual equilibrium line altitude(ELA) proxy of both methods coincide very well in their interannual variability in accordance with interannual variability of climatic conditions. Since SLAs of both methods do notconsistently agree on a daily basis a usage of remote sensing derived SLAs for model calibration in the absence of field observation data is only limitedly feasible for daily analysis. ELA approximation using the highest SLA at the end of ablation period may not be applied to UM because the negative winter mass balance(MB) is not reflected in the summer SLA. The study reveals moderate negative MB for UM throughout the modelling period. The mean regional MB of UM accounts for-523±410 mm w.e. a-1 in the modelling period. Hence UM seems not to belong to the area of the ‘Karakorum anomaly' comprising a region of positive mass balances in recent years which has its centre presumably in the Western Kunlun Shan.     

Time–Latitudinal Development of the White-Light Coronal Structures over a Solar Cycle

Large-scale coronal structures (helmet streamers) observed in the white-light corona during total solar eclipses and/or with ground-based coronagraphs are mostly located only above quiescent types of prominences. These helmet streamers are maintained due to the magnetic fields of the Sun. Time–latitudinal distribution of prominences during a solar cycle, however, shows both the poleward and equatorward migrations, similar to the 530.3 nm emission corona (the green corona) intensities. Distribution of observed coronal helmet streamers during total solar eclipses, enlarged with the helmet streamers as were obtained by the ground-based coronagraph observations, are compared with the heliographic distribution of prominences and the green corona intensities for the first time. It is shown that the distribution of above-mentioned helmet streamers, reflects – roughly – the time–latitudinal distribution of prominences and emission corona branches, and migrates together with them over a solar cycle.     

Development of methods to collect and analyze gasoline range (C5–C12) hydrocarbons from seabed sediments as indicators of subsurface hydrocarbon generation and entrapment

Gasoline range hydrocarbons (C₅–C₁₂) are usually associated with petroleum generation, yet few surface geochemical surveys have attempted to evaluate the gasoline range hydrocarbons in near-surface marine sediments. This is due to the difficulty in capturing and analyzing this volatile range of hydrocarbons with minimum loss and evaporative fractionation. In this study, a Headspace Solid Phase Microextraction (HSPME) method was developed and evaluated for the purpose of capturing the gasoline range of hydrocarbons within unconsolidated sediment using a solventless protocol.     

Bridging Political Expectations and Scientific Limitations in Climate Risk Management – On the Uncertain Effects of International Carbon Sink Policies*

Despite great advances in carbon cycle research during the past decade the climatic impact of terrestrial ecosystems is still highly uncertain. Although contemporary studies suggest that the terrestrial biosphere has acted as a net sink to atmospheric carbon during the past two decades, the future role of terrestrial carbon pools is most difficult to foresee. When land use change and forestry activities were included into the Kyoto Protocol in 1997, the requirements for scientific precision increased significantly. At the same time the political expectations of carbon sequestration as climate mitigation strategy added uncertainties of a social kind to the study of land-atmosphere carbon exchange that have been difficult to address by conventional scientific methods. In this paper I explore how the failure to take into account the effects of direct human activity in scientific projections of future terrestrial carbon storage has resulted in a simplified appreciation of the risks embedded in a global carbon sequestration scheme. I argue that the social limits to scientific analysis must be addressed in order to accommodate these risks in future climate governance and to enable continued scientific authority in the international climate regime.     

Depositional rates and dating techniques of modern deposits in the Brno reservoir (Czech Republic) during the last 70 years

Facies analysis, magnetic susceptibility, and analysis of grain size, TOC content and isotopes (¹³⁷Cs, ²¹⁰Pb, ²²⁶Ra, ²²⁸Ra, and ²³⁸U concentrations) were used to determine the history of the modern deposits of the Brno reservoir. The sedimentary succession can be subdivided into two main units. The lower unit is formed predominantly by medium- to coarse-grained silty sands and is interpreted as a fluvial succession deposited before the Svratka River was dammed. The upper unit consists of brownish planar laminated silts and rarely of clayey or sandy silts and is interpreted as a product of the reservoir deposition. The concentrations of ²³⁸U reflect the history of uranium mining in the upper part of the Svratka River catchment. As a consequence, ²¹⁰Pb radionuclide concentrations cannot be used for establishing a sediment chronology. Concentrations of ¹³⁷Cs show two marked peaks, the upper of which is attributed to the Chernobyl reactor accident in 1986, and the lower one is attributed to the maximum rate of atomic weapons testing in 1963. From these peaks, mean depositional rates of 3.2 cm year⁻¹ for the time period of 1986–2007 and of 3.4 cm year⁻¹ between 1963 and 1986 are calculated. Based on the known age of the reservoir, which was constructed in 1939, we can also calculate mean depositional rate for the time period of 1939–1963, which is 3.1 cm year⁻¹.