Spatial evolution of an AMD stream in the Iberian Pyrite Belt: process characterization and control factors on the hydrochemistry

ABSTRACT

This paper presents hydrochemical data of an AMD stream, Poderosa Creek, in the Iberian Pyrite Belt, obtained between its source, in the Poderosa Mine portal, and its confluence with the Odiel River. The main objective is to establish potential interdependent relationships between sulphate and metal loads and the following physico-chemical variables: pH, electrical conductivity (EC), redox potential (EH) and dissolved oxygen (DO). All the parameters show an overall increasing tendency from the tunnel exit to the confluence at the Odiel River. The TDS and EC are two relevant exceptions. They behave similarly, showing a decreasing trend and a strong inflection that describes a minimum immediately after the discharging point. Spatial analysis combined with statistical tools reveal typical AMD processes and the respective physico-chemical implications. Inputs with distinctive hydrochemical signatures impose relevant modifications in the Poderosa Creek waters. This indicates low hydrochemical inertia and high vulnerability to external stimuli.

Editor D. Koutsoyiannis; Associate editor not assigned     

Evaluation of geochemical data acquired from regular grids

Geochemical data obtained during mineral exploration often are biased by systematic as well as random errors; these may result in failures when usual methods of evaluation are used. This is true particularly in soil surveys carried out in regions where a long history of prospecting and mining activity has occurred and/or where aerial chemical pollution is likely to have occurred.A satisfactory evaluation of geochemical data even in such an unfavorable case requires sampling on a relatively dense grid and utilization of all available knowledge of types of mineralization. The evaluation procedure proposed consists of five consecutive phases: (1). Dividing the area of interest into subareas of a relatively homogeneous geological nature. (2). Processing by multivariate methods (factor analysis, in particular) without consideration of geographic relations. (3). A preliminary interpretation and search for a geochemical explanation of factors. (4). Processing of individual factors in two-dimensional geographic space by directional and frequency linear filtering methods. (5). Final interpretation and construction of a geochemical model. The procedure is illustrated by an example from a geochemical exploration survey in the vicinity of Píbram (Middle Bohemia).     

A Rule-Based Strategy for the Semantic Annotation of Geodata

The ability to represent geospatial semantics is of great importance when building geospatial applications for the Web. This ability will enhance discovery, retrieval and translation of geographic information as well as the reuse of geographic information in different contexts. The problem of generating semantic annotations has been recognized as one of the most serious obstacles for realizing the Geospatial Semantic Web vision. We present a rule‐based strategy for the semantic annotation of geodata that combines Semantic Web and Geospatial Web Services technology. In our approach, rules are employed to partially automate the annotation process. Rules define conditions for identifying geospatial concepts. Based on these rules, spatial analysis procedures are implemented that allow for inferring whether or not a feature in a dataset represents an instance of a geospatial concept. This automated evaluation of features in the dataset generates valuable information for the creation and refinement of semantic annotations on the concept level. The approach is illustrated by a case study on annotating data sources containing representations of lowlands. The presented strategy lays the foundations for the specification of a semantic annotation tool for geospatial web services that supports data providers in annotating their sources according to multiple domain views.     

Exploring Changes in Biodiversity Through Pictures: A Citizen Science Experience

To accurately document the accelerated changes in biodiversity, scientists need an accurate historic baseline to which to compare the current state of a locale. These historic baselines are hard to come by, and specifically in the coastal principality of Asturias (northern Spain), biodiversity information before 1980 is scarce, fragmented, or entirely lacking. However, most families still keep old photographs, and we wondered if these historic documentations of the environment could provide missing baseline biodiversity data. We conducted a case study asking volunteers to find old family photographs, then return to the same place to retake the photograph from the same perspective. We compiled these photographs and analyzed the changes in biodiversity indices between the past and present. Thus, we quantified diversity changes in the region over the last century.     

National contributions to climate change mitigation from agriculture: allocating a global target

Globally, agriculture and related land use change contributed about 17% of the world’s anthropogenic GHG emissions in 2010 (8.4 GtCO₂e yr^?1), making GHG mitigation in the agriculture sector critical to meeting the Paris Agreement’s 2°C goal. This article proposes a range of country-level targets for mitigation of agricultural emissions by allocating a global target according to five approaches to effort-sharing for climate change mitigation: responsibility, capability, equality, responsibility-capability-need and equal cumulative per capita emissions. Allocating mitigation targets according to responsibility for total historical emissions or capability to mitigate assigned large targets for agricultural emission reductions to North America, Europe and China. Targets based on responsibility for historical agricultural emissions resulted in a relatively even distribution of targets among countries and regions. Meanwhile, targets based on equal future agricultural emissions per capita or equal per capita cumulative emissions assigned very large mitigation targets to countries with large agricultural economies, while allowing some densely populated countries to increase agricultural emissions. There is no single ‘correct’ framework for allocating a global mitigation goal. Instead, using these approaches as a set provides a transparent, scientific basis for countries to inform and help assess the significance of their commitments to reducing emissions from the agriculture sector.

Key policy insights

• Meeting the Paris Agreement 2°C goal will require global mitigation of agricultural non-CO₂ emissions of approximately 1 GtCO₂e yr^?1 by 2030.

• Allocating this 1 GtCO₂e yr^?1 according to various effort-sharing approaches, it is found that countries will need to mitigate agricultural business-as-usual emissions in 2030 by a median of 10%. Targets vary widely with criteria used for allocation.

• The targets calculated here are in line with the ambition of the few countries (primarily in Africa) that included mitigation targets for the agriculture sector in their (Intended) Nationally Determined Contributions.

• For agriculture to contribute to meeting the 2°C or 1.5°C targets, countries will need to be ambitious in pursuing emission reductions. Technology development and transfer will be particularly important.

     

Ecological consequence of the introduction of the polychaete Marenzelleria cf. viridis into a shallow-water biotope of the northern Baltic Sea

Effects of the North American polychaete Marenzelleria cf. viridis on a simple shallow-water benthic community of the northern Baltic Sea were studied in a field experiment combining natural densities of dominating macrofaunal species. The presence of M. cf. viridis increased benthic production (chlorophyll a) and reduced the survival of the native polychaete Nereis diversicolor. Adult Macoma balthica caused a significant mortality on M. cf. viridis whereas adult Cerastoderma glaucum had no effect on M. cf. viridis. We suggest that the competitive interactions between M. cf. viridis and M. balthica are a possible key factor determining the distribution pattern of M. cf. viridis in the Baltic Sea.     

Mechanisms of imposex induction in the mud snail,Ilyanassa obsoleta: TBT as a neurotoxin and aromatase inhibitor

The occurrence of imposex, imposition of male sex characteristics on female snails, has been extensively documented throughout the world. Tributyltin (TBT) and other organotins have been causally linked to imposex induction at levels as low as 2 ng/l. There are several proposed mechanisms of action. First, TBT has been shown to be neurotoxic and to accumulate in snail ganglia. Peptide hormones control sexual differentiation in gastropods, and one hypothesis is that TBT acts as a neurotoxin to abnormally release the peptide hormone Penis Morphogenic Factor (PMF). However, PMF has not been characterized to date. The neuropeptide APGWamide significantly induces imposex in the mud snail, Ilyanassa obsoleta, at 10(-16) moles sub-cutaneous (SQ) injection over 2 weeks, and could be the PMF in this species. A second hypothesis is that TBT inhibits aromatase activity leading to increased testosterone levels and decreased estradiol. In vitro studies with snail digestive gland microsomes showed that TBT-dosed snails not exhibiting imposex had a 52% reduction in aromatase activity. Although the role of vertebrate sex steroids is not known in gastropods, it is possible that the combination of changes in peptide and steroid hormones may lead to imposex induction at extremely low doses of TBT.     

Oil spills in Narragansett Bay: Comparison between federal and state records

Oil spill response in the US is divided among several jurisdictions due to separate and overlapping legislative and regulatory authority. In Rhode Island, data concerning oil spill incidents are kept by two agencies of the federal government and by one agency of the state government. Narragansett Bay and its tributaries are geographically in three jurisdictions; however, because of a tradition of good interagency cooperation, there were very few duplications in spill response. Because each agency has differing expertise and equipment, the types of spill incidents reported by each, if considered separately, present an entirely different picture of the nature of oil spills in this region. Assessment of oil spills as a source of pollution to coastal waters requires examination of all data, not only that from one agency. For Narragansett Bay and its tributaries, oil spills were a minor part of the total oil pollution budget.