Ambient nanoparticles/nanominerals and hazardous elements from coal combustion activity:Implications on energy challenges and health hazards

Coal is the most abundant fossil fuel in the world. Because of the growth of coal mining, coal-fired power plants and coal-burning industries, the increase of the emission of particulates(coarse, fine or ultrafine)is of great concern. There is a relationship between increasing human morbidity and mortality and progressive environmental air pollution caused by these types of particles. Thus, the knowledge of the physico-chemical composition and ambient concentrations of coal-derived nanoparticles will improve pollution control strategy. Given the current importance of this area of research, the advanced characterization of this coal combustion-derived nanoparticles/nanominerals as well as hazardous elements is likely to be one of the hottest research fields in coming days. In this review, we try to compile the existing knowledge on coal-derived nanoparticles/nanominerals and discuss the advanced level of characterization techniques for future research. This review also provides some of aspects of health risks associated with exposure to ambient nanoparticles. In addition, the presence of some of the hazardous elements in coal and coal combustion activities is also reviewed.     

Application of the coconut fiber in radioactive liquid waste treatment

The treatment of radioactive liquid waste containing organic compounds was always a cause for concern to radioactive waste management facilities because the processes available are expensive and difficult to manage. Biosorption has been studied as a new process in simulated wastes as an alternative to treating them. Among the potential biomass, the coconut fiber has very attractive features that allow the removal of radionuclides using a low-cost biosorbent. The aim of this study was to evaluate the capacity of coconut fiber to remove uranium, americium, and cesium from real radioactive liquid organic waste. Experiments with the biosorption of these radionuclides in coconut fiber were made including (1) preparation, activation, and characterization of biomass and (2) biosorption assays. The biomass was tested in raw and activated form. Biosorption assays were performed, adding the biomass to real waste solutions. The solutions contain natural uranium, americium-241, and cesium-137. The contact times and the concentrations range were varied. The radioisotopes remaining concentration in the solutions was determined by inductively coupled plasma optical emission spectrometry and gamma spectrometry. The results were evaluated by maximum experimental sorption capacity and isotherm and kinetics ternary models. The highest sorption capacity was observed with the activated coconut fiber, with values of 2 mg/g of U (total), 70E?06 mg/g of Am-241 and 40E?09 mg/g of Cs-137. These results suggest that biosorption with activated coconut fiber can be applied in the treatment of radioactive liquid organic wastes containing uranium, americium-241, and cesium-137.     

Evaluation of susceptibility for terrain collapse and subsidence in karst areas,municipality of Iraquara,Chapada Diamantina (BA), Brazil

The morphological evolution of the karstic systems is associated with a set of physical and chemical processes, triggered by the dissolution of the rocks, related to percolation of groundwater and surface water, which consequently open underground voids and carve out peculiar forms of relief. Due to environmental and geotechnical aspects, this system is naturally more fragile and vulnerable than other natural systems and, therefore, has increasingly received the attention of the scientific community over the past decades. The objective of the study was to delimit zones with varying degrees of susceptibility for collapses and subsidence of sinkholes in the municipality of Iraquara, Chapada Diamantina (BA), Brazil, and to understand their geological and morphological determinant factors. Geological data, karst phenomenon map, and visual analysis in the field were used to categorize zones with different types of susceptibilities to the nucleation of new sinkholes based on a Hazard Index. This index was defined from the sum of geological hazard factors, lineament density, and sinkhole density. The areas that presented the highest susceptibility for terrain collapse and subsidence corresponded to regions where carbonate rocks outcrop, with high density of photolineaments and 2.62 sinkholes/km². Processes associated with terrain collapse and subsidence in karst areas consisted of a combination of various factors, hindering precise predictions. However, zones of different types of susceptibilities to terrain collapse and subsidence can be delimited when the relationships between these processes and their factors are understood. The Hazard Index proposed does not provide quantitative values for the probability of hazard susceptibility, but rather indicates areas that are more susceptible to terrain subsidence and collapse.     

Tebuthiuron leaching in three Brazilian soils as affected by soil pH

Underground contamination water by herbicides depends on the interactions between their molecules with physical and chemical soil characteristics and climatic conditions. Studies with columns can estimate the leaching potential of herbicides in soils. This study aimed to determine the effect of soil pH on tebuthiuron leaching, and capacity of bioindicators to detect tebuthiuron residues in three Brazilian soils. Cucumber plants (Cucumis sativus) were more negatively affected when grown in soils with lower amounts of organic matter and clay, and in these soils, the tebuthiuron levels reached greater depths in the column. There was a positive correlation between tebuthiuron concentration and cucumber intoxication, and a negative correlation between tebuthiuron concentration and dry matter cucumber in all soils. The tebuthiuron leached up to 50 cm depth even in soils with higher organic matter and clay content. The increasing of soil pH can affect the leaching of nonionic herbicides, and liming practice may elevate the environmental contamination risk by tebuthiuron. The bioindicator method using Cucumis sativus is viable and can be recommended to detect tebuthiuron concentrations above 0.2 mg kg^?1.     

Vulnerability to contamination by phosphorus in a zero-order basin with a high density of pigs and a history of slurry addition: extrapolation of an index

The application of phosphorus (P)-index methodology to assess the risk of water pollution from agriculture in river basins usually takes time and expends a great amount of resources. This study adapted the P-index methodology using digital mapping of key basin risk criteria for P loss in reference areas to evaluate the wider vulnerability to P loss in a zero-order basin with an intense concentration of pigs and with a history of pig slurry additions to the soil. The P content of eleven reference areas, where ten areas have received various applications of pig slurry and one area has no history of addition, was extrapolated to a zero-order basin using principal component analysis and analysis of hierarchical groupings. Estimated loss of soil and the distance between the P source and the watercourse were mapped using satellite images and in situ evaluations. The methodology of extrapolating was well correlated with a survey of P concentrations in land runoff and provides the potential to improve land management of those areas that are most vulnerable. Principal component analysis and hierarchical clustering analysis proved to be useful tools for the separation of areas with different slurry application times. Our results suggest that the P loss risk could be reduced through the adoption of soil conservation techniques such as reduced-tillage incorporating slurry and crop residue management to provide adequate soil protection, reduce the impact of raindrops and reduce erosion risk and transport of chemical pollutants to water bodies.     

Influence of a Drought Event on Hydrological Characteristics of a Small Estuary on the Amazon Mangrove Coast

The effects of atypical climatic conditions, such as those of a drought event, are remarkably accentuated in minor estuaries filled with sediments and with reduced or sporadic freshwater input, where the salinity intrusion is pronounced. To understand these effects, hydrological and hydrodynamic parameters were evaluated during a drought period in a small estuary located on the eastern Amazon coast in northern Brazil. Five campaigns were conducted between June 2012 and June 2013. Samples were collected from the surface and bottom layer every 3 h over a 25-h period at three stations of the Taperaçu Estuary. To compare drought and post-drought periods, in terms of salinity and chlorophyll-a, data was recorded until June 2015. Taperaçu is a relatively shallow estuary of the Amazon coastal zone, which is characterized by the absence of any direct fluvial discharge, although it does receive freshwater input from adjacent wetlands, as well as less saline waters from the Caeté Estuary through the Taici Creek. Hydrological variables were controlled by rainfall levels and the tidal range, and the water became more saline and more oxygenated, with reduced dissolved nutrient and chlorophyll-a concentrations when precipitation decreased. A significant variation was found between the months of June 2012 (most intense drought) and 2013 (less intense drought). The connection to the neighboring Caeté Estuary and adjacent mangroves and wetlands contributed to the influx of nutrient-enriched waters. Overall, then, it is hoped that the results of this study can contribute to the understanding of the effects of drought events in other minor estuaries on the highly indented Amazon coast, as well as in other areas of the equatorial zone with similar environmental characteristics.     

New impact equation using barrier Froude number for the design of dual rigid barriers against debris flows

Landslides - In the design of multiple rigid barriers, the height of the first barrier governs the impact dynamics of debris flow on the next barrier in a channel. However, current design...