Environmental issues in urban groundwater systems: a multidisciplinary study of the Paranhos and Salgueiros spring waters,Porto (NW Portugal)

This study presents the results of a multidisciplinary approach, using hydrogeochemical, isotopic and ecotoxicological analyses, performed to assess the nature and suitability for use of Paranhos and Salgueiros spring waters (Porto city, NW Portugal). Based on the surface activities located along the course of the springs, 23 water samples were collected. All the samples were analysed for major element concentrations. The isotopic techniques employed included δ²H, δ¹⁸O and ³H. Standard acute bioassays with Daphnia magna were also performed. The hydrogeochemical analyses showed a nitrate and sulphate-enriched composition for these groundwaters, resulting mainly from urban drainage and sewer leakage. In the ecotoxicological analyses, no significant mortality was observed in any of the tests performed. The results obtained in this study suggest that Porto urban groundwater could be suitable for irrigation uses.     

The late pleistocene paleoenvironment and paleoclimate of the madaras section (South Hungary), based on preliminary records from mollusks

24 species and 110 506 specimens of mollusks were collected and identified from 250 samples of the loess profile at Madaras, South Hungary. According to changes in the mollusk fauna, six malacological-paleoecological zones can be identified in this profile. The Quaternary malacological data from the Madaras loess section suggest that the Middle and Late Pleniglacial development of the mollusk fauna, and local climatic and environmental conditions in this area differed from other loess regions in Europe.     

Preliminary malacological investigation on the loess profile at Zmajevac, Croatia

More than 5 500 specimens of 37 terrestrial snail species were collected from a loess paleosol section at Zmajevac village, Croatia. The presence of Ena montana, Mastus bielzi, Cochlodina laminata, Macrogastra ventricosa, Clausilia pumila, Clausilia dubia, Pseudofusulus varians, Trichia unidentata and Trichia edentula species from the lower paleosol layer suggests that this malacological zone formed during the initial phase of a Middle Pleistocene interglacial cycle.     

Modeling biodiversity loss by global warming on Pantepui, northern South America: projected upward migration and potential habitat loss

This work aims to estimate the potential effects of the global warming projected for the twenty-first century on the biodiversity of a remote and pristine region of the Neotropics called Pantepui. Habitat loss and fragmentation by upward migration of bioclimatic conditions is analyzed using Species-Area Relationships (SAR) and Altitudinal Range Displacement (ARD) analysis. The ARD is a tool that uses the present-day lapse rate to estimate the upward migration of the species based on the global warming predicted by the IPCC. The results show that around 80% of the vascular flora, ca. 1,700 species of which up to 400 would be Pantepui endemics, are threatened of extinction. These estimates should be considered preliminary, but the danger is real. Therefore, suitable conservation or mitigation strategies are needed.     

Cloud condensation nuclei from biomass burning during the Amazonian dry-to-wet transition season

Aircraft measurements of cloud condensation nuclei (CCN) during the Large-Scale Biosphere–Atmosphere Experiment in Amazonia (LBA) were conducted over the Southwestern Amazon region in September–October 2002, to emphasize the dry-to-wet transition season. The CCN concentrations were measured for values within the range 0.1–1.0% of supersaturation. The CCN concentration inside the boundary layer revealed a general decreasing trend during the transition from the end of the dry season to the onset of the wet season. Clean and polluted areas showed large differences. The differences were not so strong at high levels in the troposphere and there was evidence supporting the semi-direct aerosol effect in suppressing convection through the evaporation of clouds by aerosol absorption. The measurements also showed a diurnal cycle following biomass burning activity. Although biomass burning was the most important source of CCN, it was seen as a source of relatively efficient CCN, since the increase was significant only at high supersaturations.     

Downscaling extreme month-long anomalies in southern South America

We investigate the performance of one stretched-grid atmospheric global model, five different regional climate models and a statistical downscaling technique in simulating 3 months (January 1971, November 1986, July 1996) characterized by anomalous climate conditions in the southern La Plata Basin. Models were driven by reanalysis (ERA-40). The analysis has emphasized on the simulation of the precipitation over land and has provided a quantification of the biases of and scatter between the different regional simulations. Most but not all dynamical models underpredict precipitation amounts in south eastern South America during the three periods. Results suggest that models have regime dependence, performing better for some conditions than others. The models’ ensemble and the statistical technique succeed in reproducing the overall observed frequency of daily precipitation for all periods. But most models tend to underestimate the frequency of dry days and overestimate the amount of light rainfall days. The number of events with strong or heavy precipitation tends to be under simulated by the models.     

Paleolimnologically inferred eutrophication of a shallow, tropical, urban reservoir in southeast Brazil

We studied the eutrophication history of a tropical shallow reservoir in the S?o Paulo metropolitan region, southeast Brazil. We analyzed grain size, geochemistry, diatom assemblages, and land-use records in a sediment core from the reservoir to infer its trophic state history during the last ~110?years (1894?C2005). Eighty diatom species were observed in the core and shifts in the relative abundances of planktonic and benthic taxa indicate major limnological changes associated with complex interactions between hydrologic factors and eutrophication. Discostella stelligera was associated with deforestation and water physical changes whereas Aulacoseira granulata, a species abundant throughout the core, was mostly associated with high flux conditions and erosion events, regardless of trophic state. Eutrophication was triggered by construction of the city zoo (1958) and installation of the S?o Paulo State Department of Agriculture (1975) within the Gar?as watershed, and increasing loads of untreated sewage from these institutions. The data suggest that deterioration in water quality began after ~1975 and markedly accelerated after ~1990. The reservoir has been hypereutrophic since 1999. Steady increases in geochemical proxies for trophic state, along with a decrease in C/N ratios, indicated higher nutrient concentrations and the prevalence of autochthonous production towards the core top. Appearance of Achnanthidium catenatum ~1993 highlighted the onset of a marked eutrophication phase. The subsequent dominance of Planothidium rostratum and Cyclotella meneghiniana suggested a sharp shift to a hypereutrophic state since 1999. Land-use history proved valuable for validating the chronology and interpreting anthropogenic impacts. Multi-proxy analysis of the sediment record provided an effective tool for tracking ecological shifts in the reservoir ecosystem. This study provides the first reconstruction of lake eutrophication history in Brazil and highlights the importance of hydrological/physical changes as drivers of diatom assemblage shifts in reservoirs, which may confound trophic state inferences based on shifts in the planktonic/benthic diatom ratio.     

The 1996 eruption at Gjálp,Vatnajökull ice cap,Iceland: efficiency of heat transfer,ice deformation and subglacial water pressure

The 13-day-long Gjálp eruption within the Vatnajökull ice cap in October 1996 provided important data on ice–volcano interaction in a thick temperate glacier. The eruption produced 0.8 km³ of mainly volcanic glass with a basaltic icelandite composition (equivalent to 0.45 km³ of magma). Ice thickness above the 6-km-long volcanic fissure was initially 550–750 m. The eruption was mainly subglacial forming a 150–500 m high ridge; only 2–4% of the volcanic material was erupted subaerially. Monitoring of the formation of ice cauldrons above the vents provided data on ice melting, heat flux and indirectly on eruption rate. The heat flux was 5–6×10⁵ W m^-2 in the first 4 days. This high heat flux can only be explained by fragmentation of magma into volcanic glass. The pattern of ice melting during and after the eruption indicates that the efficiency of instantaneous heat exchange between magma and ice at the eruption site was 50–60%. If this is characteristic for magma fragmentation in subglacial eruptions, volcanic material and meltwater will in most cases take up more space than the ice melted in the eruption. Water accumulation would therefore cause buildup of basal water pressure and lead to rapid release of the meltwater. Continuous drainage of meltwater is therefore the most likely scenario in subglacial eruptions under temperate glaciers. Deformation and fracturing of ice played a significant role in the eruption and modified the subglacial water pressure. It is found that water pressure at a vent under a subsiding cauldron is substantially less than it would be during static loading by the overlying ice, since the load is partly compensated for by shear forces in the rapidly deforming ice. In addition to intensive crevassing due to subsidence at Gjálp, a long and straight crevasse formed over the southernmost part of the volcanic fissure on the first day of the eruption. It is suggested that the feeder dyke may have overshot the bedrock–ice interface, caused high deformation rates and fractured the ice up to the surface. The crevasse later modified the flow of meltwater, explaining surface flow of water past the highest part of the edifice. The dominance of magma fragmentation in the Gjálp eruption suggests that initial ice thickness greater than 600–700 m is required if effusive eruption of pillow lava is to be the main style of activity, at least in similar eruptions of high initial magma discharge.Editorial responsibility: J. Donnelly-Nolan     

Probing the relationship between surface waters and aquifers by <Superscript>18</Superscript>O measurements on the top of the Araripe Plateau/NE Brazil

The Araripe Plateau in northeastern Brazil has an area of about 8,000 km², confined by 39°05E and 40°55E, and 7°10S and 7°50S. Due to high permeability of soils, a surface drainage system is practically inexistent. Water is stored in excavations with clayey soil, the barreiros. Monthly samples were taken for ¹⁸O measurements, from September 1999 to August 2000, from four barreiros, three dug wells and five drilled wells. Results show that (1) groundwaters in the eastern part of the plateau are derived from present-day rainfall (¹⁸O–3.2), whereas groundwaters in the western portion are isotopically different (¹⁸O–5.0); (2) barreiros are strongly marked seasonally by elevated ¹⁸O during the dry period due to elevated evaporation; (3) a dug well at a distance of 30 m from a barreiro exhibits ¹⁸O similar to that of the reservoir, indicating a strong interaction between groundwater and surface water; and (4) a tubular well of 242-m depth, located in a fault, exhibits strong seasonal changes in ¹⁸O and electrical conductivity, revealing downward leakage between aquifers.