Electron Density distribution and bonding in silicates

This paper summarizes the recent results of the investigation of bonding in silicates obtained by precision X-ray diffraction. The experimental electron density distribution is compared with theoretical electron density maps calculated for model silicate molecules. The characteristic features of the chemical bonds in ortho-, ring-, chain- and framework silicates are discussed.     

Geochemistry and health aspects of F-rich mountainous streams and groundwaters from sierras Pampeanas de Cordoba,Argentina

Symptoms of dental fluorosis have been observed in rural communities located in the Sierras Pampeanas de Córdoba, a mountainous area in Central Argentina. The clinical assessment was performed in the Charbonier Department, where the fluoride (F⁻) intake was determined to be 3.90 ± 0.20 mg day⁻¹ (n = 16). In this community, mild and severe fluorosis reach an incidence of 86.7% (total teeth surface = 636 teeth) among the children population. To determine the origin and distribution of fluorine in natural waters from the Charbonier Department and nearby regions, sampling was performed in the area covering the San Marcos River basin. The obtained results show that F⁻ concentrations vary between ~1 to ~2.5 mg l⁻¹, with an outlier value of 8 mg l⁻¹. The spatial distribution of F⁻ shows that the lowest concentrations are found at the basin’s catchments. Maximum values are located in two sectors of the basin: the Charbonier depression in the eastern part and at the San Marcos village, downstream the main collector, in the western part of the basin. In these two regions, the F⁻ contents in ground- and surface waters are >2.0 mg l⁻¹ and nearly constant. Dissolved F⁻ in natural waters from the study area has its origin in the weathering of F-bearing minerals present in the region’s dominant lithology. The extent of mineral weathering is mostly determined by the residence time of water within the aquatic reservoir. Longer residence times and a major solid–water interaction lead to enhanced release of F⁻. This explains the higher F⁻ concentrations found in basin areas with lower run off. The removal of F⁻ from water appears to occur by neither fluorite precipitation, nor by adsorption. Hence, variations in F⁻ concentrations seem to be more related to regional hydrological conditions.     

Developing synergy regression models with space-borne ALOS PALSAR and Landsat TM sensors for retrieving tropical forest biomass

Forest stand biomass serves as an effective indicator for monitoring REDD (reducing emissions from deforestation and forest degradation). Optical remote sensing data have been widely used to derive forest biophysical parameters inspite of their poor sensitivity towards the forest properties. Microwave remote sensing provides a better alternative owing to its inherent ability to penetrate the forest vegetation. This study aims at developing optimal regression models for retrieving forest above-ground bole biomass (AGBB) utilising optical data from Landsat TM and microwave data from L-band of ALOS PALSAR data over Indian subcontinental tropical deciduous mixed forests located in Munger (Bihar, India). Spatial biomass models were developed. The results using Landsat TM showed poor correlation (R² = 0.295 and RMSE = 35 t/ha) when compared to HH polarized L-band SAR (R² = 0.868 and RMSE = 16.06 t/ha). However, the prediction model performed even better when both the optical and SAR were used simultaneously (R² = 0.892 and RMSE = 14.08 t/ha). The addition of TM metrics has positively contributed in improving PALSAR estimates of forest biomass. Hence, the study recommends the combined use of both optical and SAR sensors for better assessment of stand biomass with significant contribution towards operational forestry.     

Chemical Composition,U–Th–Pb Age,and Geodynamic Setting of Metavolcanic Filla Series (Rauer Islands,East Antarctica)

Geotectonics - An assemblage of mafic granulites (schists), plagiogneisses, and metasedimentary rocks, which is referred to as the Filla Series, is exposed in the Rauer Islands (opposite the...     

The Linear Coregionalization Model and the Product–Sum Space–Time Variogram

The product covariance model, the product–sum covariance model, and the integrated product and integrated product–sum models have the advantage of being easily fitted by the use of marginal variograms. These models and the use of the marginals are described in a series of papers by De Iaco, Myers, and Posa. Such models allow not only estimating values at nondata locations but also prediction in future times, hence, they are useful for analyzing air pollution data, meteorological data, or ground water data. These three kinds of data are nearly always multivariate and because the processes determining the deposition or dynamics will affect all variates, a multivariate approach is desirable. It is shown that the use of marginal variograms for space–time modeling can be extended to the multivariate case and in particular to the use of the Linear Coregionalization Model (LCM) for cokriging in space–time. An application to an environmental data set is given.     

A steady state model of the Somali current

A steady state model of the Somali current including forcing by both the curl and the divergence of the wind stress is discussed. The model equations are linear, but the results presented are for the one nonlinear case. The grid resolution was 12 km in the zonal and 24 km in the meridional direction. The streamfunction and velocity potential of the current are presented for forcing by divergence and compared with a situation when only the curl is present. The results indicate that a two-gyre system appears in July, a representative month for the summer monsoon, only when divergence is included. Computations with available data indicate that the divergence is comparable in magnitude to the curl near the location of the Somali current. The model produces three other important features: (i) strong upwelling off the east coast of Africa, (ii) downwelling over central Arabian sea and (iii) a strong eastward current in the upper layer towards the interior of the Arabian sea near 12°N.     

A lithogeochemical approach to Stratigraphical problems at the Millstream potash deposit, New Brunswick, Canada

A lithogeochemical study was undertaken of the Millstream potash deposit, New Brunswick, Canada, a marine evaporite deposit with a complex depositional and tectonic history. The objective of the study was to determine if potash intersections in boreholes represent different geological horizons, or the same stratum repeated by folding or faulting. The deposit is found at a depth of 800–1000 m.Water-soluble and -insoluble fractions of drill core from five ore zones in four holes were analyzed using multielement ICP instrumentation following sequential hot water and aqua regia leaches. Meaningful variations in the data for the different ore zones were evident for eight elements in the water-soluble portion, and for seventeen elements in the water-insoluble residue. These results characterize a lowermost sylvinite unit which is relatively depleted in most elements, with the exception of Mg and Al in the residue. Regression analysis indicates a weak correlation between Fe and the common base metals, in contrast to the immediately overlying sylvinite unit which is relatively enriched in most elements, including Fe, but where Fe apparently exerts no control over the base metals. Cluster analysis confirms these two units are easily distinguished from each other. The upper two ore horizons are distinguishable from the lower units on the basis of different abundances of some elements, such as water-soluble B, and on the strong scavenging abilities of Fe on the common base metals.No single element is able to uniquely fingerprint a particular sylvinite horizon, but suites of elements are able to classify each horizon as geochemically distinctive. The results appear to confirm the validity of the geological correlations.     

Reduction of mass loss by the hot Jupiter WASP-12b due to its magnetic field

The influence of the dipolar magnetic field of a “hot Jupiter” with the parameters of the object WASP-12b on the mass-loss rate from its atmosphere is investigated. The results of three-dimensional gas-dynamical and magnetohydrodynamical computations show that the presence of a magnetic moment with a strength of ~0.1 the magnetic moment of Jupiter leads to appreciable variations of the matter flow structure. For example, in the case of the exoplanet WASP-12b with its specified set of atmospheric parameters, the stream from the vicinity of the Lagrange point L₁ is not stopped by the dynamical pressure of the stellar wind, and the envelope remains open. Including the effect of the magnetic field leads to a variation in this picture—the atmosphere becomes quasi-closed, with a characteristic size of order 14 planetary radii, which, in turn, substantially decreases the mass-loss rate by the exoplanet atmosphere (by~70%). This reduction of the mass-loss rate due to the influence of the magnetic fieldmakes it possible for exoplanets to form closed and quasi-closed envelopes in the presence of more strongly overflowing Roche lobes than is possible without a magnetic field.     

High‐ to ultrahigh‐temperature metamorphism in the lower crust: An example resulting from Hikurangi Plateau collision and slab rollback in New Zealand

Lower crustal xenoliths erupted from an intraplate diatreme reveal that a portion of the New Zealand Gondwana margin experienced high‐temperature (HT) to ultrahigh‐temperature (UHT) granulite facies metamorphism just after flat slab subduction ceased at c. 110–105 Ma. P–T calculations for garnet–orthopyroxene‐bearing felsic granulite xenoliths indicate equilibration at ~815 to 910°C and 0.7 to 0.8 GPa, with garnet‐bearing mafic granulite xenoliths yielding at least 900°C. Supporting evidence for the attainment of HT and UHT conditions in felsic granulite comes from re‐integration of exsolution in feldspar (~900–950°C at 0.8 GPa), Ti‐in‐zircon thermometry on Y‐depleted overgrowths on detrital zircon grains (932°C ± 24°C at aTiO₂ = 0.8 ± 0.2), and correlation of observed assemblages and mineral compositions with thermodynamic modelling results (≥850°C at 0.7 to 0.8 GPa). The thin zircon overgrowths, which were mainly targeted by drilling through the cores of grains, yield a U–Pb pooled age of 91.7 ± 2.0 Ma. The cause of Late Cretaceous HT‐UHT metamorphism on the Zealandia Gondwana margin is attributed to collision and partial subduction of the buoyant oceanic Hikurangi Plateau in the Early Cretaceous. The halt of subduction caused the fore‐running shallowly dipping slab to rollback towards the trench position and permitted the upper mantle to rapidly increase the geothermal gradient through the base of the extending (former) accretionary prism. This sequence of events provides a mechanism for achieving regional HT–UHT conditions in the lower crust with little or no sign of this event at the surface.     

Formation of intracratonic basins by lithospheric shortening and phase changes: a case study from the ultra‐deep East Barents Sea basin

The origin of large subsidence in intracratonic basins is still under debate. We propose a new and self‐consistent model for the formation of those basins, where lithospheric shortening/buckling triggers metamorphism and densification of crustal mafic heterogeneities. We use a forward thermo‐mechanical finite element technique to evaluate this mechanism for the typical example of the East Barents Sea basin (EBB) where a very large and compensated subsidence, accommodating an up to 20‐km‐thick sediment succession, is observed. The lower crust in the dynamic model is modelled with petrologic‐consistent densities for a wet mafic gabbroic composition that depend on pressure and temperature taking into account dehydration at high PT conditions. The model successfully explains the main characteristics of the EBB, notably the large anomalous and fast subsidence during the Late Permian–Early Triassic, its present‐day geometry and the absence of a significant gravity anomaly.