Retrograde garnet zoning at low water pressure in metapelitic rocks from Kemiö, SW Finland

The compositional zoning of almandine-spessartine garnet has been studied in pelitic gneisses from the Kemiö region, SW Finland. Garnets with inverse zoning (outward increase in Mn) abound in the low-grade musc+qz zone. Garnets with inverse zoning, normal zoning (outward decrease in Mn), and with a homogeneous composition occur in the higher-grade sill+ Kfs zone. The formation of garnet with inverse zoning is explained by continuous retrograde reactions in the model system K₂O-Al₂O₃-FeO-MnO-MgO-SiO₂-H₂O at strongly reduced partial water pressures.A comparison of temperatures based on critical metamorphic reactions and on garnet-biotite thermometry shows the usefulness of geothermometry in rocks with spessartine-rich garnet and Mn-bearing biotite.     

Sustainable Utilisation of Fisheries as Governmentality: Constraining the Potential for Ecosystems‐Based Management?

This paper examines the constitution of ‘sustainable management’ within the context of the New Zealand marine environment. Firstly this paper examines the difference between ‘sustainable ecosystems’ and ‘sustainable utilisation’. The distinction is important if we are to make sense of the different ways in which various stakeholders (fishers, fisheries companies, scientists, fisheries managers and environmental groups) use ‘sustainability’ in the management of New Zealand's marine environment. We then examine how contestation results in sustainable management becoming a governmentality. We propose that such contestation transforms stakeholders into subjects whose everyday practices and relationships are influenced by seemingly incommensurable understandings of the lexicon that surrounds sustainable management. We conclude try considering how the potential revelation of new unknowns may be needed in order for disparate stakeholders to forge a unified approach to New Zealand's marine management.     

Collaborative Visioning or Urban Planning as Therapy? The Politics of Public‐Private Policy Making

One aspect of a recent restructuring of urban economies, societies, and spaces has been a change in urban planning practice. Planning is increasingly privatized and decentralized in U.S. cities. Private planning consultants are often hired by public‐private coalitions in order to shape the future of cities, while the planning processes they institute are frequently claimed to be consensus‐based, collaborative, and inclusionary, rather than elite‐centered and expert‐driven. This paper discusses the use of “visioning”—an increasingly popular technique that develops goals for the future of a city through consensus‐based meetings, open to all parties—as developed by New Century Lexington, a public‐private planning initiative in Lexington, Kentucky. It argues that: (1) new public‐private planning procedures, incorporating collaborative techniques, frequently become the institutional sites of political struggle over how future urban geographies are produced; (2) in order to understand the role of visioning in contemporary urban politics and in policy making outcomes, we must recognize the sociospatial context in which it is deployed; and (3) in the case of New Century, the way in which local elites controlled the mechanics of the visioning process made dissent difficult and, therefore, produced a vision of the future largely parallel to their standard economic development models.     

Comparing Two Implementations of a Micromixing Model. Part I: Wall Shear-Layer Flow

A Lagrangian stochastic (LS) micromixing model is used for estimating concentration fluctuations in plumes of a passive, non-reactive tracer dispersing from elevated and ground-level compact sources into a neutral wall shear-layer flow. SPMMM (for sequential particle micromixing model) implements the familiar IECM (interaction by exchange with the conditional mean) micromixing scheme. The parametrization of the scalar micromixing time scale is identical to that proposed in a previously reported LS–IECM model (Cassiani et al., Atmos Environ 39:1457–1469, 2005a). However, while SPMMM is mathematically equivalent to the previously reported model, it differs in its numerical implementation: SPMMM releases N independent particles sequentially, whereas the previously reported model releases N independent particles simultaneously. In both implementations, the trajectories of the N particles are governed by single-point velocity statistics. The sequential particle implementation is computationally efficient, but cannot be applied to the case of reacting species. Results from both implementations are compared to experimental wind-tunnel dispersion data and to each other.     

Chemical analyses of ten stony meteorites

A group of stony meteorites, mainly unequilibrated chondrites ( and , 1965), has been analysed chemically. The chemical analyses of ten meteorites are given in this paper. Detailed studies of the petrology and mineralogy of these meteorites are in progress.     

On facies belts and facies mosaics: Holocene isolated platforms,South China Sea

Although the general criteria for recognition and environmental interpretation of different carbonate facies are well‐established, a predictive understanding of the areal extent and spatial patterning of facies bodies and why they might organize into facies belts or facies mosaics is poorly constrained. To explore patterns and process dynamics of facies on isolated carbonate platforms, quantitative analysis of thematic maps derived from remote sensing images of 27 Holocene atolls of the Paracel and Spratly chains in the South China Sea explores variability within and among platforms. On these systems, most annular shelf‐margin reefs are less than 500 m wide on both chains; inboard of the reefs, reef sand aprons range up to 500 m (Spratlys) and 1000 m (Paracels) wide. Around individual platforms, Spratly Chain sand apron widths are wider to the north‐west, whereas apron widths in the Paracel Chain are more symmetrical; collectively, data indicate log‐normal width‐exceedance probability distributions. Platform‐interior patch reefs include area‐exceedance probability distributions and gap size distributions (lacunarity) consistent within chains, but distinct between the chains. To understand the processes underlying distinct distributions, simulations explored distinct growth scenarios. Results suggest that differences may represent distinct process classes: proportional growth processes with multiplicative random effects (reef sand aprons – belts), versus non‐linear, size‐proportional growth of randomly aged and distributed elements (patch reefs – mosaics). The probabilistically distinct sizes and spatial patterns of geomorphic elements within these general process classes are interpreted to represent ‘variations on themes’ related to the different impacts of tropical storms, winter cold fronts and circulation in each chain. The results highlight fundamentally different growth patterns impacting the sizes and distribution of facies belts and mosaics on isolated carbonate platforms. Because these types of bodies ultimately construct stratigraphy, the themes could be applied to understand and predict variability in the architecture of subsurface reservoir analogues.     

Depositional environment and OSL chronology of the Homeb silt deposits, Kuiseb River, Namibia

Previous studies suggest that the Homeb silts of the Kuiseb valley, Namibia (i) accumulated in a dune-dammed lake, (ii) are end-point deposits, (iii) represent an aggrading river bed, and (iv) are slackwater deposits. Thus, they have been used alternatively as evidence of past drier conditions or past wetter conditions. Lithostratigraphic analysis of two sediment sequences at Homeb indicates sedimentation by aggradation of the Kuiseb River triggered by a transition from an arid to humid climate. OSL ages for the sequences were obtained by the SAR protocol on aliquots of 9.6-mm and 4.0-mm diameter and on single grains. Four-millimeter aliquot minimum ages closely approximate the single-grain minimum ages and are younger than 9.6-mm aliquot minimum and central ages. Based on these results, the small-aliquot (4-mm) approach appears to provide ages comparable to those obtained by the more laborious and time-consuming single-grain method. Minimum ages indicate rapid deposition of the Homeb Silts in at least two episodes centered at 15 ka and 6 ka during climate transitions from arid to humid. Flash floods eroded the valley fills during slightly more arid conditions.     

Magmatic evolution of Hekla,Iceland

The extrusive rocks of Hekla are predominantly flows of basaltic andesite and andesite (icelandite) but each eruptive cycle is initiated by production of tephra of andesitic, dacitic, and even rhyolitic composition. The evolution of basaltic andesites to dacites and rhyolites can be explained by crystallization and (presumably gravitative) separation of olivine, titaniferous magnetite, plagioclase, and probably augite. No contamination by sialic crustal material is required.Although basalts are never erupted from Hekla the origin of the basaltic andesites is probably best explained by separation of magnesian olivine, augite, and calcic plagioclase from an olivine tholeiite parent, producing an initial differentiation trend toward a high Fe/Mg ratio. The increase in Fe/Mg ratio is limited by the appearance of magnetite as a liquidus phase.From the Fe/Mg ratios of the lavas and from compositions of the plagioclase phenocrysts the water pressure of the basaltic andesites is estimated to have been between 0.6 and 2.4 kb. Total pressure may have been significantly higher. A best estimate for the water content is approximately 2 1/2 to 6 weight percent. This high water content accounts for the explosive initiation of each eruptive cycle and is consistent with fractional crystallization in a shallow magma chamber.Division of Geological and Planetary Sciences, California Institute of Technology, Contribution No. 2355.     

Dynamic processes occurring at the Craq-manganite (γ-MnOOH) interface: simultaneous adsorption, microprecipitation, oxidation/reduction, and dissolution

The complex interaction between Cr^III_aq and manganite (γ-MnOOH) was systematically studied at room temperature over a pH range of 3 to 6, and within a concentration range of 10⁻⁴ to 10⁻² M CrOH²⁺_aq. Solution compositional changes during batch reactions were characterized by inductively coupled plasma spectroscopy and ultraviolet-visible spectrophotometry. The manganites were characterized before and after reaction with X-ray photoelectron spectroscopy, scanning electron microscopy (SEM), high-resolution field-emission SEM, and energy-dispersive spectroscopy analysis. Fluid-cell atomic force microscopy was used to follow these metal-mineral interactions in situ. The reactions are characterized by (1) sorption of Cr^III and the surface-catalyzed microprecipitation of Cr^III-hydroxy hydrate on manganite surfaces, (2) the acidic dissolution of the manganite, and (3) the simultaneous reductive dissolution of manganite coupled with the oxidation of Cr^III_aq to highly toxic Cr^VI_aq. Cr^III-hydroxy hydrate was shown to precipitate on the manganite surface while still undersaturated in bulk solution. The rate of manganite dissolution increased with decreasing pH due both to acid-promoted and Mn-reduction-promoted dissolution. Cr oxidation also increased in the lower pH range, this as a result of its direct redox coupling with Mn reduction. Neither Mn^II nor Cr^VI were ever detected on manganite surfaces, even at the maximum rate of their generation. At the highest pHs of this study, Cr^III_aq was effectively removed from solution to form Cr^III-hydroxy hydrate on manganite surfaces and in the bulk solution, and manganite dissolution and Cr^VI_aq generation were minimized. All interface reactions described above were heterogeneous across the manganite surfaces. This heterogeneity is a direct result of the heterogeneous semiconducting nature of natural manganite crystals and is also an expression of the proximity effect, whereby redox processes on semiconducting surfaces are not limited to next nearest neighbor sites.