Three-Dimensional p–q Resonant Orbits Close to Second Species Solutions

The purpose of this paper is to study, for small values of , the three-dimensional p–q resonant orbits that are close to periodic second species solutions (SSS) of the restricted three-body problem. The work is based on an analytic study of the in- and out-maps. These maps are associated to follow, under the flow of the problem, initial conditions on a sphere of radius around the small primary, and consider the images of those initial points on the same sphere. The out-map is associated to follow the flow forward in time and the in-map backwards. For both mappings we give analytical expressions in powers of the mass parameter. Once these expressions are obtained, we proceed to the study of the matching equations between both, obtaining initial conditions of orbits that will be 'periodic' with an error of the order ^1–, for some (1/3,1/2). Since, as 0, the inner solution and the outer solution will collide with the small primary, these orbits will be close to SSS.     

Spatial collinear restricted four-body problem with repulsive Manev potential

We outline some aspects of the dynamics of an infinitesimal mass under the Newtonian attraction of three point masses in a symmetric collinear relative equilibria configuration when a repulsive Manev potential (\(-1/r +e/r^{2}\)), \(e>0\), is applied to the central mass. We investigate the relative equilibria of the infinitesimal mass and their linear stability as a function of the mass parameter \(\beta \), the ratio of mass of the central body to the mass of one of two remaining bodies, and e. We also prove the nonexistence of binary collisions between the central body and the infinitesimal mass.     

Vegetation re-establishment in polar "lichen-kill" landscapes: a case study of the Little Ice Age impact

It has been accepted that the extremely sparse vegetation currently observed in Canadian polar deserts is due to prevailing unfavourable climatic conditions, inhibiting plant establishment, growth and survival. Less considered in the literature is the additional antagonistic factor of episodic adverse climatic anomalies. Such was the most recent Little Ice Age (LIA) cooling which caused a setback to, or even largescale extinction of, high Arctic plant communities that had taken centuries to develop. The LIA brought about new glacial advances, expansion of permanent snow banks and formation of ice crusts over entire landscapes. The newly formed ice (and snow) killed the underlying vegetation, thus creating what is in the geological literature referred to as "lichen-kill zones." In these zones the current plant diversity and abundance are exceedingly low and the plants are all relatively young and even-aged, factors which all point to their recent origin. Here we maintain that this vegetation has not yet reached equilibrium with the present prevailing climate and that it is still in an initial stage of succession. We present results of eight upland sites sampled in the vicinity of Alexandra Fiord Lowland, Ellesmere Island, Canada, to demonstrate the slow recolonization process that has been occurring within the last 100–150 years after the LIA termination. The widespread presence of the "lichen-kill" zones throughout the Canadian polar regions reflects the extent and destructive nature of even minor climatic cooling on vulnerable polar ecosystems.     

Comparison Between Theoretical Predictions and LEGRI Background Noise Experimental Measurements

Trapped protons are responsible for the main component of LEGRIbackground. Detailed theoretical model has demonstrated that theproton-induced counting rate is two orders of magnitude larger thanthe counting rate of the diffuse gamma-ray flux. The continuous passesof LEGRI through the SAA (7 times everyday) makes very difficult thebackground modelling. Long and short lived isotopes contribute in verydifferent time scales to the proton-induced background component.The goal of this paper is to present a comparison between the long-livedbackground noise theoretical predictions and the experimental data. Theresults show an unexpected good agreement between the predicted and theobserved counting rates.     

Still a good neighbour? Implications of changing priorities in New Zealand Aotearoa's aid sector

The period following the election of the National government in 2008 has been controversial for Aotearoa New Zealand's aid programme for a number of reasons. This article examines changes in funding modalities and other aspects of non‐governmental organisation (NGO)–government relations as the sites of contested philosophies that surround aid and development discourse. In focusing on the introduction of the Sustainable Development Fund in 2010, the article argues that this shift has generated significant uncertainty among the aid community and may ultimately undermine many of the relationships NGOs previously enjoyed with partners in the Global South.     

Bioaccumulation and histopathological effects of oil on a stony coral

Colonies of the shallow-water Caribbean coral Manicina areolata incorporated petroleum hydrocarbons into their tissues during exposure to water accommodated fractions of No. 2 fuel oil for three months. This contamination was not removed after depuration periods of up to two weeks. Although these corals remained alive, evidence of pathological responses was found which included impaired development of reproductive tissues, degeneration and loss of symbiotic zooxanthellae, and atrophy of mucous secretory cells and muscle bundles.     

Dehydroxylation mechanisms in Al/Fe dioctahedral phyllosilicates by quantum mechanical methods with cluster models

Atomic models involving the dehydroxylation process of dioctahedral phyllosilicates without interlayer charge were used to calculate energies and explore the reaction paths of the possible mechanisms of this reaction at a quantum mechanical level. The geometrical features and electronic structure of a molecular cluster model of two edge-sharing octahedrally coordinated cations coupled to a ring of six silicate tetrahedra was evaluated by ab initio molecular orbital calculations with Hartree-Fock approximation. Two dehydroxylation mechanisms are considered. One mechanism involves two contiguous hydroxyl that are on an octahedron shared edge that joins a pair of octahedral cations. The other model considered involves OH loss from across an octahedral vacant. The substitution effect of Al³⁺ by Fe³⁺ in the octahedral sheet on the activation energy and structural transformations is compared by minimization of the critical points of the Potential Energy Surface (PES) for the reactant, transition state and product along the reaction path of the dehydroxylation process. The calculated energy differences and vibration frequencies are according to previous experimental results. The dehydroxylation mechanism involving OH across the octahedral hole, is less energetically favorable and is endothermic.     

Hydrothermal processes in partially serpentinized peridotites from Costa Rica: evidence from native copper and complex sulfide assemblages

Native metals and metal alloys are common in serpentinized ultramafic rocks, generally representing the redox and sulfur conditions during serpentinization. Variably serpentinized peridotites from the Santa Elena Ophiolite in Costa Rica contain an unusual assemblage of Cu-bearing sulfides and native copper. The opaque mineral assemblage consists of pentlandite, magnetite, awaruite, pyrrhotite, heazlewoodite, violarite, smythite and copper-bearing sulfides (Cu-pentlandite, sugakiite [Cu(Fe,Ni)₈S₈], samaniite [Cu₂(Fe,Ni)₇S₈], chalcopyrite, chalcocite, bornite and cubanite), native copper and copper–iron–nickel alloys. Using detailed mineralogical examination, electron microprobe analyses, bulk rock major and trace element geochemistry, and thermodynamic calculations, we discuss two models to explain the formation of the Cu-bearing mineral assemblages: (1) they formed through desulfurization of primary sulfides due to highly reducing and sulfur-depleted conditions during serpentinization or (2) they formed through interaction with a Cu-bearing, higher temperature fluid (350–400 °C) postdating serpentinization, similar to processes in active high-temperature peridotite-hosted hydrothermal systems such as Rainbow and Logatchev. As mass balance calculations cannot entirely explain the extent of the native copper by desulfurization of primary sulfides, we propose that the native copper and Cu sulfides formed by local addition of a hydrothermal fluid that likely interacted with adjacent mafic sequences. We suggest that the peridotites today exposed on Santa Elena preserve the lower section of an ancient hydrothermal system, where conditions were highly reducing and water–rock ratios very low. Thus, the preserved mineral textures and assemblages give a unique insight into hydrothermal processes occurring at depth in peridotite-hosted hydrothermal systems.     

Assessment of ERA5 and ERA-Interim in Reproducing Mean and Extreme Climates over West Africa

In situ data in West Africa are scarce, and reanalysis datasets could be an alternative source to alleviate the problem of data availability. Nevertheless, because of uncertainties in numerical prediction models and assimilation methods, among other things, existing reanalysis datasets can perform with various degrees of quality and accuracy. Therefore, a proper assessment of their shortcomings and strengths should be performed prior to their usage. In this study, we examine the performance of E...