In situ bioremediation of 1,2-dichloroethane under anaerobic conditions

Historic spillages of chlorinated hydrocarbons at a vinyl chloride plant in the Rotterdam–Botlek area in The Netherlands has lead to deep-seated pollution of the underlying aquifer. The principal pollutant is 1,2-dichloroethane (1,2-DCA). As a temporary measure, the contamination is being contained using a pump and treat system. In the long term, in-situ bioremediation has been proposed using a biologically active zone where pollutants would be dechlorinated by microorganisms that simultaneously degrade other carbon sources. In order to investigate the suitability of this new technology, a programme of laboratory tests was carried out. The laboratory programme involved a series of anaerobic soil column tests, where the selection and delivery of different carbon substrates that stimulated 1,2-DCA dechlorination were investigated. The soil columns were prepared using soil and groundwater samples from boreholes. Groundwater was flushed through the columns under anaerobic conditions. A comparison was made between the transformation of 1,2-DCA without a carbon substrate and in the presence of sugars (molasses) and alcohol (methanol) respectively. In addition, different modes of delivery were investigated. In the case of molasses, the material was injected into the column as a plug to simulate grout injection in the field, whereas methanol was delivered as a constant flow dissolved in the influent. Both carbon substrates resulted in the biotransformation of 1,2-DCA. However, fermentation of molasses produced secondary effects that led to a drop in pH and an excessive production of carbon dioxide, which temporarily blocked the flow of groundwater.     

Adakitic lavas in the Central Luzon back‐arc region,Philippines: lower crust partial melting products?

Abstract Volcanism in the back-arc side region of Central Luzon, Philippines, with respect to the Manila Trench is characterized by fewer and smaller volume volcanic centers compared to the adjacent forearc side-main volcanic arc igneous rocks. The back-arc side volcanic rocks which include basalts, basaltic andesites, andesites and dacites also contain more hydrous minerals (ie, hornblende and biotite). Adakite-like geochemical characteristics of these back-arc lavas, including elevated Sr, depleted heavy rare earth elements and high Sr/Y ratios, are unlikely to have formed by slab melting, be related to incipient subduction, slab window magmatism or plagioclase accumulation. Field and geochemical evidence show that these adakitic lavas were most probably formed by the partial melting of a garnet-bearing amphibolitic lower crust. Adakitic lavas are not necessarily arc–trench gap region slab melts.     

Complex origin for the south-western Zamboanga metamorphic basement complex, Western Mindanao, Philippines

Abstract Amphibolites unconformably overlain by a metasedimentary sequence of quartz-muscovite-feldspar-kyanite schists, metagraywackes and epidote-bearing amphibolites occur in the northern portion of the south-western Zamboanga metamorphic basement complex, western Mindanao. These amphibolites (here identified as the Mount Dansalan amphibolites) display relict magmatic textures inherited from cumulate gabbro protoliths. Bulk-rock major and trace-element data are consistent with this hypothesis. Together with the chemistry of relict igneous clinopyroxenes, they indicate a magmatic arc-related signature for the gabbro protoliths. Geochemical data allow us to identify various sources for the associated metasediments: the gabbro themselves for the metagraywackes and a continental basement for the quartz-muscovite-feldspar-kyanite schists. Both sources contributed to the genesis of the epidote-amphibolite metasediments. The compositions of the metamorphic mineral assemblages suggest that the rocks have undergone metamorphism at temperatures ranging from 550°C to 700°C and pressures probably in the range of 5–9 kbar. ⁴⁰K–⁴⁰Ar isotopic study of amphibole separates from the Mount Dansalan samples document a metamorphic event dated at 24.6 ± 1.4, 22.2 ± 1.4 and 21.2 ± 1.2 Ma. Our results are in agreement with plate tectonic models which describe the south-western Zamboanga metamorphic basement as a continental terrane. However, its evolution was not as simple as it was usually considered. In particular the basement incorporated slivers of magmatic arc crust, which cannot be unambiguously related to any of the Tertiary arcs documented in the area.     

Infiltration Measured by the Drip of Stalactites

The hydrodynamic processes and mechanisms involved in rain infiltration and recharge in local areas of karst terrain can be identified and quantified by using measurements of the seepage of cave stalactites. Detailed measurements of the seepage of stalactites in seven caves located in an area close to the land surface, or the subcutaneous area of the karst, show a diversity of complex factors involved in infiltration: type of precipitation (rain or snow), air temperature, soil type and thickness, etc., which give rise to larger or smaller variations of flow in the espeleothem hydrographs. In some cases, no explanation can be found for the response of stalactites to rainfall, while in others there is a relationship between outer atmospheric parameters and the recharge represented by the stalactite drip. Romperopas Cave (Spain) has both a rapid and a basic flow, with hydrograph recessions similar to those observed in other caves. Water seepage in this cave varies greatly both in space and in time. The infiltration in Altamira Cave (Spain) was calculated and a multiple regression was found between infiltration, rain and outside air temperature. In other cases, the balance of the water on the soil is responsible for the seepage. Thus, a precipitation runoff numerical model that simulated the stalactite hydrographs could be applied to the Baradla and Beké Caves (Hungary). The complex properties of the ground, which are required for other flow numerical models for the unsaturated zone, were not taken into consideration.     

Quiet-time periods observed by EPHIN/SOHO during the minimum of the 22nd solar cycle

An analysis of the hydrogen and helium isotopic composition from EPHIN data, during the quiet-time period from January 1 to June 1, 1996, is presented. An isotopic discrimination and background rejection have been applied and relationships between the abundances of ²H/¹H, ³He/⁴He, and ⁴He/¹H have been calculated. The energy spectra in the 4–50 MeV nucl^–1 range have been obtained and the contribution of the different spectral components have been analysed in this energy range. We conclude that the main contribution to the ⁴He spectrum is of anomalous origin, while the proton and ³He spectra have contributions mainly from particles of solar origin at low energies and from the galactic cosmic radiation modulated by the heliosphere at high energies. The deuterium spectrum is mainly of galactic origin.     

贝叶斯统计方法在海浪方向谱研究中的应用

较详细介绍了贝叶斯统计方法在海浪方向谱估计中的应用,指出先验分布的不同对估计结果没有影响,由于均匀分布与最大熵原则相对应,使其具有某种特殊性.数值模拟表明贝叶斯方法对双峰方向分布估计的有效性,将其应用于黑海实测资料,证明双峰方向分布的出现依赖于估计方法分辨力的大小,而用最大似然法得到的双峰方向分布值得怀疑.最后给出出现双峰方向分布的一种可能物理解释.     

Tectonics of an extinct ridge-transform intersection,Drake Passage (Antarctica)

New swath bathymetric, multichannel seismic and magnetic data reveal the complexity of the intersection between the extinct West Scotia Ridge (WSR) and the Shackleton Fracture Zone (SFZ), a first-order NW-SE trending high-relief ridge cutting across the Drake Passage. The SFZ is composed of shallow, ridge segments and depressions, largely parallel to the fracture zone with an `en echelon' pattern in plan view. These features are bounded by tectonic lineaments, interpreted as faults. The axial valley of the spreading center intersects the fracture zone in a complex area of deformation, where N120° E lineaments and E–W faults anastomose on both sides of the intersection. The fracture zone developed within an extensional regime, which facilitated the formation of oceanic transverse ridges parallel to the fracture zone and depressions attributed to pull-apart basins, bounded by normal and strike-slip faults.On the multichannel seismic (MCS) profiles, the igneous crust is well stratified, with numerous discontinuous high-amplitude reflectors and many irregular diffractions at the top, and a thicker layer below. The latter has sparse and weak reflectors, although it locally contains strong, dipping reflections. A bright, slightly undulating reflector observed below the spreading center axial valley at about 0.75 s (twt) depth in the igneous crust is interpreted as an indication of the relict axial magma chamber. Deep, high-amplitude subhorizontal and slightly dipping reflections are observed between 1.8 and 3.2 s (twt) below sea floor, but are preferentially located at about 2.8–3.0 s (twt) depth. Where these reflections are more continuous they may represent the Mohorovicic seismic discontinuity. More locally, short (2–3 km long), very high-amplitude reflections observed at 3.6 and 4.3 s (twt) depth below sea floor are attributed to an interlayered upper mantle transition zone. The MCS profiles also show a pattern of regularly spaced, steep-inclined reflectors, which cut across layers 2 and 3 of the oceanic crust. These reflectors are attributed to deformation under a transpressional regime that developed along the SFZ, shortly after spreading ceased at the WSR. Magnetic anomalies 5 to 5 E may be confidently identified on the flanks of the WSR. Our spreading model assumes slow rates (ca. 10–20 mm/yr), with slight asymmetries favoring the southeastern flank between 5C and 5, and the northwestern flank between 5 and extinction. The spreading rate asymmetry means that accretion was slower during formation of the steeper, shallower, southeastern flank than of the northwestern flank.     

The role of constraints on joint hypocentre determination in seismotectonic studies

In this paper we show how the performance of the joint hypocentre determination (JHD) method can be improved, leading to reduced instability in cases close to singularity. The method has been extended by imposing a number of constraints introduced by other authors, and adding a new one. We tested the stability of the method and the relative advantages of the various constraints by simulating a geometrical space distribution of hypocentres recorded by a regional seismic network. We then applied this method to deep earthquakes that occurred in the Southern Tyrrhenian Sea subduction zone and to the seismicity of the Northern Apennines, which is moderately deeper than the typical shallow seismicity of the Apennines. The results obtained from the analysis of synthetic data and actual earthquakes confirm that the JHD method produces less scatter in the hypocentral determinations with respect to the standard locations. The main conclusion of our study is that we can significantly reduce the systematic mislocations that result from applying JHD to very clustered seismicity if we introduce the appropriate set of constraints.     

基于实测与模拟的青海湖冰厚时空变化特征

湖冰厚度是湖泊在封冻期的重要物理参数,明晰其时空变化特征对于认识气候变暖背景下的湖冰响应规律具有重要的理论价值和现实意义.基于ERA5 Climate Reanalysis气温数据集、MODIS MOD09GQ数据产品和2019年湖冰钻孔测厚数据及雷达测厚数据,重建20002019年青海湖冰厚时间序列并分析其时空变化特...     

近邻景区的联动与溢出效应研究——以黄山、西递、宏村为例

空间邻近性是地理学第一定律,近邻旅游地相互作用定量化研究对丰富旅游地理学理论与实践意义重大.以近邻旅游地黄山、西递和宏村作为案例地,在格兰杰因果分析的基础上,运用当前经济研究中使用极为广泛的DY溢出指数(Diebold&Yilmaz spillover index)分析近邻旅游地的溢出效应.结果表明:宏村和黄山、西递和...