The metamorphic evolution of migmatites from the Ötztal Complex (Tyrol,Austria) and constraints on the timing of the pre-Variscan high-T event in the Eastern Alps

Within the Ötztal Complex (ÖC), migmatites are the only geological evidence of the pre-Variscan metamorphic evolution, which led to the occurrence of partial anatexis in different areas of the complex. We investigated migmatites from three localities in the ÖC, the Winnebach migmatite in the central part and the Verpeil- and Nauderer Gaisloch migmatite in the western part. We determined metamorphic stages using textural relations and electron microprobe analyses. Furthermore, chemical microprobe ages of monazites were obtained in order to associate the inferred stages of mineral growth to metamorphic events. All three migmatites show evidence for a polymetamorphic evolution (pre-Variscan, Variscan) and only the Winnebach migmatite shows evidence for a P-accentuated Eo-Alpine metamorphic overprint in the central ÖC. The P-T data range from 670–750 °C and < 2.8 kbar for the pre-Variscan event, 550–650 °C and 4–7 kbar for the Variscan event and 430–490 °C and ca. 8.5 kbar for the P-accentuated Eo-Alpine metamorphic overprint. U-Th-Pb electron microprobe dating of monazites from the leucosomes from all three migmatites provides an average age of 441 ± 18 Ma, thus indicating a pervasive Ordovician-Silurian metamorphic event in the ÖC.     

Heat and momentum transport in an oak forest canopy

With the use of a sonic anemometer, vertical heat and momentum fluxes were measured at three different levels in an oak forest canopy. A quadrant analysis of the resulting data shows that approximately half of the transport occurs in extreme events lasting about 5 to 10% of the time. The partition of transport into momentum sweeps, bursts and interactions shows good agreement with existing data. The heat flux is analysed by observing the fluxes during the different momentum events and considering concurrent momentum and heat flux intensities by means of conditional probabilities. While low intensity (normal) events show similar probability distributions throughout the canopy, different structures appear at the three measurement heights for high intensity (extreme) events that can tentatively be explained by taking the temperature profile into account. This supports the idea that these events are coherent motions with scales comparable to the canopy height.     

Die Mikroseismik und ihre Anwendung zum Abschätzen der Dicke der Kontinentalschollen

Zusammenfassung An Hand einiger Wetterlagen mit besonders starker Mikroseismik wird der Verlauf von Amplituden und Perioden in Stuttgart verfolgt. Das Gesetz der Abhängigkeit zwischen Periode und Amplitude wird empirisch ermittelt, das Periodenspektrum gezeichnet. Die am häufigsten auftretende Periode wird zur Berechnung der Dicke der schwingenden Schicht benutzt unter der Annahme, dass diese Schicht mit ihrer Unterlage lose verbunden ist und die Art der Schwingungen sich nicht wesentlich von Rayleighwellen unterscheidet. Es ergibt sich so der theore tische Zusammenhang zwischen Periode und Amplitude einerseits und der Schichtdicke andrerseits. Sie beträgt für Norwegen etwas über 40 km.

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Summary With the help of several weather-situations with particularty violent microseism the progress of amplitudes and periods as perceived at Stuttgart is examinated. The law of dependency between period and amplitude is found empirically, the spectrum of periods is drawn up. The period, which occurs most frequently is used for calculating the thickness of the swinging layer as this layer is supposed to be in loose connection with its support and as the sort of oscillations is not essentially different from Rayleight waves. Thus there is found the theoretical connection between periods and amplitudes and, on the other side, the thickness of layer of something more than 40 km for Norway.

     

Bemerkungen zur Zwillingsbildung bei Plagioklasen

Ohne Zusammenfassung     

A zircon study from the Rhodope metamorphic complex, N-Greece: Time record of a multistage evolution

Zircons from an eclogite and a diamond-bearing metapelite near the Kimi village (north-eastern Rhodope Metamorphic Complex, Greece) have been investigated by Micro Raman Spectroscopy, SEM, SHRIMP and LA-ICPMS to define their inclusion mineralogy, ages and trace element contents. In addition, the host rocks metamorphic evolution was reconstructed and linked to the zircon growth domains.

The eclogite contains relicts of a high pressure stage (ca. 700 °C and > 17.5 kbar) characterised by matrix omphacite with Jd_40–35. This assemblage was overprinted by a lower pressure, higher temperature metamorphic event (ca. 820 °C and 15.5–17.5 kbar), as indicated by the presence of clinopyroxene (Jd_35–20) and plagioclase. Biotite and pargasitic amphibole represent a later stage, probably related to an influx of fluids. Zircons separated from the eclogite contain magmatic relicts indicating Permian crystallization of a quartz-bearing gabbroic protolith. Inclusions diagnostic of the high temperature, post-eclogitic overprint are found in metamorphic zircon domain Z2 which ages spread over a long period (160 – 95 Ma). Based on zircon textures, zoning and chemistry, we suggest that the high-temperature peak occurred at or before ca. 160 Ma and the zircons were disturbed by a later event possibly at around 115 Ma. Small metamorphic zircon overgrowths with a different composition yield an age of 79 ± 3 Ma, which is related to a distinct amphibolite-facies metamorphic event.

The metapelitic host rock consists of a mesosome with garnet, mica and kyanite, and a quartz- and plagioclase-bearing leucosome, which formed at granulite-facies conditions. Based on previously reported micro-diamond inclusions in garnet, the mesosome is assumed to have experienced UHP conditions. Nevertheless, (U)HP mineral inclusions were not found in the zircons separated from the diamond-bearing metapelite. Inclusions of melt, kyanite and high-Ti biotite in a first metamorphic zircon domain suggest that zircon formation occurred during pervasive granulite-facies metamorphism. An age of 171 ± 1 Ma measured on this zircon domain constrains the high-temperature metamorphic event. A second, inclusion-free metamorphic domain yielded an age of 160 ± 1 Ma that is related to decompression and melt crystallization.

The similar age data obtained from the samples indicate that both rock types recorded a high-T metamorphic overprint at granulite-facies conditions at ca. 170 – 160 Ma. This age implies that any high pressure or even ultra-high pressure metamorphism in the Kimi Complex occurred before that time. Our findings define new constraints for the geodynamic evolution for the Alpine orogenic cycle within the northernmost Greek part of the Rhodope Metamorphic Complex. It is proposed that the rocks of the Kimi Complex belong to a suture zone squeezed between two continental blocks and result from a Paleo-ocean basin, which should be located further north of the Jurassic Vardar Ocean.     

Interaction of organic compounds with calcium carbonate-II. Organo-carbonate association in Recent sediments

Surface area measurements as well as organic carbon, nitrogen and phosphorus analyses on various grain size fractions of carbonate mud samples confirm that in natural environments of carbonate deposition, surface sorption processes take place which are similar to those described earlier for dissolved organics and artificially suspended calcite particles in both seawater and synthetic solutions.The specific surface area of the sediment increases from 1.8m²/g for the coarse-grained fraction to 12.5 m²/g for the fine material; likewise organic carbon, nitrogen and phosphorus increase with increasing surface area so that there are 1.20 mg C, 0.175 mg N and 0.06–0.20 mg P associated with every square meter of carbonate surface irrespective of the mineralogy of the sediment particles.It appears that the organic matter in these sediments is similar in composition, structure and quantity to the organic layers produced in sorption experiments. With their apparently defined structure and ubiquitous nature, these layers could determine the mineralogy and orientation of submarine carbonate cement or could even be a prerequisite to calcification in general.     

Ionization of the earth’s atmosphere by solar and galactic cosmic rays

A brief review of the research of atmospheric effects of cosmic rays is presented. Numerical models are discussed, that are capable to compute the cosmic ray induced ionization at a given location and time. Intercomparison of the models, as well as comparison with fragmentary direct measurements of the atmospheric ionization, validates their applicability for the entire atmosphere and the whole range of the solar activity level variations. The effect of sporadic solar energetic particle events is shown to be limited on the global scale, even for the most severe event, but can be very strong locally in polar regions, affecting the physical-chemical properties of the upper atmosphere, especially at high altitudes. Thus, a new methodology is presented to study cosmic ray induced ionization of the atmosphere in full detail using realistic numerical models calibrated to direct observations.     

Magnetic signature of hydrocarbon-contaminated soils and sediments at the former oil field H?nigsen, Germany

Magnetic properties of hydrocarbon (HC) containing soils and sediments from two sites (Site A and B) of the former oil-field H?nigsen were analyzed in order to determine whether magnetic methods can be employed to delineate HC contamination of soils and sediments. Magnetic parameters such as magnetic susceptibility and induced isothermal remanent magnetizations, as well as soil and sediment properties such as pH, iron content and water content, HC content and most probable number counts of iron-metabolizing microorganisms were determined. The magnetic concentration-dependent parameters for HC contaminated samples were 25 times higher in soils from Site A than in sediment samples from Site B. However, at Site B the magnetic susceptibility was still four times higher in comparison to lithologically similar non-contaminated sediment samples from a third Site C. Newly formed magnetite containing mainly single domain particles was responsible for the magnetic enhancement, whereas superparamagnetic grains represented only a minor component. Site A had an acidic pH compared to neutral pH at Site B, and a higher crystalline and bioavailable total iron content. Nevertheless, Site B samples contained significant numbers of both iron(II)-oxidizing and iron(III)-reducing microorganisms indicating that microbial iron cycling might have taken place at this site and potentially played a role for iron mineral transformation, including magnetite (trans)formation. The content of total non-polar hydrocarbons (TNPH) at Site A was one order of magnitude higher than at Site B. Only at Site A magnetic susceptibility correlated well with TNPH. Our results demonstrate that HC contaminated samples had an enhanced magnetite content compared to non-contaminated soils and sediments. Therefore, magnetic methods may provide a quick and cost-effective way to assess HC contamination in soils and sediments. However, more field sites and laboratory investigations are needed to reveal the complex nature of the processes involved.