Use of normalized metal concentrations in the Mn oxides/hydrous oxides extraction phase of stream sediments to enhance the difference between a landfill emission plume and background

Normalized concentrations of Fe, Zn, Ba and Co bound to the Mn phase were determined using a ratio of metal concentration to Mn concentration. Metal concentrations were taken from a previous study which found elevated concentrations of heavy metals in the stream sediments in the vicinity of 2 landfills using a HN0₃ extraction of the whole sediment sample and geochemical phases. Results from the normalized metal concentrations for Zn, Fe and Ba showed a clearer distinction between background and emission plume regions along the stream compared to the same for the HN0₃ and Mn phase extractions. Lack of elevated concentrations and normalized concentrations for Co indicated the concentrations represented the background. The small distance used in the study could explain the lack of a decreasing trend of metal concentrations and normalized metal concentrations downstream in the emission plume of the sediments. Although Mn⁺² 2concentrations are known to be incorporated into the natural state of the Mn phase, these concentrations were thought to be small enough not to influence the results from the normalized concentrations. Non-selectivity of extractants and metal redistribution among chemical phases during extraction procedures are thought to be small and did not invalidate the results.     

Acoustic wave propagation in saturated porous media: reformulation of the Biot/Squirt flow theory

A model of wave propagation in fluid-saturated porous media is developed where the principal fluid/solid interaction mode affecting the propagation of the acoustic wave results from the conjunction of the Biot and the Squirt flow mechanism. The difference between the original Biot/Squirt (BISQ) flow theory and the new theory, which we call the reformulated BISQ, is that the average fluid pressure term appearing in the dynamic equation for a two component solid/fluid continuum is independent of squirt flow length. P-velocity and attenuation relate to measurable rock physical parameters: the Biot's poroelastic constants, porosity, permeability, pore fluid compressibility and viscosity. Modelling shows that velocity and attenuation dispersion obtained using the reformulated BISQ theory are of the same order of magnitude as those obtained using the original BISQ theory. Investigation on permeability effect on velocity and attenuation dispersion indicate that the transition zone in velocity and attenuation peak, occurring both at the relaxation frequency, shifts toward high frequency when permeability decreases. This behaviour agrees with Biot's theory prediction.     

An experiment to gauge an ungauged catchment: rapid data assessment and eco-hydrological modelling in a data-scarce rural catchment

Abstract

We conducted a PUB (predictions in ungauged basins) experiment looking at hydrology and crop dynamics in the semi-arid rural Mod catchment in India. The experiment was motivated by the aims (a) to develop a coupled eco-hydrological model capable of analysing land-use strategies concerning crop water need, erosion protection, crop yield and resistivity against droughts and floods, and (b) to assess the feasibility of a strategy for collecting the necessary data in a data-scarce region. Our experiment combines parsimonious data assessment and eco-hydrological model coupling at the lower mesoscale. Linking bottom-up sampling of functionally representative soil classes and top-down regionalization based on spectral properties of the same resulted in a comprehensive distributed data basis for the model. A clear focus on the dominating processes and the catena as the organizing landscape element in the given environmental setting enabled this. We employed the WASA (Water Availability in Semi-Arid environments) model for uncalibrated process-based water balance modelling and integrated a crop simulation subroutine based on the SWAP (Soil Water Atmosphere Plant) model to account for crop dynamics, feedbacks and yield estimation. While we found the data assessment strategy and the hydrological model application largely feasible, in terms of its accounting for scale, processes and model concepts, the simulation of feedbacks with crops was problematic. Contributing to the PUB issue, more general conclusions are drawn concerning spatially-distributed structural information and uncalibrated modelling.

Editor Z.W. Kundzewicz; Associate editor F. Hattermann     

Downstream effects of impounding a natural lake: the Snake River downstream from Jackson Lake Dam,Wyoming, USA

A sediment mass balance constructed for a 16‐km reach of the Snake River downstream from Jackson Lake Dam (JLD) indicates that river regulation has reduced the magnitude of sediment mass balance deficit that would naturally exist in the absence of the dam. The sediment budget was constructed from calibrated bed load transport relations, which were used to model sediment flux into and through the study reach. Calibration of the transport relations was based on bed load transport data collected over a wide range of flows on the Snake River and its two major tributaries within the study area in 2006 and 2007. Comparison of actual flows with unregulated flows for the period since 1957 shows that operations of JLD have reduced annual peak flows and increased late summer flows. Painted tracer stones placed at five locations during the 2005 spring flood demonstrate that despite the reduction in flood magnitudes, common floods are capable of mobilizing the bed material. The sediment mass balance demonstrates that more sediment exits the study reach than is being supplied by tributaries. However, the volume of sediment exported using estimated unregulated hydrology indicates that the magnitude of the deficit would be greater in the absence of JLD. Calculations suggest that the Snake River was not in equilibrium before construction of JLD, but was naturally in sediment deficit. The conclusion that impoundment lessened a natural sediment deficit condition rather than causing sediment surplus could not have been predicted in the absence of sediment transport data, and highlights the value of transport data and calculation of sediment mass balance in informing dam operations. Copyright © 2011 John Wiley & Sons, Ltd.     

Marine cold seeps and their manifestations: geological control,biogeochemical criteria and environmental conditions

Characteristics of cold seeps at different geologic settings are the subject of this review primarily based on results of the Research Consortium SFB 574. Criteria are drawn from examples on the erosive convergent margin off Costa Rica, the accretionary margin off Chile supplemented by examples from the transform margin of the Golf of Cadiz and the convergent Hikurangi margin off New Zealand. Others are from well-studied passive margins of the Black Sea, the Golf of Mexico, the eastern Mediterranean Sea and the South China Sea. Seeps at all settings transport water and dissolved compounds to the ocean through the seafloor by different forcing mechanism and from different depths of the submerged geosphere (10s of meters to 10s of km). The compounds sustain oasis-type ecosystems by providing bioactive reductants sulfide, methane and hydrogen. Hereby, the interaction between fluid composition, flux rates and biota results in a diagnostic hydrocarbon–metazoan–microbe–carbonate association; currently, well over 100 active sites are known. The single most important reaction is microbially mediated anaerobic oxidation of methane with secondary reactions involving S-biogeochemistry and carbonate mineral precipitation. Seep fluids and their seafloor manifestations provide clues as to source depth, fluid–sediment/rock interaction during ascent, lifetime and cyclicity of seepage events but less so on the magnitude of return flow. At erosive margins, Cl-depleted and B-enriched fluids from clay dehydration provide criteria for source depth and temperature. The upward material flow generates mud volcanoes at the seafloor above the projected location of dehydration at depth. At accretionary margins, fluids are derived from more shallow depths by compaction of sediments as they ride on the incoming oceanic plate; they are emitted through thrust faults. At highly sedimented margins, organic-rich and evaporite-containing strata (when present) determine the final fluid composition, by emitting characteristically gas hydrate-derived methane, brine-associated non-methane hydrocarbons or leached elements and their isotopes (Li, δ⁷Li, B, Ba) from host sediments. Smectite–illite transformation and associated Cl-depletion from release of interlayer water is a pervasive process at these margins. Rare earth element pattern in conjunction with redox-sensitive metals retained in seep carbonates indicate whether or not they precipitated in contact with oxic bottom water or suboxic fluids; clear environmental characterization, though, currently remains inconclusive. More deeply sourced fluids as in transform margins may be characterized by their ⁸⁷Sr/⁸⁶Sr ratios from interaction with oceanic crustal rocks below. Quantification of flow and reliable estimates of total volatile output from fore-arcs remain a challenge to seep research, as does understanding the role of geologically derived methane in the global methane cycle.     

Past methane release events and environmental conditions at the upper continental slope of the South China Sea: constraints by seep carbonates

Authigenic carbonates and seep biota are archives of seepage history and record paleo-environmental conditions at seep sites. We obtained the timing of past methane release events at the northeastern slope of the South China Sea based on U/Th dating of seep carbonates and seep bivalve fragments from three sites located at 22°02′–22°09′N, 118°43′–118°52′E (water depths from 473 to 785 m). Also, we were able to reconstruct the paleo-bottom water temperatures by calculating the equilibrium temperature using the ages, the corresponding past δ¹⁸O of seawater (δ¹⁸O_sw) and the δ¹⁸O of the selected samples formed in contact with bottom seawater with negligible deep fluid influence. A criterion consists of mineralogy, redox-sensitive trace elements and U/Th-isotope systematics is proposed to identify whether the samples were formed from pore water or have been influenced by deep fluid. Our results show that all methane release events occurred between 11.5 ± 0.2 and 144.5 ± 12.7 ka, when sea level was about 62–104 m lower than today. Enhanced methane release during low sea-level stands seems to be modulated by reduced hydrostatic pressure, increased incision of canyons and increased sediment loads. The calculated past bottom water temperature at one site (Site 3; water depth: 767–771 m) during low sea-level stands 11.5 and 65 ka ago ranges from 3.3 to 4.0 °C, i.e., 1.3 to 2.2 °C colder than at present. The reliability of δ¹⁸O of seep carbonates and bivalve shells as a proxy for bottom water temperatures is critically assessed in light of ¹⁸O-enriched fluids that might be emitted from gas hydrate and/or clay dehydration. Our approach provides for the first time an independent estimate of past bottom water temperatures of the upper continental slope of the South China Sea.     

The Greenwich Photo-heliographic Results (1874 – 1976): Summary of the Observations, Applications, Datasets, Definitions and Errors

The measurements of sunspot positions and areas that were published initially by the Royal Observatory, Greenwich, and subsequently by the Royal Greenwich Observatory (RGO), as the Greenwich Photo-heliographic Results (GPR), 1874?–?1976, exist in both printed and digital forms. These printed and digital sunspot datasets have been archived in various libraries and data centres. Unfortunately, however, typographic, systematic and isolated errors can be found in the various datasets. The purpose of the present paper is to begin the task of identifying and correcting these errors. In particular, the intention is to provide in one foundational paper all the necessary background information on the original solar observations, their various applications in scientific research, the format of the different digital datasets, the necessary definitions of the quantities measured, and the initial identification of errors in both the printed publications and the digital datasets. Two companion papers address the question of specific identifiable errors; namely, typographic errors in the printed publications, and both isolated and systematic errors in the digital datasets. The existence of two independently prepared digital datasets, which both contain information on sunspot positions and areas, makes it possible to outline a preliminary strategy for the development of an even more accurate digital dataset. Further work is in progress to generate an extremely reliable sunspot digital dataset, based on the programme of solar observations supported for more than a century by the Royal Observatory, Greenwich, and the Royal Greenwich Observatory. This improved dataset should be of value in many future scientific investigations.     

The Greenwich Photo-heliographic Results (1874 – 1976): Procedures for Checking and Correcting the Sunspot Digital Datasets

Attention is drawn to the existence of errors in the original digital dataset containing sunspot data extracted from certain sections of the printed Greenwich Photo-heliographic Results (GPR) 1874?–?1976. Calculating the polar coordinates from the heliographic coordinates and comparing them with the recorded polar coordinates reveals that there are both isolated and systematic errors in the original sunspot digital dataset, particularly during the early years (1874?–?1914). It should be noted that most of these errors are present in the compiled sunspot digital dataset and not in the original printed copies of the Greenwich Photo-heliographic Results. Surprisingly, many of the errors in the digitised positions of sunspot groups are apparently in the measured polar coordinates, not the derived heliographic coordinates. The mathematical equations that are used to convert between heliographic and polar coordinate systems are formulated and then used to calculate revised (digitised) polar coordinates for sunspot groups, on the assumption that the heliographic coordinates of every sunspot group are correct. The additional complication of requiring accurate solar ephemerides in order to solve the mathematical equations is discussed in detail. It is shown that the isolated and systematic errors, which are prevalent in the sunspot digital dataset during the early years, disappear if revised polar coordinates are used instead. A comprehensive procedure for checking the original sunspot digital dataset is formulated in an Appendix.