Acoustic wave propagation in saturated porous media: reformulation of the Biot/Squirt flow theory

A model of wave propagation in fluid-saturated porous media is developed where the principal fluid/solid interaction mode affecting the propagation of the acoustic wave results from the conjunction of the Biot and the Squirt flow mechanism. The difference between the original Biot/Squirt (BISQ) flow theory and the new theory, which we call the reformulated BISQ, is that the average fluid pressure term appearing in the dynamic equation for a two component solid/fluid continuum is independent of squirt flow length. P-velocity and attenuation relate to measurable rock physical parameters: the Biot's poroelastic constants, porosity, permeability, pore fluid compressibility and viscosity. Modelling shows that velocity and attenuation dispersion obtained using the reformulated BISQ theory are of the same order of magnitude as those obtained using the original BISQ theory. Investigation on permeability effect on velocity and attenuation dispersion indicate that the transition zone in velocity and attenuation peak, occurring both at the relaxation frequency, shifts toward high frequency when permeability decreases. This behaviour agrees with Biot's theory prediction.     

Use of normalized metal concentrations in the Mn oxides/hydrous oxides extraction phase of stream sediments to enhance the difference between a landfill emission plume and background

Normalized concentrations of Fe, Zn, Ba and Co bound to the Mn phase were determined using a ratio of metal concentration to Mn concentration. Metal concentrations were taken from a previous study which found elevated concentrations of heavy metals in the stream sediments in the vicinity of 2 landfills using a HN0₃ extraction of the whole sediment sample and geochemical phases. Results from the normalized metal concentrations for Zn, Fe and Ba showed a clearer distinction between background and emission plume regions along the stream compared to the same for the HN0₃ and Mn phase extractions. Lack of elevated concentrations and normalized concentrations for Co indicated the concentrations represented the background. The small distance used in the study could explain the lack of a decreasing trend of metal concentrations and normalized metal concentrations downstream in the emission plume of the sediments. Although Mn⁺² 2concentrations are known to be incorporated into the natural state of the Mn phase, these concentrations were thought to be small enough not to influence the results from the normalized concentrations. Non-selectivity of extractants and metal redistribution among chemical phases during extraction procedures are thought to be small and did not invalidate the results.     

Modeling climate change and biophysical impacts of crop production in the Austrian Marchfeld Region

Climate change affects major biophysical processes in agricultural crop production (e.g. evaporation of plants and soils, nutrient cycles, and growth of plants). This analysis aims to assess some of these effects by simulating regional climate projections that are integrated in the biophysical process model EPIC (Environmental Policy Integrated Climate). Statistical climate models have been developed for six weather parameters based on daily weather records of a weather station in the Austrian Marchfeld region from 1975 to 2006. These models have been used to estimate daily weather parameters for the period 2007–2038. The resulting projections have been compared to climate scenarios provided from the TYNDALL Centre for Climate Change Research, which are based on General Circulation Models (GCMs). The comparison indicates some differences, namely a smaller temperature increase and a higher precipitation amount in the TYNDALL data. Both climate datasets have been used to simulate impacts of climate change on crop yields, topsoil organic carbon content, and nitrate leaching with EPIC and thus to perform a sensitivity analysis of EPIC. Yield impacts have been assessed for four simulated crops, i.e. 6.2?t/ha for winter wheat for statistical climate projections compared to 5.7?t/ha for TYNDALL scenarios, 10.6?t/ha for corn compared to 10.5?t/ha, 3.9?t/ha for sunflower compared to 3.7?t/ha, and 4.5?t/ha for spring barley compared to 4.3?t/ha—all values as an average over the period 2007–2038. Smaller differences have been simulated for topsoil organic carbon content i.e. 55.1?t/ha for the statistical climate projections compared to 55.3?t/ha for the TYNDALL scenarios and nitrate leaching i.e. 7.1?kg/ha compared to 11.1?kg/ha. All crop yields as well as topsoil organic carbon content and nitrate leaching show highest sensitivity to temperature and solar radiation.     

Downstream effects of impounding a natural lake: the Snake River downstream from Jackson Lake Dam,Wyoming, USA

A sediment mass balance constructed for a 16‐km reach of the Snake River downstream from Jackson Lake Dam (JLD) indicates that river regulation has reduced the magnitude of sediment mass balance deficit that would naturally exist in the absence of the dam. The sediment budget was constructed from calibrated bed load transport relations, which were used to model sediment flux into and through the study reach. Calibration of the transport relations was based on bed load transport data collected over a wide range of flows on the Snake River and its two major tributaries within the study area in 2006 and 2007. Comparison of actual flows with unregulated flows for the period since 1957 shows that operations of JLD have reduced annual peak flows and increased late summer flows. Painted tracer stones placed at five locations during the 2005 spring flood demonstrate that despite the reduction in flood magnitudes, common floods are capable of mobilizing the bed material. The sediment mass balance demonstrates that more sediment exits the study reach than is being supplied by tributaries. However, the volume of sediment exported using estimated unregulated hydrology indicates that the magnitude of the deficit would be greater in the absence of JLD. Calculations suggest that the Snake River was not in equilibrium before construction of JLD, but was naturally in sediment deficit. The conclusion that impoundment lessened a natural sediment deficit condition rather than causing sediment surplus could not have been predicted in the absence of sediment transport data, and highlights the value of transport data and calculation of sediment mass balance in informing dam operations. Copyright © 2011 John Wiley & Sons, Ltd.     

Marine cold seeps and their manifestations: geological control,biogeochemical criteria and environmental conditions

Characteristics of cold seeps at different geologic settings are the subject of this review primarily based on results of the Research Consortium SFB 574. Criteria are drawn from examples on the erosive convergent margin off Costa Rica, the accretionary margin off Chile supplemented by examples from the transform margin of the Golf of Cadiz and the convergent Hikurangi margin off New Zealand. Others are from well-studied passive margins of the Black Sea, the Golf of Mexico, the eastern Mediterranean Sea and the South China Sea. Seeps at all settings transport water and dissolved compounds to the ocean through the seafloor by different forcing mechanism and from different depths of the submerged geosphere (10s of meters to 10s of km). The compounds sustain oasis-type ecosystems by providing bioactive reductants sulfide, methane and hydrogen. Hereby, the interaction between fluid composition, flux rates and biota results in a diagnostic hydrocarbon–metazoan–microbe–carbonate association; currently, well over 100 active sites are known. The single most important reaction is microbially mediated anaerobic oxidation of methane with secondary reactions involving S-biogeochemistry and carbonate mineral precipitation. Seep fluids and their seafloor manifestations provide clues as to source depth, fluid–sediment/rock interaction during ascent, lifetime and cyclicity of seepage events but less so on the magnitude of return flow. At erosive margins, Cl-depleted and B-enriched fluids from clay dehydration provide criteria for source depth and temperature. The upward material flow generates mud volcanoes at the seafloor above the projected location of dehydration at depth. At accretionary margins, fluids are derived from more shallow depths by compaction of sediments as they ride on the incoming oceanic plate; they are emitted through thrust faults. At highly sedimented margins, organic-rich and evaporite-containing strata (when present) determine the final fluid composition, by emitting characteristically gas hydrate-derived methane, brine-associated non-methane hydrocarbons or leached elements and their isotopes (Li, δ⁷Li, B, Ba) from host sediments. Smectite–illite transformation and associated Cl-depletion from release of interlayer water is a pervasive process at these margins. Rare earth element pattern in conjunction with redox-sensitive metals retained in seep carbonates indicate whether or not they precipitated in contact with oxic bottom water or suboxic fluids; clear environmental characterization, though, currently remains inconclusive. More deeply sourced fluids as in transform margins may be characterized by their ⁸⁷Sr/⁸⁶Sr ratios from interaction with oceanic crustal rocks below. Quantification of flow and reliable estimates of total volatile output from fore-arcs remain a challenge to seep research, as does understanding the role of geologically derived methane in the global methane cycle.     

Past methane release events and environmental conditions at the upper continental slope of the South China Sea: constraints by seep carbonates

Authigenic carbonates and seep biota are archives of seepage history and record paleo-environmental conditions at seep sites. We obtained the timing of past methane release events at the northeastern slope of the South China Sea based on U/Th dating of seep carbonates and seep bivalve fragments from three sites located at 22°02′–22°09′N, 118°43′–118°52′E (water depths from 473 to 785 m). Also, we were able to reconstruct the paleo-bottom water temperatures by calculating the equilibrium temperature using the ages, the corresponding past δ¹⁸O of seawater (δ¹⁸O_sw) and the δ¹⁸O of the selected samples formed in contact with bottom seawater with negligible deep fluid influence. A criterion consists of mineralogy, redox-sensitive trace elements and U/Th-isotope systematics is proposed to identify whether the samples were formed from pore water or have been influenced by deep fluid. Our results show that all methane release events occurred between 11.5 ± 0.2 and 144.5 ± 12.7 ka, when sea level was about 62–104 m lower than today. Enhanced methane release during low sea-level stands seems to be modulated by reduced hydrostatic pressure, increased incision of canyons and increased sediment loads. The calculated past bottom water temperature at one site (Site 3; water depth: 767–771 m) during low sea-level stands 11.5 and 65 ka ago ranges from 3.3 to 4.0 °C, i.e., 1.3 to 2.2 °C colder than at present. The reliability of δ¹⁸O of seep carbonates and bivalve shells as a proxy for bottom water temperatures is critically assessed in light of ¹⁸O-enriched fluids that might be emitted from gas hydrate and/or clay dehydration. Our approach provides for the first time an independent estimate of past bottom water temperatures of the upper continental slope of the South China Sea.     

An Algorithm to Determine the Slope of the Spectral Absorption of Colored Dissolved Organic Matter (CDOM) and Detritus

A simple method to determine the slope of spectral variations of combined absorption of the colored dissolved organic matter and detritus (CDM) is presented. This method uses the slope of total absorption spectrum excluding contribution of waters in lieu of slope for the CDM. The errors in slopes using the new method decreased with increase in contributions of CDM to the total absorption. The relative errors were less than 10% when CDM contributions were above 60% and even at very low contributions of CDM of 25%, errors in the slopes were less than 40%. For estuarine and coastal waters rich in CDM, the errors in the slopes for CDM were less than 10% using this simple method. Absorption of CDM derived using the slope with the new method in a semi-analytical algorithm QAAV6 showed improved performance with RMSE of 0.07, 0.0119 and 0.0027 at 405, 555 and 665 nm respectively and with R² > 0.95 at all spectral range. The method provided values of spectral absorption due to CDM with fewer errors when validated with the satellite derived data from MODIS and SeaWiFS. This method to determine the slope of CDM could be easily implemented in any model, as it was very generic in nature, simple, did not involve any mathematical model and avoids empirical methods. Since the method is also independent of any specific bands, it can be used for most ocean color satellites. Considering the performance of this new method and applicability for most water types, it was considered as a better option to derive the slope of CDM than using a constant value or deriving the slope with empirical method.     

Environmental mechanism of magnetic susceptibility changes of lacustrine sediments from Lake Hulun, China

The changes of magnetic susceptibility(κ) are correlated with those of corresponding sedimentological, geochemical, mineralogical and biological results, which verifies thatκ can be taken as one of the environmental proxies. However, usually the exact origin of magnetic signal is poorly understood, and is difficult to relate with the environmental evolution. Magnetic properties of material derived from the catchment and sedimentary environment may affect the accumulation, preservation, or authigenesis and diagenesis of magnetic minerals. In the Lake Hulun region in Inner Mongolia, it is found that muddy sediments, deposited during high water level period (corresponding to humid climate), have comparatively highκ values. In contrast, the sandy sediments, deposited during low water level period (corresponding to arid climate), have lowκ values. Detailed rock magnetic investigation confirms that detrital magnetite derived from volcanic rocks in the catchment exists in both muddy and sandy sediments. During high water level period, secondary ferrimagnetic iron sulphide was produced in muddy sediments under relatively reductive conditions. Ferrimagnetic iron sulphide, coexisting with detrital magnetite, predominates the magnetic properties of muddy sediments, resulting in increasingκ. This paper reveals the significance of authigenic ferrimagnetic iron sulphide produced after sediment deposition.