Toxic Effects of Copper‐Based and Synthetic Organic Pesticides on Activated Sludge

Toxic effects of five commonly used pesticides on the biomass of a municipal activated sludge system were determined on the basis of the reduction in the oxygen uptake rate (OUR) and specific oxygen uptake rate (SOUR). Toxicity levels of the selected pesticides were determined by employing a modified OECD 209 (Organisation for Economic Cooperation and Development) method which was performed as batch experiments using a respirometer. Copper sulphate (CuSO₄ · 5 H₂O), copper oxychloride (Cu₂Cl(OH)₃), copper calcium oxychloride (CaCu₃Cl₂(OH)₆) as copper‐based pesticides and chlorsulphuron (C₁₂H₁₂ClN₅O₄S), 2,4‐dichlorophenoxyacetic acid (2,4‐D) (C₈H₆Cl₂O₃) as synthetic organic pesticides were selected for the experiments. The EC₅₀ values were determined to be 78, 249 and 281 mg/L for CuSO₄ · 5 H₂O, Cu₂Cl(OH)₃ and CaCu₃Cl₂(OH)₆, respectively. Corresponding values for C₁₂H₁₂ClN₅O₄S and 2,4‐D were 860 and 3664 mg/L, respectively. Results indicated that toxicity effects of copper‐based pesticides were higher than that of synthetic organic pesticides. CuSO₄ · 5 H₂O was found to exert the highest toxicity among the copper‐based pesticides, whereas, C₁₂H₁₂ClN₅O₄S was determined to be the most toxic among the organic pesticides on activated sludge biomass.     

Producing forest fire susceptibility map via multi-criteria decision analysis and frequency ratio methods

Natural Hazards - Located in the Mediterranean basin, one of the world’s leading places in terms of forest fires, Turkey is one of the countries where forest fires are experienced very often...     

Comparison of GPS TEC with modelled values from IRI 2016 and IRI-PLAS over Istanbul,Turkey

The Total Electron Content (TEC) prediction performances of the empirical IRI model and IRI-PLAS model were investigated by comparing the GPS-based TEC values provided by the IONOLAB group. TEC values were obtained on equinox (March 21 and September 23) and solstice (June 21, and December 21) days in low (2009), medium (2012) and high (2015) solar activity periods at Istanbul, Turkey. The prediction performances of the models were statistically analyzed based on the differences between the GPS-TEC and the empirical models, considering the maximum and minimum deviations, the correlation analysis and the root mean square error (RMSE). As a result of the investigation, it is seen that the empirical models have similar predictive performances when the plasmaspheric effects are neglected, and the IRI-PLAS estimations are generally a little closer to the observed GPS-TEC values than all options of IRI-2016 model. Also, it can be said that “IRI2001”, one of the IRI-2016’s “topside” options, can make better predictions than other options and “IG” solar proxy option of IRI-PLAS model is a more appropriate option than the others in TEC calculations over Istanbul, Turkey.     

Upper crustal Poisson’s ratio and coda-wave attenuation beneath Eastern Anatolia

The attenuation of seismic waves reflects the elastic nature of the media within which the waves propagate. In this study, we calculate the Coda-Q(Q_c), frequency dependence(η), Vp/Vs and Poisson's(υ) ratios by using 2621 vertical component seismograms generated by 987 earthquakes recorded by 13 seismic stations in Eastern Anatolia, and creat a 2-D seismic tomographic Q_c model for the region. The obtained model provides significant information for exploring the boundaries of adjacent tectonic units within the upper crust and interpreting their dynamic characteristics. The 2-D Q_c model and the other parameters are consistent with the seismotectonic features of Eastern Anatolia. Highly heterogeneous Q_c values are observed in the study area dividing it into north-south directed bands of low and high attenuation. The highest η values were obtained beneath the northwestern and eastern parts of the study region. Clear, high and low υ values are obtained in the western and eastern parts of the study area, respectively. The spatial variations in the measured parameters are consistent with many geophysical observations including low Pn velocities, efficient Sn blockage, high heat flow, and widespread volcanism. Different upper crustal thicknesses and inhomogeneous stress distribution along the East and North Anatolian Fault Zones may also contribute to the observed heterogeneities.     

Spatial Heating Monthly Degree-Day Features and ClimatologicPatterns in Turkey

Summary  Degree-days as a measure of accumulated temperature deviations from a base temperature have many practical applications in various human related activities such as home cooling, heating, plant growth in agriculture and power generation in addition to energy requirement. Long temperature records are necessary for their reliable estimations at given stations. In this paper, degree-day measure has been applied to monthly temperature records for systematically changed base temperature values from − 25 °C to + 35 °C with 5 °C increments at 255 meteorology stations in Turkey. The results are represented in the form of spatial degree-day distribution maps, which are then related to various climatic, meteorological and topographic features of Turkey. For instance, free surface water bodies in forms of surrounding seas, lakes and rivers insert retardation in the expansion of heating degree-days over large regions. On the other hand, cold air penetration from polar regions in the northeastern Turkey originating from Siberia appears at moderate base temperature heating degree-days. Received August 20, 1998 Revised June 21, 1999     

Geological evolution of the Gulf of Saros,NE Aegean Sea

 The Gulf of Saros is an Upper Miocene transtensional basin in NW Anatolia, formed by the interaction between the North Anatolian Fault and the N-S extensional tectonic régime of the Aegean. The present configuration of the basin evolved mainly during the Plio-Quaternary under the increased activity of the North Anatolian Fault. During the late Miocene-late Quaternary, no sedimentation took place on the shelves. After this long hiatus, an important change in tectonic style about 0.2 Ma BP allowed sedimentation to resume in the gulf. Received: 14 February 1997 / Revision received: 12 November 1997     

Investigation of groundwater contamination using electric and electromagnetic methods at an open waste-disposal site: a case study from Isparta, Turkey

 Geophysical methods, when integrated with soil chemical and hydrogeological methods, can be used to investigate groundwater contamination. Direct current (DC) resistivity geo-electrical sounding and very-low-frequency electromagnetic (VLF-EM) data were collected at an open waste site used by the municipality of the city of Isparta, Turkey. The groundwater at shallow depths in alluvium, which is composed of gravel, sand and clay, were expected to be hazardously contaminated under and around the open waste-disposal site, in which both household and industrial wastes are known to be disposed of improperly. In this study, we mapped the spread of groundwater contamination using a VLF-EM method, which allows fast and inexpensive data collection. The method complements the results of geo-electrical sounding. There is a good correlation between the results of the VLF-EM and the DC-resistivity methods employed for the investigation of subsurface structure of the site, where soil chemical and previous hydrogeological surveys have indicated high levels of chemical concentrations. Received: 17 January 2000 · Accepted: 12 August 2000     

Vibration analysis of stepped-pipe strings for mining from deep-sea floors

The present study addresses essentially to the investigation of the longitudinal vibrations of a stepped-pipe string for mining from deep-sea floors. The stepped-pipe string, consisting of four parts having different physical properties in each pipe string segment, is assumed to have two pump modules and a buffer, each of which is equipped with a vibration absorber. Moreover, the pipe string is subjected to external viscous damping because of the surrounding medium. A theoretical analysis has been made for a simplified model of the system, in which it is assumed that both the pump modules and buffer can be considered as concentrated masses, the fluid inside of the pipe string vibrates together with the string, and that the flexible pipe does not affect the vibration of the pipe string. Furthermore, absorbers are modeled as concentrated masses, each of which is attached to pump modules and the buffer by springs and dampers. Applying the method of separation of variables, exact analytical solutions for damped free and forced responses of the system subjected to heave motion of the mining ship are determined with and without absorbers, in which overdamped and underdamped modes are determined and studied separately too. It is important to note that the solutions obtained are expressed in terms of parameters characterizing the physical properties of the system under consideration. Numerical applications show that the attachment of convenient vibration absorbers causes the longitudinal displacements at the certain locations to decrease to very small values, where the vibration absorbers are adjusted to the excitation frequency.     

Swell pressure prediction by suction methods

Soil suction is the most relevant soil parameter for characterization of the swell behavior. An attempt was made to predict swell pressures from soil suction measurements. In this study, Na-bentonite was mixed with kaolinite in the ratios of 5, 10, 15, 20 and 25% of dry kaolinite weight to obtain soils in a wide range of plasticity indices (i.e. 30, 50, 68, 84 and 97%). Suction measurements using thermocouple psychrometer technique were made on statically compacted specimens. The dependence of soil suction on water content, dry density and bentonite content was examined. Soil suction was correlated to the soil properties, namely, water content, plasticity index, dry density, cation exchange capacity and specific surface area using multiple regression analyses. The correlations revealed a simple regression equation for a quick prediction of soil suctions from easily determined soil properties. In order to investigate soil suction versus swell pressure behavior, the results of standard constant volume swell tests (ASTM, 1990) performed on statically compacted samples of these clay mixtures were used. A linear relationship was established between the logarithm soil suction and the swell pressure. It was also found that an experimental relationship which would directly relate the initial soil suction to the swell pressure can be established.